Journal ArticleDOI
Synthesis of bio-based methacrylic acid from biomass-derived itaconic acid over barium hexa-aluminate catalyst by selective decarboxylation reaction
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TLDR
In this paper, an environmentally-benign, efficient and inexpensive high surface area barium hexa-aluminate (BaAl12O19, BHA) was developed as a catalyst for the decarboxylation of the biomass-derived itaconic acid (IA) to bio-based methacrylic acid (MAA).About:
This article is published in Molecular Catalysis.The article was published on 2019-10-01. It has received 18 citations till now. The article focuses on the topics: Methacrylic acid & Itaconic acid.read more
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Radical Polymerization of Acrylates, Methacrylates, and Styrene: Biobased Approaches, Mechanism, Kinetics, Secondary Reactions, and Modeling
T. Pirman,M. Ocepek,Blaž Likozar +2 more
TL;DR: In this article, the different intermediate pathways toward renewable structural constituents, which can substitute petrochemically derived unsustainable biomolecular molecules, are discussed. But, the intermediate pathways are not considered in this paper.
Journal ArticleDOI
Isosorbide: Recent advances in catalytic production
Frederic Delbecq,Mohamad Reza Khodadadi,Daily Rodriguez Padron,Daily Rodriguez Padron,Rajender S. Varma,Christophe Len,Christophe Len +6 more
TL;DR: In this article, the state-of-the-art advancements on the production of isosorbide, a furanic diol exclusively produced via a two-steps dehydrocyclisation of sorbitol; polyol acquired from the catalytic reduction of glucose.
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A Review of the Biotechnological Production of Methacrylic Acid.
TL;DR: The potential of biobased routes from sugars to the large volume commodity, methacrylic acid, involving fermentation based bioprocesses is reviewed, including both academic as well as patent literature.
Journal ArticleDOI
Production and Polymerization of Biobased Acrylates and Analogs.
TL;DR: In this paper, a review of the progress made in the production and polymerization of (meth)acrylates and their analogs is presented, focusing on the obtention of the monomers from which they are derived.
Journal ArticleDOI
A sustainable waterborne vanillin–eugenol–acrylate miniemulsion with suitable antibacterial properties as a substitute for the styrene–acrylate emulsion
TL;DR: In this article, double bond modified vanillin (DV) and double-bonded modified eugenol (DE) were respectively used as sustainable alternatives for petroleum-based styrene (St) and the diacetone acrylamide-adipic acid dihydrazide (DAAM-ADH) crosslinker to copolymerize with butyl acrylate (BA) to prepare a sustainable, water-borne P(DV-BA-DE) miniemulsion by the mini-emulsion polymerization technique.
References
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Graphitic Carbon Nitride: Synthesis, Properties, and Applications in Catalysis
TL;DR: This paper aims to inspire readers to search for further new applications for this material in catalysis and in other fields by describing the methods used for synthesizing this material with different textural structures and surface morphologies.
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Facile synthesis of highly active g-C3N4 for efficient hydrogen production under visible light
TL;DR: In this paper, a graphitic C3N4 photocatalyst from a mixture of urea and melamine with advanced structural, optical and electronic properties and enhanced photocatalytic activity for the production of hydrogen gas is explored.
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Decarboxylation as the Key Step in C−C Bond‐Forming Reactions
Tuhin Patra,Debabrata Maiti +1 more
TL;DR: This Review provides an overview on the most recent progress in the field of C-C bond formation involving decarboxylation as a key step involving carboxylic acid.
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Bio-Ethanol Based Ethylene
TL;DR: The use of bioethanol-based ethylene as raw material for chemical products, especially to produce polyethylene and other polymers, is being considered an effective way to capture carbon dioxide from the atmosphere and offer to the market an alternative of a commodity plastic with a wide range of applications and a low carbon footprint as mentioned in this paper.
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New developments in the production of methyl methacrylate
TL;DR: Methyl methacrylate MMA can be produced in different ways based on C2-C4 hydrocarbon feedstocks as discussed by the authors, and a comparison of these production routes is given.