Journal ArticleDOI
Transition metal complexes with bulky 4,6-di-tert-butyl-N-aryl(alkyl)-o-iminobenzoquinonato ligands: Structure, EPR and magnetism
TLDR
In this paper, a comprehensive review of homoleptic transition metal complexes of bulky bidentate N-aryl-o-iminoquinonato type ligands involving comparison with o-quinonato analogues is presented.About:
This article is published in Coordination Chemistry Reviews.The article was published on 2009-02-01. It has received 299 citations till now. The article focuses on the topics: Metal–ligand multiple bond & Transition metal thiolate complex.read more
Citations
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Radical ligand-containing single-molecule magnets
TL;DR: A survey of radical ligand-containing single-molecule magnets can be found in this article, with a brief overview of other classes of metal-ligand radical complexes that could be exploited in the design of new single molecule magnet.
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Manifestations of noninnocent ligand behavior.
TL;DR: The relationships of noninnocent ligand behavior with excited-state descriptions and perspectives regarding material properties and single-electron or multielectron reactivity are illustrated briefly.
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New avenues for ligand-mediated processes – expanding metal reactivity by the use of redox-active catechol, o-aminophenol and o-phenylenediamine ligands
TL;DR: Redox-active ligands containing catechol, o-aminophenol or o-phenylenediamine moieties show great potential to be exploited as reversible electron reservoirs, donating or accepting electrons to activate substrates and metal centers and to enable new reactivity with both early and late transition as well as main group metals.
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Redox-Active Ligand-Mediated Oxidative Addition and Reductive Elimination at Square Planar Cobalt(III): Multielectron Reactions for Cross-Coupling
TL;DR: Together these reactions comprise a complete, well-defined cycle for cobalt Negishi-like cross-coupling of alkyl halides with organozinc reagents.
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Ruthenium complexes with non-innocent ligands: Electron distribution and implications for catalysis
TL;DR: In this article, the electron distribution within Ru-NIL systems can be modulated by altering both the ancillary ligands and the NIL, and in a few cases the resultant electron distributions are exploited for catalysis.
References
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Journal ArticleDOI
Transition metal complexes of o-benzoquinone, o-semiquinone, and catecholate ligands
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Studies on charge distribution and valence tautomerism in transition metal complexes of catecholate and semiquinonate ligands
TL;DR: In this paper, the authors present an overview of recent research on transition metal complexes of quinone ligands that exhibit reversible shifts in charge distribution under equilibrium conditions, which has been considered as an example of valence tautomerism.
Journal ArticleDOI
Dinuclear Complexes with Predictable Magnetic Properties
TL;DR: In this article, the authors proposed a method for tuning the magnitude of the interaction through a given bridging network by modifying the nature of the terminal ligands, which, in some way, play the role of adjusting screws.