Journal ArticleDOI
The Anderson–Evans polyoxometalate: From inorganic building blocks via hybrid organic–inorganic structures to tomorrows “Bio-POM”
Amir Blazevic,Annette Rompel +1 more
TLDR
The Anderson-Evans archetype is a highly flexible POM cluster that allows modification from several point-of-views; it can incorporate a large number of different heteroatoms differing in size and oxidation state, and can incorporate inorganic and organic cations and molecules demonstrating different coordination motifs, and covalent attachment with tris(hydroxymethyl)methane ligands allows it to be combined with specific organic functionalities as mentioned in this paper.About:
This article is published in Coordination Chemistry Reviews.The article was published on 2016-01-15. It has received 227 citations till now. The article focuses on the topics: Heteroatom.read more
Citations
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Polyoxometalates as Potential Next-Generation Metallodrugs in the Combat Against Cancer.
TL;DR: An overview is given of the cytotoxic effects of POMs with a special focus on POM‐based hybrid and nanocomposite structures and a proposed mode of actions and to identify molecular targets are provided.
Journal ArticleDOI
Synthesis, structures and applications of electron-rich polyoxometalates
TL;DR: More than 200 reduced polyoxometalates (POMs) structures are described in this paper, with emphasis placed on how reduction influences POM structure, function and properties.
Journal ArticleDOI
The antibacterial activity of polyoxometalates: structures, antibiotic effects and future perspectives.
TL;DR: This Feature Article focuses on the antibacterial activity of POMs and POM-based hybrid and nanocomposite structures highlighting recent advances in the synthesis of biologically active POM systems and providing the state of the art in this research field.
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Hybrid polyoxometalates as post-functionalization platforms: from fundamentals to emerging applications
TL;DR: This review article provides an overview on the state of the art in POM post-functionalization and highlights the key design and structural features that permit the discovery of new hybrid-POM platforms to make the subject more comprehensible.
Journal ArticleDOI
Recent advances in alkoxylation chemistry of polyoxometalates: From synthetic strategies, structural overviews to functional applications
TL;DR: The functionalization of polyoxometalates with organic ligands provides a novel strategy to precisely incorporate POMs with advanced functional organic moieties on their surfaces and enhance their compatibility in organic media.
References
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Book
Heteropoly and Isopoly Oxometalates
TL;DR: A survey of polyoxometalates can be found in this paper, where the authors survey the chemistry, structures, and applications of these species, as well as their applications in inorganic chemistry.
Journal ArticleDOI
Quantum computing in molecular magnets
TL;DR: In this article, an implementation of Grover's algorithm that uses molecular magnets was proposed, which can be used to build dense and efficient memory devices based on the Grover algorithm, in which one single crystal can serve as a storage unit of a dynamic random access memory device.
Quantum computing in molecular magnets
TL;DR: In this article, an implementation of Grover's algorithm that uses molecular magnets was proposed, which can be used to build dense and efficient memory devices based on the Grover algorithm, in which one single crystal can serve as a storage unit of a dynamic random access memory device.
Journal ArticleDOI
Polyoxometalate clusters, nanostructures and materials: From self assembly to designer materials and devices
TL;DR: In this critical review the synthetic and design approaches to the many polyoxometalate cluster types are presented encompassing all the sub-types of polyxometalates including, isopolyoxometAlates, heteropolyoxometricalates, and reduced molybdenum blue systems.
Journal ArticleDOI
Polyoxometalates: Building Blocks for Functional Nanoscale Systems
TL;DR: The possibilities of creating highly sophisticated functional hierarchical systems with multiple, interdependent, functionalities along with a critical analysis that allows the non-specialist to learn the salient features of POMs are discussed.