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Arnold L. Rheingold
Researcher at University of California, San Diego
Publications - 1415
Citations - 35872
Arnold L. Rheingold is an academic researcher from University of California, San Diego. The author has contributed to research in topics: Ligand & Crystal structure. The author has an hindex of 75, co-authored 1392 publications receiving 33260 citations. Previous affiliations of Arnold L. Rheingold include Scripps Research Institute & University of Cambridge.
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Journal ArticleDOI
Chiral Palladium(0) trans -Stilbene Complexes: Synthesis, Structure, and Oxidative Addition of Phenyl Iodide
Tim J. Brunker,Natalia F. Blank,Jillian R. Moncarz,Corina Scriban,Brian J. Anderson,David S. Glueck,Lev N. Zakharov,James A. Golen,Roger D. Sommer,Christopher D. Incarvito,Arnold L. Rheingold +10 more
TL;DR: The rate of oxidative addition of phenyl iodide to the stilbene complexes, which gave Pd(diphos*)(Ph)(I), depended on the ligand and was markedly faster than oxidative addition to mixtures of Pd (dba)2 and diphos*.
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Synthesis, structure, and properties of chiral titanium and zirconium complexes bearing biaryl strapped substituted cyclopentadienyl ligands
William W. Ellis,T. Keith Hollis,W. Odenkirk,John Whelan,Robert L. Ostrander,Arnold L. Rheingold,B. Bosnich +6 more
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Deprotonated thioamides as thiolate S-donor ligands with a high tendency to avoid M-S-M bridge formation: crystal and molecular structure of bis(2-hydroxy-5-methylacetophenone N,N-dimethylthiosemicarbazonato)dinickel
TL;DR: The crystal structure of [Ni(tmtssA] as discussed by the authors has a phenolate O-bridge rather than the expected imino thiolate S-bridge, which implies that deprotonated thioamides have a much lower bridging tendency than alkane- or arenethiolates.
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A reversible chemical reaction in a single crystal. The dimerization of .eta.5-cyclopentadienyl(o-dithiobenzene)cobalt [CpCo(S2C6H4-o)]
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[Re(η5-C5H5)(CO)3]+ Family of 17-Electron Compounds: Monomer/Dimer Equilibria and Other Reactions
Daesung Chong,Derek R. Laws,Ayman Nafady,Paulo J. Costa,Arnold L. Rheingold,Maria José Calhorda,W. E. Geiger +6 more
TL;DR: DFT calculations show that the SOMO of 1+ is highly Re-based and hybridized to point away from the metal, thereby facilitating the dimerization process and other reactions of the Re(II) center.