Fundamentals of Plasmonics.- Electromagnetics of Metals.- Surface Plasmon Polaritons at Metal / Insulator Interfaces.- Excitation of Surface Plasmon Polaritons at Planar Interfaces.- Imaging Surface Plasmon Polariton Propagation.- Localized Surface Plasmons.- Electromagnetic Surface Modes at Low Frequencies.- Applications.- Plasmon Waveguides.- Transmission of Radiation Through Apertures and Films.- Enhancement of Emissive Processes and Nonlinearities.- Spectroscopy and Sensing.- Metamaterials and Imaging with Surface Plasmon Polaritons.- Concluding Remarks.

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Plasmonics: Fundamentals and Applications

From molecules to crystal engineering: supramolecular isomerism and polymorphism in network solids.

This critical review will be of interest to the experts in porous solids (including catalysis), but also solid state chemists and physicists. It presents the state-of-the-art on hybrid porous solids, their advantages, their new routes of synthesis, the structural concepts useful for their ‘design’, aiming at reaching very large pores. Their dynamic properties and the possibility of predicting their structure are described. The large tunability of the pore size leads to unprecedented properties and applications. They concern adsorption of species, storage and delivery and the physical properties of the dense phases. (323 references)

Hybrid porous solids: past, present, future

Since the first application of the surface plasmon resonance (SPR) phenomenon for sensing almost two decades ago, this method has made great strides both in terms of instrumentation development and applications. SPR sensor technology has been commercialized and SPR biosensors have become a central tool for characterizing and quantifying biomolecular interactions. This paper attempts to review the major developments in SPR technology. Main application areas are outlined and examples of applications of SPR sensor technology are presented. Future prospects of SPR sensor technology are discussed.

Surface plasmon resonance sensors: review

Optical tweezers use the forces exerted by a strongly focused beam of light to trap and move objects ranging in size from tens of nanometres to tens of micrometres. Since their introduction in 1986, the optical tweezer has become an important tool for research in the fields of biology, physical chemistry and soft condensed matter physics. Recent advances promise to take optical tweezers out of the laboratory and into the mainstream of manufacturing and diagnostics; they may even become consumer products. The next generation of single-beam optical traps offers revolutionary new opportunities for fundamental and applied research.

http://physics.nyu.edu/grierlab/nreview2c/nreview2c.pdf

A revolution in optical manipulation

The morphology and size dependence of silver microstructures in a novel microfabrication process, fatty salts-assisted multiphoton photoreduction (MPR), were investigated by using the fatty salts with different carbon chain lengths (Cn: n=4,5,7,9) under varied powers and irradiation times of a femtosecond near-infrared laser with the wavelength of 800 nm. Not only the feature size of the silver structures was reduced but also the surface smoothness was improved by increasing the chain length of the fatty salts. The highest resolution of a silver line was obtained to be 285 nm, which exceeded the diffraction limit. The fatty salts-assisted MPR microfabrication approach would provide an efficient protocol for fabricating metallic micro/nanostructures with fine morphology and size and could play an important role in the fabrication of the metallic micro/nanostructures for applications in photonics and electronics as well as in sensors.

Morphology and size dependence of silver microstructures in fatty salts-assisted multiphoton photoreduction microfabrication

Single-walled carbon nanotubes (SWCNTs) are promising for a staggering array of applications, ranging from thin-film electronics to sporting goods. Unfortunately, bulk manufacture yields a mixture of nanotubes with different properties, and separating them is very difficult. The authors have found that the tiny optical force from a laser beam can be used to sort SWCNTs according to their sizes and electronic properties. By tuning the laser to an appropriate color, any of multiple types of nanotubes can be selected and separated from a mixture---a discovery that could be the key to realizing new and higher quality applications for this wonder material.

Chirality-Selective Optical Scattering Force on Single-Walled Carbon Nanotubes

A read-and-write, randomly accessible, multilayered optical memory with a Bi(12) SiO(20) crystal as the medium is demonstrated. Data are recorded in the crystal as an absorption change that is due to the photochromic effect. These data are successfully recorded, read, and selectively erased in five layers in the crystal. The axial-separation distance between neighboring layers is 30 μm, and the lateral distance between bits is 5 μm. Selective bit erasure of the data is accomplished by illumination of the recorded bit datum with He-Ne laser light. To our knowledge, this is the first successful demonstration of the selective optical erasure of the photochromic effect in a BSO crystal.

Randomly accessible, multilayered optical memory with a Bi(12)SiO(20) crystal

We demonstrate high-resolution fluorescence imaging in biological samples by saturated excitation (SAX) microscopy. In this technique, we saturate the population of fluorescence molecules at the excited state with high excitation intensity to induce strong nonlinear fluorescence responses in the center of laser focus, which contributes the improvement of the spatial resolution in three dimensions. Using SAX microscopy, we observed stained microtubules in HeLa cells with improved spatial resolution. We also measured the relation of the fluorescence and excitation intensity with several kinds of fluorescence dyes and, in the results, confirmed that SAX microscopy has the potential to observe any kind of fluorescence samples in current usage.

/pdf/beyond-the-diffraction-limit-biological-imaging-by-saturated-saeklo54kv.pdf

Satoshi Kawata

Papers

Morphology and size dependence of silver microstructures in fatty salts-assisted multiphoton photoreduction microfabrication

Chirality-Selective Optical Scattering Force on Single-Walled Carbon Nanotubes

Randomly accessible, multilayered optical memory with a Bi(12)SiO(20) crystal

Beyond the diffraction-limit biological imaging by saturated excitation microscopy.

Three‐Dimensional Nanonetwork Assembled in a Photopolymerized Rod Array