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Open AccessJournal ArticleDOI

Titanium nitride as light trapping plasmonic material in silicon solar cell

TLDR
In this paper, the plasmonic effect significantly dominant to achieve maximum absorption enhancement g (λ ) at longer wavelengths (red and near infrared) and as comparable with Au nanoparticle on thin film Silicon.
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This article is published in Optical Materials.The article was published on 2017-10-01 and is currently open access. It has received 35 citations till now. The article focuses on the topics: Plasmonic solar cell & Polymer solar cell.

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Citations
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Bifunctional biomorphic SiC ceramics embedded molten salts for ultrafast thermal and solar energy storage

TL;DR: In this article, a strategy to achieve ultrafast solar and thermal energy storage based on biomorphic SiC skeletons embedded NaCl-KCl molten salts is presented. But, the intrinsic low thermal conductivity of PCMs has become a bottleneck for rapid energy transport and storage.
Journal ArticleDOI

Versatile photonic band gap materials for water desalination

TL;DR: In this article, a novel way using photonic crystals by theoretical studies to water desalination was obtained by coupling between pyramids and porous structures to yield an efficient solar desalification device.
Journal ArticleDOI

Multipass and reciprocating microwear study of TiN based films

TL;DR: In this paper, the effect of sliding motion in wear tests was studied, comparing multipass (unidirectional) and reciprocating (bidirectional), and the results showed that increasing the nitrogen content during the deposition cause a decrease in the adhesion of the coating.
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Performance improvement of ultrathin organic solar cells utilizing light-trapping aluminum-titanium nitride nanosquare arrays

TL;DR: In this article, a bilayer of Al-TiN nanosquare array has been proposed as a novel plasmonic scheme in order to improve the photocurrent and the solar absorption of organic solar cells.
Journal ArticleDOI

Polarization-tuned chromatic electrodes using hybrid design of graphene-aluminum nanocross arrays for efficient organic solar cells

TL;DR: In this paper, a hybrid nanostructure of graphene and aluminum nanocross arrays has been employed for the first time to replace ITO in organic solar cells, mapping the polarization of the incident light to visible color results in solar-powered chromatic polarizers.
References
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Journal ArticleDOI

Plasmonics for improved photovoltaic devices

TL;DR: Recent advances at the intersection of plasmonics and photovoltaics are surveyed and an outlook on the future of solar cells based on these principles is offered.
Book

Optical Properties of Metal Clusters

TL;DR: In this paper, the authors present a survey of optical spectra of Elemental Metal Clusters and Chain Aggregates and discuss experimental results and experimental methods for metal clustering experiments.
Journal ArticleDOI

Surface plasmon enhanced silicon solar cells

TL;DR: Pillai and Catchpole this article acknowledge the UNSW Faculty of Engineering Research Scholarship and the support of an Australian Research Council fellowship, which they used to support their work in this article.
Journal ArticleDOI

Alternative Plasmonic Materials: Beyond Gold and Silver

TL;DR: This review explores different material classes for plasmonic and metamaterial applications, such as conventional semiconductors, transparent conducting oxides, perovskiteOxides, metal nitrides, silicides, germanides, and 2D materials such as graphene.
Journal ArticleDOI

Photovoltaic materials: Present efficiencies and future challenges

TL;DR: A comprehensively and systematically review the leading candidate materials, present the limitations of each system, and analyze how these limitations can be overcome and overall cell performance improved.
Related Papers (5)
Frequently Asked Questions (18)
Q1. What is the effect of plasmonics on solar cells?

At plasmonic resonance, light is preferentially scattered by the nanoparticles decorating the surface of solar cell into solar cell’s actively absorbing layer and improves free carrier generation. 

In this paper, the effect of surface plasmon resonance ( LSPR ) on solar cells was investigated. 

The maximum absorption enhancement g(λ) of 20% is achieved when the TiN nanoparticle diameter is about 100 nm and 40% of enhancement is achieved in case Au Nanoparticles about 100 nm. 

In this process, incident light stimulates the oscillation of conduction electrons at interfaces containing metal nanoparticles or nanostructures of subwavelength size. 

Further absorption enhancement g(λ) is decreased at higher wavelength range with an increment of TiN nanparticles diameter above 110 nm. 

If the plasmonic nanoparticledeposited between the air-glass interface then preferential scattering would be into the glass due to its higher refractive index [52, 53]. 

The further increment of metal nanoparticle size, higher order mode excitation will take place, which light scatter can enhance or decrease the light trapping efficiency into the substrate depending upon the order of modes excited [22, 44, 45, 13, 48]. 

The insights in this paper suggest that TiN can be a potential plasmonic material for thin film photovoltaics, Visible and infrared applications and optoelectronics. 

In addition, destructive interference between incident and scattered light are not in phase which results the reduction in absorption enhancement. 

The absorption enhancement g(λ) with the optimum size of the metal nanoparticle 100 nm in their case, the forward scattering efficiency of the particle enhances due to the excitation of quadrupole resonances. 

It is well known that around 100 nm size of spherical plasmonic nanoparticles usually having the large cross-section area of scattering. 

The absorption enhancement peak can be tuned to the desired position of solar spectrum by adjusting the size of TiN nanoparticles. 

Besides this antireflection effect, constructive interference between the directly transmitted light at the Silicon interface and reradiated or scattered incident light by the nanoparticles when they are in phase which also results the absorption enhancement [16, 20, 54, 55]. 

Meanwhile the absorption peak red-shifts and also broadening in wavelength range with the increment of TiN nanoparticle diameter from 40 to 200 nm. 

The absorption enhancement spectrum g(λ) for the wavelength range 300 nm to 1100 nm as written as follows;g (λ) = QENP (λ) QEbare (λ) = PNP (λ) Pbare (λ) (3)g was calculated for each nanoparticle diameters simulated via the computation of quantum efficiencies. 

In this paper, the authors numerically studied how the plasmonic material TiN nanopar-ticles influence the light trapping and absorption enhancement in thin film silicon solar cells. 

In addition destructive interference between an incident and scattered light are not in phase and also parasitic absorption of higher order resonance modes [38, 42, 43]. 

In Figure 2, it can also observe that in the near infrared wavelength range, the absorption peaks are enhanced which influenced by forward scattering effects due to LSPR [36, 38].