Journal ArticleDOI
Synthesis and Structure of a Monomeric Aluminum(I) Compound [{HC(CMeNAr)2}Al] (Ar=2,6–iPr2C6H3): A Stable Aluminum Analogue of a Carbene
Chunming Cui,Herbert W. Roesky,Hans-Georg Schmidt,Mathias Noltemeyer,Haijun Hao,Fanica Cimpoesu +5 more
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This article is published in Angewandte Chemie.The article was published on 2000-12-01. It has received 385 citations till now. The article focuses on the topics: Carbene & Lewis acids and bases.read more
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N-heterocyclic carbene analogues with low-valent group 13 and group 14 elements: syntheses, structures, and reactivities of a new generation of multitalented ligands.
Journal ArticleDOI
The Chemistry of β-Diketiminatometal Complexes
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NHCs in Main Group Chemistry.
Vitaly Nesterov,Dominik Reiter,Prasenjit Bag,Philipp Frisch,Richard Holzner,Amelie Porzelt,Shigeyoshi Inoue +6 more
TL;DR: A general overview of the chemistry of low-coordinate main group element compounds, basic synthetic approaches, key features of NHC-main group element adducts, and might be useful for the broad research community are given.
Journal ArticleDOI
The Chemistry of Aluminum(I), Silicon(II), and Germanium(II)
TL;DR: Although tetrameric Al(I) compounds have been known for a long time, the monomeric carbenes are very recent entrants in Al-I chemistry as discussed by the authors.
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Oxidative Addition and Reductive Elimination at Main-Group Element Centers
Terry Chu,Georgii I. Nikonov +1 more
TL;DR: This Review highlights the substantial progress achieved in the past decade for the activation of robust single bonds by main-group compounds and the more recently realized activation of multiple bonds by these elements.
References
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General atomic and molecular electronic structure system
Michael W. Schmidt,Kim K. Baldridge,Jerry A. Boatz,Steven T. Elbert,Mark S. Gordon,Jan H. Jensen,Shiro Koseki,Nikita Matsunaga,Kiet A. Nguyen,Shujun Su,Theresa L. Windus,Michel Dupuis,John A. Montgomery +12 more
TL;DR: A description of the ab initio quantum chemistry package GAMESS, which can be treated with wave functions ranging from the simplest closed‐shell case up to a general MCSCF case, permitting calculations at the necessary level of sophistication.
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Phase annealing in SHELX-90: direct methods for larger structures
TL;DR: In this article, a phase annealing method, related to the simulated-annealing approach in other optimization problems, is proposed and it is shown that it can result in an improvement of up to an order of magnitude in the chances of solving large structures at atomic resolution.
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π-Bonding and the Lone Pair Effect in Multiple Bonds between Heavier Main Group Elements
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Synthesis, Structure, and Reactivity of β-Diketiminato Aluminum Complexes
TL;DR: In this article, the preparation and reaction chemistry of β-diketiminato aluminum complexes are described, and the precursors of these complexes are obtained by treating AlCl3 with LiTTP.