Journal ArticleDOI
Synthesis, characterization and magnetic property of a succinate bridged 1D coordination polymer of cobalt(II) containing benzidine as end-capping ligand
TLDR
In this article, a bis(monodentate) succinate bridged 1D coordination polymer [Co(bnzd) 2 (μ-suc)(OH 2 ) 2 ] n ⋅(H 2 O) n ( 1 ) (bnzdr=benzidine; suc=succinate dianion) has been isolated using a one-pot reaction of the building components, and characterized structurally and magneto-structurally.About:
This article is published in Journal of Molecular Structure.The article was published on 2014-03-05. It has received 15 citations till now. The article focuses on the topics: Coordination polymer & Octahedral molecular geometry.read more
Citations
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Journal ArticleDOI
Paramagnetic One-Dimensional Chain Complex Consisting of Three Kinds of Metallic Species Showing Magnetic Interaction through Metal-Metal Bonds.
Kazuhiro Uemura,Rika Miyake +1 more
TL;DR: The magnetic behavior of 3 was investigated and found to be consistent with a complex interaction involving both zero-field splitting and Pauli paramagnetism attributed to band formation superimposed on relatively strong exchange coupling (zJ = -22.2 cm-1).
Journal ArticleDOI
1,1-Cyclohexanediacetate as New Bridging Ligand for Assembling of Homo- and Heterometallic Molecular Complexes with Cu 3 II , Cu 2 II Ln 2 III (Ln = Sm or Gd) and Ni 2 II Gd 2 III Cores: Synthesis, Structure and Magnetic Properties
N. V. Gogoleva,E. N. Zorina-Tikhonova,Grigory G. Aleksandrov,A. S. Lermontov,Nikolay N. Efimov,Artem S. Bogomyakov,Elena A. Ugolkova,Sergey V. Kolotilov,Aleksey A. Sidorov,Vadim V. Minin,Vladimir M. Novotortsev,Igor L. Eremenko +11 more
TL;DR: In this article, the trinuclear homometallic complexes were synthesized in acetonitrile with tetrabutylammonium salt of 1,1-cyclohexanediacetate (Chda2−) and 2,2-bipyridine (2,2′-bpy) 2(Chda)2(Piv)6] in the presence of carboxylic groups.
Journal ArticleDOI
Reactivity of vanadium oxytrichloride with β-diketones and diesters as precursors for vanadium nitride and carbide
Ben J. Blackburn,Jared H. Crane,Caroline E. Knapp,Michael Powell,Peter Marchand,David Pugh,Joseph C. Bear,Ivan P. Parkin,Claire J. Carmalt +8 more
TL;DR: In this paper, vanadium(V) oxytrichloride was reacted with 2,4-pentanedione, diethyl malonate, and Diethyl succinate under inert conditions, forming compounds.
Dissertation
Study of Gas-Phase Reactions in TiO₂ Production and Functionalised Thin Films
TL;DR: In this article, the authors present a system for the in-situ study of high temperature gas phase inorganic reactions via mass spectroscopy, which is used to study the reactivity of gaseous TiO₄ and VOCl₃.
Journal ArticleDOI
Syntheses, crystal structures and luminescence behaviors of four neutral penta-/hexacoordinate cadmium(II) compounds containing a tridentate Schiff base: Variation in coordination numbers, nuclearities and dimensionalities by changing halides/pseudohalides
TL;DR: Two neutral pentacoordinate mononuclear cadmium(II) complexes of the type [Cd(L)X2] [L=N-(pyridin-2′-yl)benzylidene)-2-(piperidin 1-yl)-ethane-1,2-diamine; X =※Cl, (1) and X`= Br, (2) have been prepared and characterized using microanalytical, spectroscopic, thermal and X-ray crystallographic results.
References
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Journal ArticleDOI
A short history of SHELX
TL;DR: This paper could serve as a general literature citation when one or more of the open-source SH ELX programs (and the Bruker AXS version SHELXTL) are employed in the course of a crystal-structure determination.
Book
Infrared and Raman Spectra of Inorganic and Coordination Compounds
TL;DR: In this article, the normal modes of vibration are illustrated and corresponding vibrational frequencies are listed for each type, including diatomic, triatomic, fouratomic, five-atomic, six-atomic and seven-atomic types.
Journal ArticleDOI
Mercury: visualization and analysis of crystal structures
Clare F. Macrae,Paul R. Edgington,Patrick McCabe,Elna Pidcock,Greg P. Shields,Robin Taylor,Matthew Towler,Jacco van de Streek +7 more
TL;DR: Mercury as discussed by the authors is a crystal structure visualization program that allows to display multiple structures simultaneously and overlay them, which can be used for comparison between crystal structures and to overlay them in a table or spreadsheets.