P
Peter S. White
Researcher at University of North Carolina at Chapel Hill
Publications - 641
Citations - 36290
Peter S. White is an academic researcher from University of North Carolina at Chapel Hill. The author has contributed to research in topics: Crystal structure & Ligand. The author has an hindex of 72, co-authored 637 publications receiving 34509 citations. Previous affiliations of Peter S. White include National Park Service & University of Chicago.
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Acid-assisted reductive elimination as a route to platinum(II) products from platinum(IV) tris(pyrazolyl)borate reagents
TL;DR: A series of chiral cationic platinum(II) complexes of the type [κ2-((Hpz*)BHPz*2)Pt(R)(L)][BAr‘4] (R = Me, L = MeCN (3), tBuNC (4), py (5), CO (6), CH2CH2 (7), PMe2Ph (8), R = Ph, L=MeCN (10); pz* = tetrakis(3,5-trifluoromethyl
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Synthesis and Investigation of [Cp*(PMe3)Rh(H)(H2)]+ and Its Partially Deuterated and Tritiated Isotopomers: Evidence for a Hydride/Dihydrogen Structure
Felicia L. Taw,Heather Mellows,Peter S. White,Frederick J. Hollander,Robert G. Bergman,Maurice Brookhart,D. Michael Heinekey +6 more
TL;DR: The structure of Complex 3 contains two terminal hydrides and one bridging hydride ligand which exchange with a barrier of 9.1 kcal/mol as observed by (1)H NMR spectroscopy.
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Synthesis and characterization of chiral (hydridotris(3,5-dimethylpyrazolyl)borato)tungsten(II) alkyne complexes
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Evidence that temperate east north american evergreen woody plants follow corner's rules
TL;DR: Coener's rules, first developed for tropical trees, predict a spectrum of woody plant forms, from ones with small leaves, thin twigs (first-year shoots) and many branches, to ones with larger Waves, thick twigs and few branches.
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Reactions of Anilines and Benzamides with a 14-Electron Iridium(I) Bis(phosphinite) Complex: N−H Oxidative Addition versus Lewis Base Coordination
TL;DR: Kinetic analysis of these reactions for 14e,f,g bearing electron-withdrawing aryl groups shows the rate is independent of ethylene concentration, while low temperature studies using p-chloroaniline show that the Ir(I) sigma-complex is the kinetic product of reaction and is likely the precursor to the Ir (III) oxidative addition adduct.