Journal ArticleDOI
The mechanism of disproportionation of D-glucose catalysed by hydridochlorocarbonyltris(triphenyl-phosphine)ruthenium(II) in tetrahydrofurfuryl alcohol
TLDR
In this paper, the rate of D-glucose disproportionation in tetrahydrofurfuryl alcohol (THFA) catalysed by RuHCl(CO)(PPh3)3 is suggested.About:
This article is published in Journal of Molecular Catalysis.The article was published on 1983-12-01. It has received 8 citations till now. The article focuses on the topics: Disproportionation & Alkoxide.read more
Citations
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Journal ArticleDOI
A Facile Route to Carbonylhalogenometal Complexes (M = Rh, Ir, Ru, Pt) by Dimethylformamide Decarbonylation
TL;DR: Dimethyl formamide (DMF) can be a convenient source of the carbonyl ligand in the coordination chemistry of rhodium, ruthenium, iridium, and platinum as discussed by the authors.
Journal ArticleDOI
Mechanism for transfer hydrogenation of ketones to alcohols catalysed by hydridotri-ironundecacarbonylate anion under phase transfer conditions
K. Jothimony,S. Vancheesan +1 more
TL;DR: In this paper, a mechanism for the transfer hydrogenation of ketones to secondary alcohols catalysed by HFe3(CO)11−1 (1) in the presence of Phase Transfer Catalysts (PTC) has been proposed using labelled hydrogen, NMR and IR techniques.
Journal ArticleDOI
Phase transfer-catalysed transfer hydrogenation of ketones using iron carbonyls as catalysts
TL;DR: In this paper, the phase transfer agent, phase transfer catalysts, and donors are compared based on the percentage yield of the products, and the efficiencies of phase transfer agents, iron carbonyls and donors.
Journal ArticleDOI
RuCl2(PPh3)3-catalyzed transfer hydrogenation of d-glucose
TL;DR: In this paper, a mixed solvent system such as dimethylacetamide-water and dioxane-water is used for the transfer hydrogenation of glucose to a mixture of mixed solvent systems.
Journal ArticleDOI
Transformation of Glucose into Sorbitol on Raney Nickel Catalysts in the Absence of Molecular Hydrogen: Sugar Disproportionation vs Catalytic Hydrogen Transfer
TL;DR: In this article, Raney nickel catalysts have been tested in the transformation of glucose into sorbitol through a hydrogen transfer pathway in the presence of short chain alcohols and showed that catalytic hydrogen transfer was only possible from ethanol under the tested neutral conditions.
References
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Journal ArticleDOI
Triarylphosphine, hydride, and ethylene complexes or rhodium(I) chloride
Journal ArticleDOI
Dichlorotris(triphenylphosphine)ruthenium-catalyzed hydrogen transfer from alcohols to saturated and .alpha.,.beta.-unsaturated ketones
Yoel Sasson,Jochanan Blum +1 more
Journal ArticleDOI
Transfer hydrogenation and transfer hydrogenolysis. V. Hydrogen transfer from amines, ethers, alcohols, and hydroaromatic compounds to olefins catalyzed by chlorotris(triphenylphosphine)rhodium(I)
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Transfer hydrogenation and transfer hydrogenolysis. IX. Hydrogen transfer from organic compounds to aldehydes and ketones catalyzed by dihydridotetrakis(triphenylphosphine)ruthenium(II)
Journal ArticleDOI
Transfer hydrogenation and transfer hydrogenolysis. II. Catalytic activity of some soluble complexes in hydrogen transfer from alcohols to olefins and the mechanism of the reaction catalyzed by hydridotetrakis(triphenylphosphine)rhodium(I)
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Methanol as a hydrogen donor in reactions homogeneously catalysed by ruthenium and rhodium complexes
Thomas J. Smith,Peter M. Maitlis +1 more