Journal ArticleDOI
The First Isolable Dialkylsilylene
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This article is published in Journal of the American Chemical Society.The article was published on 1999-09-29. It has received 348 citations till now.read more
Citations
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Stable Heavier Carbene Analogues
TL;DR: The early silylene research was concerned largely with comparing the chemistry of the dihalosilylenes with that of carbenes, so it might be difficult to isolate metallylenes as stable compounds under ambient conditions.
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Aromaticity as a cornerstone of heterocyclic chemistry.
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Lewis Base Stabilized Dichlorosilylene
TL;DR: The synthesis of the first basestabilized dichlorosilylene that is stable at room temperature, LSiCl2 is reported, which is quite similar or close to those of unstable examples, such as SiCl2.
Journal ArticleDOI
The Chemistry of Aluminum(I), Silicon(II), and Germanium(II)
TL;DR: Although tetrameric Al(I) compounds have been known for a long time, the monomeric carbenes are very recent entrants in Al-I chemistry as discussed by the authors.
Journal ArticleDOI
A stable two-coordinate acyclic silylene.
Andrey V. Protchenko,Krishna Hassomal Birjkumar,Deepak Dange,Andrew D. Schwarz,Dragoslav Vidovic,Cameron Jones,Nikolas Kaltsoyannis,Philip Mountford,Simon Aldridge +8 more
TL;DR: Simple two-coordinate acyclic silylene species, SiR(2), can be synthesized which is stable in the solid state up to 130 °C and undergoes facile oxidative addition reactions with dihydrogen and with alkyl C-H bonds, thus demonstrating fundamental modes of reactivity more characteristic of transition metal systems.
References
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Journal ArticleDOI
Synthesis and Structure of a Stable Silylene
Michael K. Denk,Robert P. Lennon,Ryuji Hayashi,Robert West,Alexander V. Belyakov,Hans Peter Verne,Arne Haaland,Matthias Wagner,Nils Metzler +8 more
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Multiply bonded germanium species. Recent developments
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Stable silylenes: synthesis, structure, reactions
Robert West,Michael K. Denk +1 more
TL;DR: Silylenes, R2Si as mentioned in this paper, are the silicon counterparts to carbenes of organic chemistry and play an even more important role in silicon chemistry than carbon chemistry, and are key intermediates in many thermal and photochemical reactions of organosilicon compounds.
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Synthesis, structures and reactions of new thermally stable silylenes.
TL;DR: In this article, a new series of stable but reactive bis(amino)silylenes, derived from the N,N′-dineopentyl-1,2-phenylenediamido ligand RC6H3[(CH2But)]2, have been prepared by reductive elimination from RC6Cl2 and characterised by NMR spectroscopy and for 1a X-ray crystallography.
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Decamethylsilicocene—Synthesis and Structure
Peter Jutzi,D. Kanne,Carl Krüger +2 more