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Arnold L. Rheingold
Researcher at University of California, San Diego
Publications - 1415
Citations - 35872
Arnold L. Rheingold is an academic researcher from University of California, San Diego. The author has contributed to research in topics: Ligand & Crystal structure. The author has an hindex of 75, co-authored 1392 publications receiving 33260 citations. Previous affiliations of Arnold L. Rheingold include Scripps Research Institute & University of Cambridge.
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Synthesis and characterization of a family of solvated sodium aryloxide compounds
Timothy J. Boyle,Andrew T. Velazquez,Daniel T. Yonemoto,Todd M. Alam,Curtis E. Moore,Arnold L. Rheingold +5 more
TL;DR: In this paper, a family of solvated sodium alkoxides ([(solv)xNa(OR)]n) was synthesized from the reaction of sodium bis(trimethylsilyl)amide with a series of sterically varied aryl alcohols.
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A Well-Defined Isocyano Analogue of HCo(CO)4. 2: Relative Brønsted Acidity as a Function of Isocyanide Ligation
TL;DR: In this article, the effect of substituting an isocyanide for a CO ligand on the acidity of the Co-H unit in HCoL4 complexes was investigated.
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Syntheses of water-soluble N-donor ligands for aqueous catalysis using green, Michael-type addition reactions
Hong-Chang Liang,Sanjib K. Das,Juan R. Galvan,Suzanne M. Sato,Yonglian Zhang,Lev N. Zakharov,Arnold L. Rheingold +6 more
TL;DR: In this article, a new route for synthesizing sulfonate-containing N-donor ligands has been developed involving the Michael-type addition reaction of primary or secondary amines with sodium vinylsulfonate in water.
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Conformational analysis and assignments of relative stereocenter configurations in fluoroalkyl-iridium complexes using 19F[1H] HOESY experiments. Comparison with solid-state X-ray structural results.
TL;DR: Solution conformations about the metal-carbon bond of the secondary fluoroalkyl ligands in iridium complexes and relative stereocenter configuration assignments have been obtained using (19)F[(1)H] HOESY and correlated with the X-ray structure for the major diastereomer of 4.
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Solution Dynamics of Redox Noninnocent Nitrosoarene Ligands: Mapping the Electronic Criteria for the Formation of Persistent Metal-Coordinated Nitroxide Radicals.
Brandon R. Barnett,Liezel A. Labios,Curtis E. Moore,Jason England,Arnold L. Rheingold,Karl Wieghardt,Joshua S. Figueroa +6 more
TL;DR: The results presented here highlight the inherent instability of metal-coordinated nitroxide radicals and suggest a general synthetic strategy for kinetically stabilizing these species in solution.