Vibration-Dissociation Coupling Using Master Equations in Nonequilibrium Hypersonic Blunt-Body Flow

TLDR: In this article, Park's dissociation model was used as baseline for coupling vibration and dissociation processes, and a new master equation-based depletion model was implemented to study the effect of dissociation on population depletion in the vibrational states of the nitrogen molecule.

Abstract: Numerical simulations are presented of a steady-state hypersonic flow past a hemisphere cylinder. Two types of models, one a lumped Landau-Teller vibrational relaxation model (Landau, L., and Teller, E.) and the other a discrete state kinetic relaxation model (DSKR), were used to study effects of vibration-dissociation coupling on the flow physics. The widely used Park's dissociation model was used as baseline for coupling vibration and dissociation processes (Park, C.). For a Mach 8.6 flow, both relaxation models matched experimental data. At Mach 11.18, however, the underprediction of shock-standoff distance by both relaxation models using Park's model for dissociation coupling provided the motivation to implement a new master equation-based (DSKR) depletion model. The new model was used to study the effect of dissociation on population depletion in the vibrational states of the nitrogen molecule. The new model helps explain the restricted success of Park's dissociation model in certain temperature ranges of hypersonic flow past a blunt body. In the range of 5000-15,000 K, the new model yielded a substantial rate reduction relative to Park's equilibrium rate at lower temperatures and a consistent value at the high end