D
Donna G. Blackmond
Researcher at Scripps Health
Publications - 218
Citations - 13584
Donna G. Blackmond is an academic researcher from Scripps Health. The author has contributed to research in topics: Catalysis & Homochirality. The author has an hindex of 62, co-authored 210 publications receiving 12046 citations. Previous affiliations of Donna G. Blackmond include Scripps Research Institute & Max Planck Society.
Papers
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Journal ArticleDOI
Kinetic Analysis of Catalytic Organic Reactions Using a Temperature Scanning Protocol
Olivia P. Schmidt,Anne-Marie R. Dechert-Schmitt,Michelle R. Garnsey,Hanna M. Wisniewska,Donna G. Blackmond +4 more
TL;DR: In this paper, the authors describe the development of temperature scanning reaction progress protocol for batch reactions, which enables the expansion of in-situ kinetic studies from a focus on isothermal concentration profiles to include reaction temperature as a parameter for rapid kinetic and mechanistic analysis.
Book ChapterDOI
Modeling of kinetically coupled selective hydrogenation reactions: Kinetic rationalization of pressure effects on enantioselectivity
TL;DR: In this paper, a two-site, two-step kinetic model is proposed to rationalize the observed effects of solution hydrogen concentration on enantioselectivity in the asymmetric hydrogenation of ethyl pyruvate using a dihydrocinchonidine-modified heterogeneous Pt catalyst.
Journal ArticleDOI
Mechanistic Insights into Anomalous Kinetic Behaviour in the Hydrogenation of a Substituted Nitrobenzene
TL;DR: In this paper, a combination of two reaction mechanisms was proposed for the Pd-catalyzed hydrogenation of 4-nitroacetophenone, one dominating at high substrate concentrations and another dominating at the low surface coverage of substrate found at the end of the reaction.
Journal ArticleDOI
In situ FTIR spectroscopic monitoring of electrochemically controlled organic reactions in a recycle reactor
TL;DR: An electrochemical cell coupled with a recycle loop through a transmission FTIR cell is employed in studies of two free radical organic reactions, the oxidation of allylic alcohols and the trifluoromethylation of heteroarenes.
Journal ArticleDOI
The nature of Rh-CO interactions on SAPO-5-supported Rh
TL;DR: In this paper, the formation of a high-frequency dicarbonyl species that depended on time and temperature of adsorption as well as on the presence of oxygen was investigated.