Journal ArticleDOI
Thermal stability of choline chloride deep eutectic solvents by TGA/FTIR-ATR analysis
Noemí Delgado-Mellado,Marcos Larriba,Pablo Navarro,Victoria Rigual,Miguel Ayuso,Julián García,Francisco Rodríguez +6 more
TLDR
In this paper, the thermal stability of choline chloride-based deep eutectic solvents based on the cation choline has been studied using isothermal and dynamic thermogravimetric analysis/Fourier transform infrared-attenuated total reflectance spectroscopy (TGA/FTIR-ATR).About:
This article is published in Journal of Molecular Liquids.The article was published on 2018-06-15. It has received 229 citations till now. The article focuses on the topics: Choline chloride & Thermogravimetric analysis.read more
Citations
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Journal ArticleDOI
Deep Eutectic Solvents: A Review of Fundamentals and Applications.
Benworth Hansen,Stephanie Spittle,Brian Chen,Derrick Poe,Yong Zhang,Jeffrey M. Klein,Alexandre Horton,Laxmi Adhikari,Tamar Zelovich,Brian W. Doherty,Burcu Gurkan,Edward J. Maginn,Arthur J. Ragauskas,Mark Dadmun,Thomas A. Zawodzinski,Gary A. Baker,Mark E. Tuckerman,Robert F. Savinell,Joshua Sangoro +18 more
TL;DR: A detailed review of the current literature reveals the lack of predictive understanding of the microscopic mechanisms that govern the structure-property relationships in deep eutectic solvents, and highlights recent research efforts to elucidate the next steps needed to develop a fundamental framework needed for a deeper understanding.
Journal ArticleDOI
Degradation of deep-eutectic solvents based on choline chloride and carboxylic acids
Nerea Rodriguez Rodriguez,Adriaan van den Bruinhorst,Laura J. B. M. Kollau,Maaike C. Kroon,Koen Binnemans +4 more
TL;DR: The thermal and long-term stability of carboxylic acid-choline chloride (ChCl) solvents has been investigated in this paper, showing that the mixture of choline chloride and carboxyl acid is stable.
Journal ArticleDOI
A paradigm of storage batteries
TL;DR: There are multiple dimensions of considerations for constructing the new paradigm of storage batteries in the search for market-winning storage solutions.
Journal ArticleDOI
Eutectics: formation, properties, and applications
TL;DR: A comprehensive overview of typical eutectics and task-specific strategies to address growing demands can be found in this paper, where the authors provide a comprehensive review of the typical eUTectics.
Journal ArticleDOI
Physicochemical properties of choline chloride-based deep eutectic solvents and excess properties of their pseudo-binary mixtures with 1-butanol
Nicolás F. Gajardo-Parra,Michael J. Lubben,Joshua M. Winnert,Angel Leiva,Joan F. Brennecke,Roberto I. Canales +5 more
TL;DR: In this article, the authors measured decomposition temperature, surface tension, density, and viscosity for deep eutectic solvents based on choline chloride as the hydrogen bond acceptor and levulinic acid, ethylene glycol and phenol as hydrogen bond donors.
References
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Deep Eutectic Solvents (DESs) and Their Applications
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Novel solvent properties of choline chloride/urea mixtures
TL;DR: Eutectic mixtures of urea and a range of quaternary ammonium salts are liquid at ambient temperatures and have interesting solvent properties.
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Deep eutectic solvents: syntheses, properties and applications
TL;DR: All works discussed in this review aim at demonstrating that Deep Eutectic Solvents not only allow the design of eco-efficient processes but also open a straightforward access to new chemicals and materials.
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Deep Eutectic Solvents Formed between Choline Chloride and Carboxylic Acids: Versatile Alternatives to Ionic Liquids
TL;DR: It is shown that the conductivity and viscosity of these liquids is controlled by ion mobility and the availability of voids of suitable dimensions, and this is consistent with the fluidity of other ionic liquids and molten salts.
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Low melting mixtures in organic synthesis – an alternative to ionic liquids?
Carolin Ruß,Burkhard König +1 more
TL;DR: A review of physicochemical data of these reaction media and highlights recent advances in their use in organic synthesis and biotransformations can be found in this article, where the authors highlight the need to replace hazardous and harmful solvents with green or sustainable media.