Showing papers on "Ankerite published in 2019"

Diagenetic sequences of continuously deposited tight sandstones in various environments: A case study from upper Paleozoic sandstones in the Linxing area, eastern Ordos basin, China

Abstract: An integrated analysis of the petrographic characteristics and types and distribution of diagenetic alteration in the upper Paleozoic Benxi–Taiyuan, Shanxi, and Xiashihezi Formations provides insights into the controlling factors on variations in porosity and permeability in tight sandstones (85% of the sandstone samples display porosity values <10% and 90% of the samples exhibit permeability <1 md). Diagenetic alteration includes mesogenetic compaction, cementation by dolomite, ankerite, and quartz, dissolution of feldspar, and illitization of smectite. Eodiagenesis includes compaction, development of smectite, cementation by pore-filling quartz and disordered kaolinite, and precipitation of calcite and Fe-calcite. Chlorite and quartz preserve primary pores against damage, whereas kaolinite, illite–smectite (I/S) mixed layer, and illite significantly diminish reservoir quality via permeability reduction. Chlorite and I/S content decrease abruptly as depth increases, whereas the kaolinite content remains elevated at depth because of the complete destruction of K-feldspar. The transformation from smectite to illite provides silica ions for the widely distributed quartz overgrowths. As the depositional environment transformed from fluvial (Xiashihezi) to deltaic (Shanxi) and to epicontinental (Taiyuan and Benxi), the dissolution effect increased monotonically. Feldspar dissolution is dominant in the Shanxi Formation, whereas the Benxi and Taiyuan Formations commonly contain quartz dissolution pores. The Taiyuan Formation has markedly higher porosities than in the overlying and underlying formations, caused by strong dissolution and high silica content. The decrease in porosity in the Benxi Formation results from the extensive formation of clay minerals caused by high frequency transgressions in a transitional environment.

Alteration and mineralization styles of the orogenic disseminated Zhenyuan gold deposit, southeastern Tibet: Contrast with carlin gold deposit

Abstract: Orogenic disseminated and Carlin gold deposits share much similarity in alteration and mineralization. The disseminated orogenic Zhenyuan Au deposit along the Ailaoshan shear zone, southeastern Tibet, was selected to clarify their difference. The alteration and mineralization from the different lithologies, including meta-quartz sandstone, carbonaceous slate, meta-(ultra)mafic rock, quartz porphyry and lamprophyre were researched. According to the mineral assemblage and replacement relationship in all types of host rocks, two reactions show general control on gold deposition: (1) replacement of earlier magnetite by pyrite and carbonaceous material; (2) alteration of biotite and phlogopite phenocrysts in quartz porphyry and lamprophyre into dolomite/ankerite and sericite. Despite the lamprophyre is volumetrically minor and much less fractured than other host rocks, it contains a large portion of Au reserve, indicating that the chemically active lithology has played a more important role in gold precipitation compared to structure. LA-ICP-MS analysis shows that Au mainly occurs as invisible gold in fine-grained pyrite disseminated in the host rocks, with Au content reaching to 258.95 ppm. The diagenetic core of pyrite in meta-quartz sandstone enriched in Co, Ni, Mo, Ag and Hg is wrapped by hydrothermal pyrite enriched in Cu, As, Sb, Au, Tl, Pb and Bi. Different host rock lithology has much impact on the alteration and mineralization features. Carbonate and sericite in altered lamprophyre show they have higher Mg than those developed in other of host rocks denoting that the carbonate and sericite incorporated Mg from phlogopite phenocrysts in the primary lamprophyre during alteration. The ore fluid activated the diagenetic pyrite in meta-quartz sandstone leading the hydrothermal pyrite enriched in Cu, Mo, Ag, Sb, Te, Hg, Tl, Pb and Bi, but the hydrothermal pyrite in meta-(ultra)mafic rock is enriched in Co and Ni as the meta-(ultra)mafic rock host rock contain high content of Co and Ni. However, Au and As shear similar range in both types of host rocks indicating that these two elements most likely come from the deep source fluid rather than the host rocks. It was shown in the disseminated orogenic gold deposit that similar hydrothermal alteration with mineral assemblage of carbonate (mainly dolomite and ankerite), sericite, pyrite and arsenopyrite develops in all types of host rocks. This is different from the Nevada Carlin type, in which alteration is mainly dissolution and silicification of carbonate host rock. On the other hand, Au mainly occur as invisible gold in both disseminated orogenic and Carlin gold deposits.

Magmatic-Hydrothermal Processes Associated with Rare Earth Element Enrichment in the Kangankunde Carbonatite Complex, Malawi

Abstract: Carbonatites undergo various magmatic-hydrothermal processes during their evolution that are important for the enrichment of rare earth elements (REE). This geochemical, petrographic, and multi-isotope study on the Kangankunde carbonatite, the largest light REE resource in the Chilwa Alkaline Province in Malawi, clarifies the critical stages of REE mineralization in this deposit. The δ56Fe values of most of the carbonatite lies within the magmatic field despite variations in the proportions of monazite, ankerite, and ferroan dolomite. Exsolution of a hydrothermal fluid from the carbonatite melts is evident based on the higher δ56Fe of the fenites, as well as the textural and compositional zoning in monazite. Field and petrographic observations, combined with geochemical data (REE patterns, and Fe, C, and O isotopes), suggest that the key stage of REE mineralization in the Kangankunde carbonatite was the late magmatic stage with an influence of carbothermal fluids i.e. magmatic–hydrothermal stage, when large (~200 µm), well-developed monazite crystals grew. The C and O isotope compositions of the carbonatite suggest a post-magmatic alteration by hydrothermal fluids, probably after the main REE mineralization stage, as the alteration occurs throughout the carbonatite but particularly in the dark carbonatites.

Carbonate cementation patterns, potential mass transfer, and implications for reservoir heterogeneity in Eocene tight-oil sandstones, Dongying depression, Bohai Bay Basin, China: Evidence from petrology, geochemistry, and numerical modeling

Abstract: This paper investigates transport mechanisms involving carbonate cementation in Eocene, tight-oil sandstones in Bohai Bay Basin, China, to determine potential mass transfer between adjacent mudstones and sandstones. Evidence from petrology, geochemistry, and numerical modeling suggests two generations of carbonate cementation: (1) early nonferroan calcite (formed at 28°C–41°C) and dolomite (formed at 45°C–63°C); and (2) later ferroan calcite (formed at 105°C–124°C) and ankerite (formed at 101°C–137°C). Based on a one-dimensional model for a coupled sandstone–mudstone system under low and high temperatures, different distribution patterns of carbonate cements reflect episodic concentration gradients that led to diffusive transport of bicarbonate species during progressive burial. Firstly, extensive precipitation of early nonferroan calcite followed by dolomite at or near mudstone–sandstone contacts resulted from initial concentration gradients related to different compositions in primary mineral assemblages. Secondly, introduction of aqueous CO2 from adjacent mudstones into sandstones resulted in dissolution of early nonferroan carbonates and led to diffusive transport of bicarbonate species. These bicarbonate species were incorporated with Fe2+ and subsequently reprecipitated as ferroan carbonate minerals at distances greater than 2 m (>6.6 ft) from sandstone–mudstone contacts. Therefore, short-distance diffusive transport is inferred to have been the predominant transport mechanism associated with carbonate cementation. Large-scale mass transfer between sandstones and adjacent mudstones occurred in a relatively open geochemical system on a very local scale. Numerical model results show that low porosity zones (2.6%–5.1%) exhibit coherence with high abundances of carbonate cements (13.9%–21.2%). Tightly cemented intervals were created by different generations of carbonate cementation and resulted in destruction of sandstone reservoir porosity.

Geochemical and Mineralogical Characteristics of the Middle Jurassic Coals from the Tongjialiang Mine in the Northern Datong Coalfield, Shanxi Province, China

Abstract: There is limited information available on the minerals and elements present in the Jurassic coals from Datong Coalfield. This paper investigates the geochemical and mineralogical characteristics of the Middle Jurassic coals from the Tongjialiang Mine using X-ray powder diffraction (XRD), X-ray fluorescence spectrometry (XRF), inductively coupled plasma mass spectrometry (ICP-MS), and scanning electron microscopy in combination with energy-dispersive X-ray spectrometry (SEM-EDS). No.12 coal is a low-medium volatile bituminous coal and is characterized by low ash yield content, low moisture content, and ultra-low sulfur content. Compared with Chinese coals, the Tongjialiang coals have slightly higher average percentages of MgO and P2O5, and lower average percentages of the other major oxides, including SiO2, TiO2, Al2O3, Fe2O3, CaO, MnO, Na2O, and K2O. Compared with the World hard coals, Be, Cr, Co, Ni, Ge, Sn, Ta, and W are slightly enriched in the Tongjialiang coals. The concentrations of Li, F, Sc, V, Cu, Ga, Se, Sr, Zr, Nb, Hf, Pb, Th, and U are close to the average values of the world’s hard coals. The minerals in No.12 coal mainly include quartz, kaolinite, siderite, and ankerite, along with smaller amounts of pyrite, illite, calcite, and rutile. The formation of syngenetic siderite in No.12 coal is related to the weathering of biotite in the gneiss of the Yinshan Upland. The modes of occurrence of ankerite indicate that the coals may be affected by the injection of low temperature hydrothermal fluids. It is noteworthy that a portion of epigenetic ankerite may be a product of metasomatism between syngenetic siderite and the epigenetic Fe-Mg-Ca rich hydrothermal fluids. The ratios of Al2O3/TiO2, REY (rare earth elements and yittrium) enrichment patterns, the modes of occurrence of siderite and ankerite, as well as the enriched lithophile and siderophile elements indicate that the No.12 coal may have originated from the Yinshan Upland and may also have been influenced by low temperature hydrothermal fluids that might have circulated in the coal basin.

Mineralogy and Geochemistry of the No. 5−2 High-Sulfur Coal from the Dongpo Mine, Weibei Coalfield, Shaanxi, North China, with Emphasis on Anomalies of Gallium and Lithium

Abstract: This paper reports the mineral compositions and geochemical characteristics of the No. 5−2 high-sulfur coal (Taiyuan Formation) from Dongpo Mine, Weibei Coalfield, Shaanxi, Northern China via transmitted and reflected light microscopy, scanning electron microscope equipped with an energy-dispersive X-ray spectrometer (SEM-EDS), X-ray diffraction (XRD), inductively coupled plasma mass spectrometry (ICP-MS), and X-ray fluorescence spectrometry (XRF). We also confirmed the input of intermediate-felsic volcanic ashes into the Taiyuan Formation coals in Dongpo Mine, Weibei Coalfield. The results show that Dongpo coals are enriched in Ga and Li compared to the average values for world hard coals, and they are depleted in Al2O3 compared to Chinese coals. The coal low temperature ash contains kaolinite, illite, quartz, calcite, pyrite, and to a lesser extent, chlorite, plagioclase, dolomite, ankerite, and apatite. The concentration anomalies of Ga and Li in No. 5−2 high-sulfur coal were not caused by the Benxi Formation Bauxite, but by the influence of multiple geological factors. The Middle Proterozoic moyite from the Yinshan Oldland led to the slightly higher Ga and Li contents of the No. 5−2 coal than those in world hard coals. Input of synchronization volcanic ash, injection of hydrothermal fluids during the syngenetic or early diagenetic stages and influence of seawater further contributed to the Ga and Li enrichment of the No. 5−2 coal.

Can Primary Ferroan Dolomite and Ankerite Be Precipitated? Its Implications for Formation of Submarine Methane-Derived Authigenic Carbonate (MDAC) Chimney

Abstract: Microbes can mediate the precipitation of primary dolomite under surface conditions. Meanwhile, primary dolomite mediated by microbes often contains more Fe2+ than standard dolomite in modern microbial culture experiments. Ferroan dolomite and ankerite have been regarded as secondary products. This paper reviews the process and possible mechanisms of microbial mediated precipitation of primary ferroan dolomite and/or ankerite. In the microbial geochemical Fe cycle, many dissimilatory iron-reducing bacteria (DIRB), sulfate-reducing bacteria (SRB), and methanogens can reduce Fe3+ to Fe2+, while SRB and methanogens can also promote the precipitation of primary dolomite. There are an oxygen respiration zone (ORZ), an iron reduction zone (IRZ), a sulfate reduction zone (SRZ), and a methanogenesis zone (MZ) from top to bottom in the muddy sediment diagenesis zone. DIRB in IRZ provide the lower section with Fe2+, which composes many enzymes and proteins to participate in metabolic processes of SRB and methanogens. Lastly, heterogeneous nucleation of ferroan dolomite on extracellular polymeric substances (EPS) and cell surfaces is mediated by SRB and methanogens. Exploring the origin of microbial ferroan dolomite may help to solve the “dolomite problem”.

Degradation of fracture porosity in sandstone by carbonate cement, Piceance Basin, Colorado, USA

Abstract: Cretaceous Mesaverde Group sandstones contain opening-mode fractures lined or filled by quartz and, locally, calcite cement. Fracture occlusion by quartz is controlled primarily by fracture size, age and thermal history. Fracture occlusion by calcite is highly heterogeneous, with open and calcite-sealed fractures found at adjacent depths. In the Piceance and in other basins, processes that control the distribution of these calcite cements have been uncertain. Using pore and fracture cement petrography, fluid inclusions, and isotopic and elemental analysis, we show that host-rock calcite distribution and remobilization govern porosity degradation and occlusion of fractures >1 mm wide by calcite. Fluid-inclusion analyses indicate calcite cement precipitation at 135–165°C. 87Sr/86Sr ratios of calcite and the presence of porous albite suggest that detrital feldspar albitization released Ca2+, driving carbonate cement precipitation. In host rock, both albite and calcite content decreases with depth along with greater fracture porosity preservation. Although the cement sequence Fe-dolomite → ankerite → calcite is widespread, Fe-dolomite and ankerite occur as host-rock cements only, with detrital dolomite as preferred precipitation substrate. We find that the rock-mass calcite cement content correlates with fracture degradation and occlusion, and can be used to accurately predict where wide fractures are sealed or open. Thematic collection: This article is part of the Naturally Fractured Reservoirs collection available at: https://www.lyellcollection.org/cc/naturally-fractured-reservoirs

Thermodynamic Modelling and Experimental Validation of CO2 Mineral Sequestration in Mandla Basalt of the Eastern Deccan Volcanic Province, India

Abstract: Deccan basalt contains primary silicates rich in Ca, Mg, and Fe ions, suitable for CO2 sequestration. Previous, basalt-water-CO2 interaction studies were focused on other than Deccan basalt types. However, such studies on the Deccan basalt are rare. Thus, present basalt-CO2 water saturated interaction modelling under hydrothermal-like conditions was carried out on the Deccan basalt of the Mandla area to understand apposite pCO2 and time parameters. Modelling results were further validated by experiments run in a laboratory time framework. Present results show negative entropy (ΔS) and enthalpy (ΔfH) that suggest feasibility of plagioclase, pyroxene and magnetite dissolution. Obtained negative Gibb’s free energy (ΔfG), ΔfH and ΔS values for calcite, dolomite and magnesite indicate spontaneous reaction, whereas, positive ΔfG and negative ΔfH and ΔS values of the siderite suggest non-spontaneous and opposing reactions. Calcite is the first carbonate mineral to form, but, at a faster rate. Magnetite dissolution begins after a time lag (not initiated along with the plagioclase and pyroxene). X-ray Powder Diffraction results of post-experiment residues revealed formation of calcite, aragonite, ankerite, huntite, siderite, smectite, chlorite, smectite/chlorite mixed layers and chabazite. Scanning electron microscopic images show tiny calcite crystal growth over the larger calcite crystal and incipient-disordered calcite with imperfections on crystal faces. Thus, basalt carbonation is mainly controlled by time, but temperature, pCO2 and pH played sub-ordinate role. Largely, thermodynamic models do not agree well with the experimental results as numerical models indicate larger carbonate growth. Additionally, transition state theory based models work well to predict dissolution rates for most of the minerals, but, they overpredict growth of the secondary minerals.

Understanding of Long-Term CO2-Brine-Rock Geochemical Reactions Using Numerical Modeling and Natural Analogue Study

Abstract: To further understand the interactions of CO2-brine-rock at geological time scales, in this study, a 1D reactive transport model of CO2 intrusion into sandstone of the Longtan Formation (P2l) in the Huangqiao area, China, was constructed based on site-specific data. The simulation time is consistent with the retention time of CO2 in the Longtan sandstone Formation and is set to 20 Ma. The reactive transport model is calibrated and revised using the measured data for sandstone samples from Well X3 (i.e., the natural analogue). By comparing the simulation results with measured data for the natural analogue, the long-term geochemical reactions are investigated. The simulation results indicate that the brine-rock interactions induced by CO2 can be roughly divided into two stages. First, susceptible minerals (e.g., chlorite, ankerite, calcite, and feldspar minerals) dissolve rapidly under acidic conditions formed by the dissolution of CO2. The precipitation of siderite is facilitated by the dissolution of ankerite and chlorite. Smectite-Ca and dawsonite precipitate due to the dissolution of anorthite and albite, respectively. Dawsonite begins to convert into smectite-Na when albite is completely dissolved. As the reactions continue, intermediate products (i.e., illite, smectite-Na, and smectite-Ca) generated in the first stage become the reactants and subsequently react with CO2 and brine. These three clay minerals are not stable under acidic conditions and transform into kaolinite and paragenetic quartz in the later stage of reaction. Comparing the simulation results of the Base Case with the measured data for the natural analogue and inspired by previous studies, the scour of kaolinite is supposed to have occurred in this region and is considered in the revised model by introducing a coefficient of the scour of kaolinite (i.e., Case 2). The simulation results of Case 2 fit well with the measured data on mineral assemblage, and the trend of the sandstone porosity growth caused by the CO2-brine-rock reaction is captured by our simulation results. The combination of numerical simulation and natural analogue study indicates that the joint effects of long-term CO2-brine-rock reactions and scour of kaolinite increase the pore space of the host rock and result in an increase in quartz content in the sandstone.

Synthesis and Characterization of Precipitated CaCO3 from Ankerite Prepared by Bubbling Method

Abstract: This study investigates characteristics of precipitated calcium carbonate (PCC) synthesized from ankerite prepared by bubbling method. Ankerite obtained from Ambunten, Sumenep (East Java, Indonesia). The bubbling method was used CO2 gas with the flow rate of 8 L/min. The crystalline phase of PCC was characterized by X-ray diffraction (XRD), the functional group CaCO3 was analyzed using infrared spectroscopy equipped with Fourier Transform (FTIR). The morphological of PCC was observed by Scanning Electron Microscope (SEM). PCC powder formed has a calcite phase based on XRD test result with characteristic 2θ at 29.33∘ . The FTIR spectra show the presence of calcite at 873 cm−1 and 712 cm−1. Observation by SEM shows the morphology of calcite is rhombohedral cubic. Keywords: Ankerite, bubbling method, precipitated CaCO3

Experimental and Modelled Reactions of CO2 and SO2 with Core from a Low Salinity Aquifer Overlying a Target CO2 Storage Complex

Abstract: CO2-induced reactions in low salinity aquifers overlying CO2 storage sites are of interest to understand potential reactions or impacts in the possible case of a leak. Previous investigations of overlying aquifers in the context of CO2 storage have focused on pure CO2 streams, however captured industrial CO2 streams may contain ancillary gases, including SO2, O2, NOx, H2S, N2, etc., some of which may be more reactive than CO2 when dissolved in formation water. Eight drill cores from two wells in a low salinity sandstone aquifer that overlies a target CO2 storage complex are characterised for porosity (helium, mercury injection, or micro CT), permeability, and mineral content. The eight Hutton Sandstone cores are variable with porosities of 5.2–19.6%, including carbonaceous mudstones, calcite cemented sandstones, and quartz rich sandstones, common lithologies that may be found generally in overlying aquifers of CO2 storage sites. A chlorite rich sandstone was experimentally reacted with CO2 and low concentrations of SO2 to investigate the potential reactions and possible mineral trapping in the unlikely event of a leak. Micro CT characterisation before and after the reaction indicated no significant change in porosity, although some fines movement was observed that could affect permeability. Dissolved concentrations of Fe, Ca, Mn, Cr, Mg, Rb, Li, Zn, etc., increased during the reaction, including from dissolution of chlorite and trace amounts of ankerite. After ~40 days dissolved concentrations including Fe, Zn, Al, Ba, As and Cr decreased. Chlorite was corroded, and Fe-rich precipitates mainly Fe-Cr oxides were observed to be precipitated on rock surfaces after experimental reaction. Concentrations of Rb and Li increased steadily and deserve further investigation as potential monitoring indicators for a leak. The reaction of chlorite rich sandstone with CO2 and SO2 was geochemically modelled over 10 years, with mainly chlorite alteration to siderite mineral trapping 1.55 kg/m3 of CO2 and removing dissolved Fe from solution. Kaolinite and chalcedony precipitation was also predicted, with minor pyrite precipitation trapping SO2, however no changes to porosity were predicted.