Journal ArticleDOI
The synthesis of polyolefin graft copolymers by reactive extrusion
TLDR
A critical review of the melt phase synthesis of polyolefin graft copolymers with reactive functionality is given in this article, which may serve as precursors to other polyolefins with grafted maleic anhydride, fumarate and maleate esters.About:
This article is published in Progress in Polymer Science.The article was published on 1999-04-01. It has received 528 citations till now. The article focuses on the topics: Reactive extrusion & Glycidyl methacrylate.read more
Citations
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Journal ArticleDOI
"Bound but not gagged"--immobilizing single-site alpha-olefin polymerization catalysts.
Journal ArticleDOI
Luminogenic polymers with aggregation-induced emission characteristics
TL;DR: Aggregation-induced emission (AIE) is a newly developed phenomenon that is exactly opposite to the aggregation-caused emission quenching effect observed with some conventional luminophores as discussed by the authors.
Journal ArticleDOI
Polypropylene–clay nanocomposites: effect of compatibilizing agents on clay dispersion
TL;DR: In this article, polypropylene-clay nanocomposites are obtained and studied by using two different coupling agents, diethyl maleate and maleic anhydride.
Journal ArticleDOI
The preparation and rheology characterization of long chain branching polypropylene
Jinghua Tian,Wei Yu,Chixing Zhou +2 more
TL;DR: In this article, the rheological behavior of long chain branching polypropylene (LCB) was studied in the presence of 2,5-dimethyl-2,5( tert -butylperoxy) hexane peroxide and pentaerythritol triacrylate (PETA) in mixer.
Journal ArticleDOI
Melt rheology of polyolefins
TL;DR: A review of the melt rheology of polyolefins, which are the most widely used group of thermoplastic polymers today, is given in this article both in terms of application and characterisation aspects.
References
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Journal ArticleDOI
Studies on polymer blend of nylon 6 and polypropylene or nylon 6 and polystyrene using the reaction of polymer
Fumio Ide,Akira Hasegawa +1 more
TL;DR: In this article, a graft polymer between maleic anhydride in polypropylene and terminal amino groups of nylon 6 was found to be formed by the formation of a certain graft polymer, which was confirmed by solvent extraction, estimation of the amino group and identification by differential scanning calorimetry.
Book
The chemistry of free radical polymerization
Graeme Moad,David H. Solomon +1 more
TL;DR: In this article, the authors introduce a free radical reaction pathway for combination pathways for disproportionation combination vs disproportionation summary, and a termination termination pathway for termination pathway with oxygen initiator efficiency cage reaction and by-products.
Journal ArticleDOI
Which Factors Determine the Reactivity and Regioselectivity of Free Radical Substitution and Addition Reactions
TL;DR: In this paper, the relative importance of bond strength, steric effects, and polarity in determining the rate and orientation of free radical subsitution and free radical addition reaction is considered.
Journal ArticleDOI
Molecular characterization of maleic anhydride-functionalized polypropylene
TL;DR: In this article, the molecular characterization of maleic anhydride melt-functionalized polypropylene (PP-g-MA) was discussed, the functionalization mechanism, the nature, the concentration, and the location of grafted anhydrides species onto the poly-propylene chain are discussed.
Book
NMR of polymers
Frank A. Bovey,Peter A. Mirau +1 more
TL;DR: In this article, the authors introduce the Solid-State NMR of polymers, and present a model of the structure of polymer chains and their properties in the solid state.