D
Donna G. Blackmond
Researcher at Scripps Health
Publications - 218
Citations - 13584
Donna G. Blackmond is an academic researcher from Scripps Health. The author has contributed to research in topics: Catalysis & Homochirality. The author has an hindex of 62, co-authored 210 publications receiving 12046 citations. Previous affiliations of Donna G. Blackmond include Scripps Research Institute & Max Planck Society.
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Journal ArticleDOI
Mechanistic Insights into the Vanadium-Catalyzed Achmatowicz Rearrangement of Furfurol
Yining Ji,Tamas Benkovics,Gregory L. Beutner,Chris Sfouggatakis,Martin D. Eastgate,Donna G. Blackmond +5 more
TL;DR: The development of improved reaction conditions and an interrogation into the fate of the metal center during the Achmatowicz rearrangement are described, allowing for easy isolation of product 3 and synthetically important derivatives.
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Mechanistic Rationalization of Unusual Sigmoidal Kinetic Profiles in the Machetti–De Sarlo Cycloaddition Reaction
TL;DR: Unusual sigmoidal kinetic profiles in the Machetti-De Sarlo base-catalyzed 1,3-dipolar cycloaddition of acrylamide to N-methylnitroacetamide are rationalized and a dual role is uncovered in which a substrate acts as a precursor to catalyze its own reaction.
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Electrochemical borylation of carboxylic acids.
TL;DR: In this article, a simple electrochemically mediated method for the conversion of alkyl carboxylic acids to their borylated congeners is presented, which features an undivided cell setup with inexpensive carbon-based electrodes and exhibits a broad substrate scope and scalability in both flow and batch reactors.
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Kinetic aspects of non-linear effects in asymmetric synthesis, catalysis, and autocatalysis
TL;DR: In this article, the Kagan ML n models developed for rationalizing nonlinear effects of catalyst enantiopurity have become a valuable mechanistic tool for probing complex asymmetric catalytic reactions.