D
Donna G. Blackmond
Researcher at Scripps Health
Publications - 218
Citations - 13584
Donna G. Blackmond is an academic researcher from Scripps Health. The author has contributed to research in topics: Catalysis & Homochirality. The author has an hindex of 62, co-authored 210 publications receiving 12046 citations. Previous affiliations of Donna G. Blackmond include Scripps Research Institute & Max Planck Society.
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Journal ArticleDOI
Quantitative determination of the catalysed asymmetric transfer hydrogenation of 1-methyl-6,7-dimethoxy-3,4-dihydroisoquinoline using in situ FTIR and multivariate curve resolution
TL;DR: In this paper, multivariate curve resolution with alternating least squares (MCR-ALS) was applied to in situ infrared measurements of rhodium catalysed asymmetric transfer hydrogenation (CATHy) reaction of 1-methyl-6,7-dimethoxy-3,4-dihydroisoquinoline to provide an alternative to the traditional method of HPLC analysis.
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Nitroethane as a probe molecule for CO hydrogenation over Ru/SiO2
TL;DR: In this article, the role of C{sub 2} surface species may play a special role in chain growth initiation during hydrocarbon formation on Ru catalysts and the values of the chain growth probabilities, α, and the olefin-to-paraffin molar ratios for the C2 and C3 fractions in the products are also listed.
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Insights into the Role of Transient Chiral Mediators and Pyridone Ligands in Asymmetric Pd-Catalyzed C-H Functionalization.
TL;DR: The unprecedented features of 2-pyridone ligands in asymmetric 1,2 migratory insertion, and norbornene as a transient chiral me-diator in relay chemistry, provide new insights into this ligand scaffold for future developments in stereoselective transition-metal catalyzed C-H functionalization.
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In situ kinetic studies of the trifluoromethylation of caffeine with Zn(SO2CF3)2
TL;DR: In this article, in situ monitoring of trifluoromethylation of caffeine using Zn(SO2CF3)2 provides mechanistic insight into this important reaction.
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Dynamic Ligand Exchange as a Mechanistic Probe in Pd-Catalyzed Enantioselective C–H Functionalization Reactions Using Monoprotected Amino Acid Ligands
David E. Hill,Katherine L. Bay,Yun-Fang Yang,R. Erik Plata,Ryosuke Takise,Kendall N. Houk,Jin-Quan Yu,Donna G. Blackmond +7 more
TL;DR: Monitoring the temporal change in product enantiomeric excess after addition of the opposite enantiomers of the ligand during the reaction provides a means of probing dynamic ligand exchange in enantioselective C-H iodination catalyzed by Pd with monoprotected amino acid ligands (MPAAs).