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Showing papers by "University of Mons published in 1994"


Journal ArticleDOI
29 Jul 1994-Science
TL;DR: These derivative relations provide a unified picture of the dependence of the polarizability and hyperpolarizabilities on the structure in linear polymethine dyes and allow for predictions of structure-property relations of higher order hyperp polarizabilities.
Abstract: An internal or external electric field F can drive the chemical structure, bond order alternation, and electronic structure of linear polymethine dyes from a neutral, bond-alternated, polyene-like structure, through a cyanine-like structure, and ultimately to a zwitterionic (charge-separated) bond-alternated structure. As the structure evolves under the influence of F, the linear polarizability α, the first hyperpolarizability β, and the second hyperpolarizability γ are seen to be derivatives, with respect to F, of their next lower order polarization (for α) or polarizability (for β and γ). These derivative relations provide a unified picture of the dependence of the polarizability and hyperpolarizabilities on the structure in linear polymethine dyes. In addition, they allow for predictions of structure-property relations of higher order hyperpolarizabilities.

585 citations


Journal ArticleDOI
TL;DR: In this article, the influence of substitution by various donor and acceptor groups onto the phenyl rings and/or the vinylene units of poly(paraphenylene vinylene) and poly(polyparaphhenylene) was investigated theoretically.

218 citations


Journal ArticleDOI
TL;DR: In this article, four new quark-quark potentials were developed in the framework of the nonrelativistic quark model (NRQM), which can reproduce quite well the spectra of mesons and baryons.
Abstract: We present four new quark-quark potentials, developed in the framework of the nonrelativistic quark model (NRQM), which can reproduce quite well the spectra of mesons and baryons. They contain a central part which is of type “Coulomb+linear” or “Coulomb +2/3-power”, and a strong but smooth hyperfine term. With these four potentials and the one proposed by Bhaduri et al., we have calculated masses and decay properties of some interesting diquonia (q2q−2 mesons). We have not found appreciable difference between the results of the five potentials considered, indicating that the properties of diquonia are, to a large extent, potential-independent in the NRQM.

119 citations


Journal ArticleDOI
TL;DR: In this article, the authors used the intermediate neglect of differential overlap method coupled with a single configuration interaction technique to calculate the optical absorption spectra of oligomers of poly(paraphenylene vinylene), PPV and their dimethoxy-substituted derivatives.

96 citations


Journal ArticleDOI
TL;DR: The aim of the present study was to test the respective contributions of the NPH, of the rostral part of the MVN, which contains most second-order vestibular neurons, and of the central part ofThe MVN to the central integrator, and to inactivate each of these three zones in the cat's brain.
Abstract: 1 For horizontal eye movements, previous observations led to the hypothesis that the legendary neural integrator necessary for correct gaze holding, adequate vestibuloocular reflex (VOR), and optokinetic nystagmus, was located in the region of the complex formed by the nucleus prepositus hypoglossi (NPH) and the medial vestibular nucleus (MVN) 2 The aim of the present study was to test the respective contributions of the NPH, of the rostral part of the MVN, which contains most second-order vestibular neurons, and of the central part of the MVN to the horizontal integrator 3 An injection of muscimol was used to inactivate each of these three zones in the cat's brain Muscimol is a gamma-aminobutyric acid (GABA) agonist By binding to GABAA receptors, it induces a hyperpolarization of the neurons that nullifies their activity Muscimol was injected into the brain stem of the alert cat through a micropipette by an air pressure system 4 The search coil technique was used to record spontaneous eye movements and the VOR induced by rotating a turntable at a constant velocity VOR was analyzed by a new method: transient analysis of vestibular nystagmus 5 A unilateral injection of muscimol into the NPH induced a bilateral gaze-holding failure: saccades were followed by a centripetal postsaccadic drift A vestibular imbalance was also present but it was moderate and variable The VOR responses were distorted drastically Through transient analysis of vestibular nystagmus, that distortion was revealed to be due more to a failure of the neural integrator than to an alteration of the vestibular input to the neural integrator The responses to a rotation either toward the injected side or in the opposite direction were asymmetrical The direction of that asymmetry was variable 6 A unilateral injection of muscimol into the rostral part of the MVN caused a vestibular imbalance: in complete darkness, a nystagmus appeared, whose linear slow phases were directed toward the side of injection 7 A unilateral injection of muscimol into the central part of the MVN induced a syndrome where a severe bilateral gaze-holding failure was combined with a vestibular imbalance In the light, saccades were followed by a bilateral centripetal postsaccadic drift In complete darkness, a nystagmus was observed, whose curved slow phases were directed towards the side of injection The VOR responses were distorted drastically Here again, that distortion was revealed by our analysis to be due more to a failure of the neural integrator than to an alteration of the vestibular input to the neural integrator(ABSTRACT TRUNCATED AT 400 WORDS)

94 citations


Journal ArticleDOI
TL;DR: Hypermetria, a classical cerebellar symptom designating the overshoot observed when a patient is asked to make a very fast and accurate movement, was found to be increased by artificially increasing the inertia of the moving hand.
Abstract: Hypermetria is a classical cerebellar symptom designating the overshoot observed when a patient is asked to make a very fast and accurate movement. The movement studied here was wrist flexion. Hypermetria was found to be increased by artificially increasing the inertia of the moving hand. A normal subject adapted himself to increasing inertia by increasing both his agonist activity (the launching force) and its antagonist activity (the braking force). In the same circumstances, a patient with symptoms of cerebellar system dysfunction was found to be able to increase his agonist activity but not his antagonist activity.

91 citations


Journal ArticleDOI
TL;DR: In this article, the spin asymmetry in the scattering of 100 GeV longitudinally-polarized muons on transversely polarized protons was measured and the asymmetry was found to be compatible with zero in the kinematic range $0.006

77 citations


Journal ArticleDOI
Guy Cheron1, Thierry Piette, A Thiriaux, Jean Jacquy, Emile Godaux1 
TL;DR: It is demonstrated that the movement gating ability of the PD patient is preserved in spite of the reduced amplitude of the frontal N30, and this result suggests that the specific change in the frontalN30 in PD is not the consequence of a continuous gating of the sensory inflow by a motor corollary discharge.

71 citations


Journal ArticleDOI
TL;DR: In this paper, the relaxation process of photoexcited states in oligomers and long chains of poly(paraphenylene vinylene), PPV was investigated within a theoretical approach including both electron-phonon and electron-electron interaction terms.

68 citations


Journal ArticleDOI
Bernardo Adeva, Shafqat Ahmad, A. Arvidson, B. Badelek  +148 moreInstitutions (21)
TL;DR: In this article, the first moment of the neutron spin dependent structure function was evaluated using all available data and the Bjorken sum rule was confirmed within an experimental uncertainty of 17%.

62 citations


Journal ArticleDOI
TL;DR: The early stages of metal/polymer interface formation between calcium and poly(2,5-diheptyl-p-phenylenevinylene) (PDHPV) have been studied using both X-ray photoelectron spectroscopy and ultraviolet photo-electron Spectroscopy as discussed by the authors.


Journal ArticleDOI
TL;DR: The intrinsic morphology of the tongue is rather similar to that previously described for iguanids, but fibers of M. verticalis encircles ventrally the lingual process could act in tongue protrusion as previously suggested for agamids.
Abstract: The anatomy of the hyo-lingual apparatus in the iguanid lizard Oplurus cuvieri has been studied by light microscopy and scanning electron microscopy. Four areas were observed on the dorsal lingual epithelium of the lizard. Tongue tips are covered with a smooth epithelium. Closely packed flattened and cylindriform papillae cover the foretongue. The surface of the midtongue bears an unpapillose epithelium. Short conical papillae are arranged on the two lateral posterior bundles of the tongue. At high magnification, microvilli and microridges are widely distributed over the surface of the papillae. The epithelium of the papillae is composed of cells filled with secretory granules. Each surface plays successive roles during food ingestion, intra-buccal transport, and swallowing. The mucous interpapillary spaces would serve the adherence between the tongue and the food, the smooth epithelium of the midtongue should facilitate movements of the prey toward the pharynx, and conical papillae of the hindtongue present a rough surface which should act on the prey during the swallowing phase. The intrinsic morphology of the tongue is rather similar to that previously described for iguanids, but fibers of M. verticalis encircles ventrally the lingual process. These fibers could act in tongue protrusion as previously suggested for agamids. The morphology and function of the extrinsic tongue musculature and the hyoid musculature, analysed by electrical stimulations, are similar to the previous descriptions in iguanids and agamids either for feeding or displaying functions.

Journal ArticleDOI
TL;DR: In this article, the chemical and electronic structure of the interface between aluminum and several proto-typical conjugated systems is investigated with a combined experimental and theoretical approach, which consists of following the evolution of the polymer surface during the early stages of aluminum deposition, with X-ray and Ultraviolet Photoelectron Spectroscopies (XPS, UPS).

Journal ArticleDOI
TL;DR: In this paper, the Long Term Average Spectrum (LTAS) was used as an acoustical measure of voice quality, and within-speaker comparisons of two kinds were performed: the between-language (Catalan/Spanish) and the within-language ones.

Journal ArticleDOI
24 Jul 1994
TL;DR: In this paper, the interaction of low-work function metals (Al, Ca) with the surface of conjugated polymers or model oligomer molecules with a combined experimental and theoretical approach is investigated.
Abstract: The chemical nature and the electronic structure of metal/conjugated polymer interfaces are investigated in the context of polymer-based light-emitting diodes. We consider the interaction of low-workfunction metals (Al, Ca) with the surface of conjugated polymers or model oligomer molecules with a combined experimental and theoretical approach. The early stages of the interface formation are followed with X-ray and ultraviolet photoelectron spectroscopies and the experimental data are compared to the results of quantum chemical calculations. The reactions of Al and Ca with the organic surface are found to be fundamentally different: while the former forms new covalent bonds onto the polymer backbone, the latter tends to dope the conjugated system. Both types of reaction are expected to modify drastically the electronic properties of the polymer semiconductor.

Journal ArticleDOI
TL;DR: In this paper, the geometry of a typical polymethine dye is tuned as a function of an external electric field from a neutral structure to a zwitterionic (charge-separated) structure.

Journal ArticleDOI
P. Abreu1, Wolfgang Adam2, Tim Adye3, E. Agasi  +552 moreInstitutions (52)
TL;DR: In this article, the decays into hadrons and charged leptons have been analysed to give values for the cross sections and leptonic forward-backward asymmetries which are significantly improved with respect to those previously published by the DELPHI collaboration.

Journal ArticleDOI
P. Abreu1, Wolfgang Adam2, Tim Adye3, E. Agasi  +579 moreInstitutions (50)
TL;DR: In this article, the DELPHI experiment was used to reconstruct J/psi mesons from their decay to mu(+)mu(-) and e(+)e(-), using the data collected by the Delphi experiment during 1991 and 1992.

Journal ArticleDOI
TL;DR: In this article, the transverse momentum distribution of the J / ψ mesons has been analyzed in the framework of the vector meson dominance model and the radii of Jψ and the ϱ 0 as well as the total J/ ψ - N and ϱ0 - N cross sections were deduced.

Journal ArticleDOI
TL;DR: In this paper, the dependence of efficiency and spatial resolution on the incidence angle of track was measured with argon-dimethylether (DME) and xenon-DME gas mixtures; for minimum ionizing particles perpendicular to the chambers, the spatial resolution for Xe gas mixture is 65 μm rms and the efficiency 98%.
Abstract: Recent measurements realized with Microstrip Gas Chambers (MSGC) manufactured on glass substrata in a range of bulk resistivity are presented. Chambers made on electronically conductive supports with resistivity of 10 9 ω cm and gold strips show a stable behaviour during long term irradiation up to an accumulated charge of 130 mC/cm of strip when operated in an argon-dimethylether (DME) mixture. Similar measurements realised with argon-methane show instead a fast degradation of gain already at collected charge of around 5 mC/cm. Further investigation of MSGC performance with different Ar-DME compositions show that the larger stable gain can be achieved with a 50-50 mixture. We present also results of beam runs performed with MSGC manufactured on Hoya SL glass with an anode to cathode distance of 200 μm and a 2 mm gas layer. The dependence of efficiency and spatial resolution on the incidence angle of track was measured with argon-DME and xenon-DME gas mixtures; for minimum ionizing particles perpendicular to the chambers (0°) the spatial resolution for Xe gas mixture is 65 μm rms and the efficiency 98%. For incidence angles up to 10° a small degradation of both parameters was observed.

Journal ArticleDOI
TL;DR: In this article, the authors reported on transitions leading to improved energy levels for the 4f, 5f, 6f, 7f, and 5g configurations of neutral neon.
Abstract: The spectrum of neutral neon used as a carrier gas has been measured by the Fourier transform spectroscopy technique from 1800 to 9000 cm−1. We report on transitions leading to improved energy levels for the 4f, 5f, 6f, 7f and the 5g configurations. In addition, we identify transitions leading to the previously unknown 6g and 7g configurations. Theoretically, we have generalized the polarization and pair coupling formulae to the extended quadrupole-polarization model. Explicitly accounting for the 6f'-7f (6g'-7g) quadrupole interaction, our two-parameter expression reproduces 18 observed levels (ng) with a mean deviation of 0.016 cm−1. Inclusion of the 24 observed pairs of nf levels increases the mean deviation to 0.036 cm−1.


Journal ArticleDOI
TL;DR: In this article, the optical properties of thin sputter-deposited A1N films on Si were measured and it was shown that they depend on the exact preparation conditions.

Journal ArticleDOI
TL;DR: The general ansatz, the energy density, and the Chern-Simons charge for static axially symmetric configurations in the bosonic sector of the electroweak theory are presented.
Abstract: We present the general ansatz, the energy density, and the Chern-Simons charge for static axially symmetric configurations in the bosonic sector of the electroweak theory. Containing the sphaleron, the multisphalerons, and the sphaleron-antisphaleron pair at finite mixing angle, the ansatz further allows the construction of the sphaleron and multisphaleron barriers and of the bisphalerons at finite mixing angle. We conjecture that further solutions exist.

Journal ArticleDOI
B. Adeva1, Shafqat Ahmad2, A. Arvidson3, B. Badelek4  +163 moreInstitutions (26)
TL;DR: A muon beam polarimeter was built for the SMC experiment at the CERN SPS, for muon energies of 100 to 200 GeV as discussed by the authors, with a relative systematic accuracy of 3%.
Abstract: A muon beam polarimeter has been built for the SMC experiment at the CERN SPS, for muon energies of 100 to 200 GeV. The beam polarisation is determined from the energy spectrum of positrons from the decay μ + → e + ν c ν μ . A polarisation of − 0.82 is measured with a relative systematic accuracy of 3%.

Journal ArticleDOI
Wolfgang Adam1, E. G. Anassontzis2, E. Albrecht1, I. Ambec1, G. W. Van Apeldoorn, Y. Arnoud3, C. Aubret4, Andre Augustinus, Paul Baillon1, C. Barnoux5, M. Battaglia, M. Berggren1, Daniel Bloch1, O. Botner1, Claire Bourdarios6, N. Brummer, J. M. Brunet4, A. Budziak, A. Buys7, L. P. Caloba8, P. Carecchio5, P. Carrie1, P. Cavalli5, R. Cereseto9, Guillaume Cerutti1, M. Chevry7, E. Christophel, E. Dahl-Jensen10, B. Dalmagne6, P. Dam10, P. Van Dam, G. Damgaard11, M. Davenport1, J. Dolbeau4, Marcos Dracos, Manolis Dris12, N. de Koning, A.S. de la Vega11, N. Dimitriou, L. O. Eek8, Tord Ekelof8, J. Erikson8, J. P. Engel, G. Evers, D. Fassouliotis12, T. A. Filippas12, A. Florek, B. Florek, E. Fokitis12, F. Fontanelli9, A. Fontenille5, D. Fraissard1, K. Galuszka, Jorge-Armando Benitez Garcia, E. Gaumann1, Evangelos Gazis12, B. Goret1, V. Gracco9, L. Guglielmi4, F. Hahn13, S. Haider, Allan Hallgren8, W. Hao, T. Henkes1, P. F. Honore4, Kathy Huet7, Pavlos Ioannou2, Håkan T Johansson8, Pierre Juillot, George Kalkanis2, E. Karvelas, S. Katsanevas2, E. C. Katsoufis12, P. Kindblom8, N. J. Kjaer1, W. Klempt1, Peter Kluit, B. Koene, P. Kokkinias, C. Kourkoumelis2, C. Lambropoulos, D. Langerveld, G. Lecoeur1, G. Lenzen13, L.-E. Lindqvist8, A. Lopez Agüera, Demetrios Loukas, A. Maltezos, S. Maltezos12, A. Markou, L. Mattsson8, J. Medbo8, Jerzy Michalowski, F. Montano9, G. Mourgue1, Borge Svane Nielsen10, R. Nicolaidou2, J.M. Noppe6, J.M. Ostler1, K. Pakonski, Th. D. Papadopoulou12, D. Poutot4, A. Petrolini9, G. Polok, L. K. Resvanis2, E. Rosso1, G. Sajot5, M. Schaeffer, Mario Sannino9, E. Saragas, E. Schyns13, S. Squarcia9, Georgios Stavropoulos, Marek Stodulski, Z. Stopa, R. Strub, J. Thadome13, G. E. Theodosiou, D. Z. Toet, L. Traspedini9, G. Tristram4, Andromachi Tsirou1, M. Turala, Spyros Tzamarias1, O. Ullaland1, P. Vergezac4, G. Voulgaris2, A. Wärm8, J. Werner7, M. Zavrtanik14, E. Zevgolatakos 
TL;DR: In this article, the DELPHI ring imaging Cherenkov detector system was designed to do particle identification over most of the solid angle in the momentum range from ∼2 GeV c to ∼40 sol GeVc.
Abstract: The ring imaging Cherenkov detector system in the DELPHI experiment at the Large Electron-Positron storage ring at CERN, is designed to do particle identification over most of the solid angle in the momentum range from ∼2 GeV c to ∼40 sol GeV c . Two radiator media are used to cover the momentum range; (i) a 1 cm layer of liquid C6F14, and (ii) a volume filled with gaseous C5F12 or C4F10. Photosensitive time projection chambers record the conversion points of the ultraviolet photons produced in both radiator systems. The total active area is ∼30 m2 in the barrel region and ∼8 m2 in the two endcaps. The design of the detector systems is described in this paper. We will also report performance figures and compare them to simulation studies.


Journal ArticleDOI
TL;DR: In this article, the concept of band structure in one-dimensional conjugated systems is developed for the non-expert in solid state physics, as well as an overview of the most commonly used theoretical and experimental methods.

Journal ArticleDOI
TL;DR: The resonance Raman excitation profiles of the vibrational modes of the emeraldine salt form of polyaniline protonated with camphor sulfonic acid are remarkably and selectively enhanced, indicating improved structural and electronic order.