Journal ArticleDOI
Valence Ionization Energies of Hydrocarbons
TLDR
In this paper, the experimental valence ionisation energies of 143 hydrocarbons, CnHm, have been determined from their He (IIα) (40.80 eV) and He (Iα)(21.22 eV)-excited photoelectron spectra.Abstract:
Experimental valence ionisation energies of 143 hydrocarbons, CnHm, have been determined from their He (IIα) (40.80 eV) and He (Iα) (21.22 eV) excited photoelectron spectra. Ionization energies, usually up to 26 eV are given in tabular form for 108 hydrocarbons with n≤6, together with their (tentative) assignment. The ionization energies up to approximately 25 eV, of 35 selected hydrocarbons with 7≤n≤10, are presented by means of their He (IIα) photoelectron spectra.read more
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Charge–transfer excitation of electron donor–acceptor complexes of arylcyclopropanes
Yasutake Takahashi,Hitoshi Ohaku,Naoki Nishioka,Hiroshi Ikeda,Tsutomu Miyashi,David A. Gormin,Edwin F. Hilinski +6 more
TL;DR: In this article, electron transfer reactions of mono- and======di-arylcyclopropanes 1 and 2 have been investigated by employing charge-transfer (CT) excitation of their electron donor-acceptor (EDA) complexes with tetracyanoethylene (TCNE) or p-chloranil====== fixme(CA).
Journal ArticleDOI
Olefin Photoaddition to 4-oxoisophorone†:
TL;DR: In this article, the intramolecular photocyclization of the enedione moiety to the olefinic moiety in 1, yielding the cage-compound 3, was first described in 1964 by Cookson et al.
Journal ArticleDOI
Photoionization and photodissociation of allene clusters in a supersonic molecular beam
TL;DR: In this article, a mass spectrum of allene (1,2-propadiene) (C3H4) has been measured with synchrotron radiation from the electron storage ring BESSY.
Journal ArticleDOI
Assignment of the UV—photoelectron spectra of cyclobutene and its syn- and anti-dimers
TL;DR: In this article, through-bond and through-space effects of the UV-PES of the title compounds are discussed in relation to through-Bond and Through-Space effects.
Journal ArticleDOI
Photoemission from non-polar aromatic molecules in the gas and liquid phase.
Luca Longetti,M Randulová,J. Ojeda,Lars Mewes,Lukas Miseikis,Jakob Grilj,Alvaro Sanchez-Gonzalez,Tobias Witting,T. Siegel,Z. Diveki,F. van Mourik,Richard T. Chapman,Cephise Cacho,S Yap,John W. G. Tisch,Emma Springate,Jonathan P. Marangos,Petr Slavíček,Christopher Arrell,Christopher Arrell,Majed Chergui +20 more
TL;DR: The suitability of three trimethylbenzenes as a solvent for liquid photoelectron spectroscopy of solute species is demonstrated and the electrokinetic charging of a non-polar liquid jet is discussed.
References
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Über die Zuordnung von Wellenfunktionen und Eigenwerten zu den Einzelnen Elektronen Eines Atoms
TL;DR: In this paper, Fock's Naherungsmethode zur Behandung des quantenmechanischen Mehrelektronenproblems aufgestellten Gleichungen werden auf etwas allgemeinerer Grundlage diskutiert.
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Core-electron relaxation energies and valence-band formation of linear alkanes studied in the gas phase by means of electron spectroscopy
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High resolution molecular photoelectron spectroscopy. III. Acetylenes and aza-acetylenes
C. Baker,D. W. Turner +1 more
TL;DR: In this paper, the spectra of the 584 A (21·22 eV) photoelectron were reported for the following linear unsaturated molecules: acetylene, dideutero-acetylene, hydrogen cyanide, deuterium cyanide and diacetylene.
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Ultra-violet photoelectron data on the complete valence shells of molecules recorded using filtered 30.4 nm radiation
TL;DR: In this paper, it was shown that in many molecules the summed binding energies of the molecular orbitals built from 2s atomic orbitals may be divided up into atomic contributions which agree in magnitude with those obtained for the same atoms in other molecules.
Journal ArticleDOI
High Resolution Molecular Photoelectron Spectroscopy. I. Fine Structure in the Spectra of Hydrogen and Oxygen
TL;DR: In this paper, a photo-electron spectrometer is described which uses focusing deflexion in a radial electrostatic field for energy analysis, and an over-all limit of about 0.002 eV is deduced as the smallest attainable line width in ordinary circumstances.