Showing papers in "International Journal of Life Cycle Assessment in 2004"

System boundaries and input data in consequential life cycle inventory analysis

Abstract: A consequential life cycle assessment (LCA) is designed to generate information on the consequences of decisions. This paper includes a comprehensive presentation of the consequential approach to system boundaries, allocation and data selection. It is based on a text produced within the SETAC-Europe working group on scenarios in LCA. For most of the methodological problems, we describe ideal methodological solutions as well as simplifications intended to make the method feasible in practice. We compile, summarize and refine descriptions of consequential methodology elements that have been presented in separate papers, in addition to methodological elements and general conclusions that have not previously been published. A consequential LCA ideally includes activities within and outside the life cycle that are affected by a change within the life cycle of the product under investigation. In many cases this implies the use of marginal data and that allocation is typically avoided through system expansion. The model resulting from a consequential life cycle inventory (LCI) also includes the alternative use of constrained production factors as well as the marginal supply and demand on affected markets. As a result, the consequential LCI model does not resemble the traditional LCI model, where the main material flows are described from raw material extraction to waste management. Instead, it is a model of causal relationships originating at the decision at hand or the decision-maker that the LCI is intended to inform.

The LCIA midpoint-damage framework of the UNEP/SETAC Life Cycle Initiative

Abstract: Life Cycle Impact Assessment (LCIA) methods can be grouped into two families: classical methods determining impact category indicators at an intermediate position of the impact pathways (e.g. ozone depletion potentials) and damage-oriented methods aiming at more easily interpretable results in the form of damage indicators at the level of the ultimate societal concern (e.g. human health damage). The Life Cycle Initiative, a joint project between UNEP1 and SETAC2, proposes a comprehensive LCA framework to combine these families of methods. The new framework takes a world-wide perspective, so that LCA will progress towards a tool meeting the needs of both developing and developed countries. By a more precise and broadly agreed description of main framework elements, the Life Cycle Initiative expects to provide a common basis for the further development of mutually consistent impact assessment methods. Inputs to the LCIA midpoint-damage framework are results of Life Cycle Inventory analyses (LCI). Impact pathways connect the LCI results to the midpoint impact categories with the corresponding indicators, as well as to the damage categories at the level of damages to human health, natural environment, natural resources and man-made environment, via damage indicators. Mid-point impact categories simplify the quantification of these impact pathways where various types of emissions or extractions can be aggregated due to their comparable impact mechanisms. Depending on the available scientific information, impact pathways may be further described up to the level of damage categories by quantitative models, observed pathways or merely by qualitative statements. In the latter case, quantitative modelling may stop at mid-point. A given type of emission may exert damaging effects on multiple damage categories, so that a corresponding number of impact pathways is required. Correspondingly, a given damage category may be affected jointly by various types of emissions or extractions. It is therefore an important task of the Life Cycle Initiative to carefully select damage indicators. The content of the midpoint and of the damage categories is clearly defined, and proposals are made on how to express the extent of environmental damage by suitable indicator quantities. The present framework will offer the practitioner the choice to use either midpoint or damage indicators, depending on modelling uncertainty and increase in results interpretability. Due to the collaboration of acknowledged specialists in environmental processes and LCIA around the globe, it is expected that - after a few years of effort - the task forces of the Life Cycle Initiative will provide consistent and operational sets of methods and factors for LCIA in the future.

Allocation of Energy Use in Petroleum Refineries to Petroleum Products Implications for Life-Cycle Energy Use and Emission Inventory of Petroleum Transportation Fuels

Abstract: Aim, Scope, and Background Studies to evaluate the energy and emission impacts of vehicle/fuel systems have to address allocation of the energy use and emissions associated with petroleum refineries to various petroleum products because refineries produce multiple products. The allocation is needed in evaluating energy and emission effects of individual transportation fuels. Allocation methods used so far for petroleum-based fuels (e.g., gasoline, diesel, and liquefied petroleum gas [LPG]) are based primarily on mass, energy content, or market value shares of individual fuels from a given refinery. The aggregate approach at the refinery level is unable to account for the energy use and emission differences associated with producing individual fuels at the next sub-level: individual refining processes within a refinery. The approach ignores the fact that different refinery products go through different processes within a refinery. Allocation at the subprocess level (i.e., the refining process level) instead of at the aggregate process level (i.e., the refinery level) is advocated by the International Standard Organization. In this study, we seek a means of allocating total refinery energy use among various refinery products at the level of individual refinery processes.

Cradle-to-gate life cycle inventory and assessment of pharmaceutical compounds

Abstract: The research presented here represents one part of GlaxoSmithKline’s (GSK) efforts to identify and improve the life cycle impact profile of pharmaceutical products. The main goal of this work was to identify and analyze the cradle-to-gate environmental impacts in the synthesis of a typical Active Pharmaceutical Ingredient (API). A cradle-to-gate life cycle assessment of a commercial pharmaceutical product is presented as a case study. Life cycle inventory data were obtained using a modular gate-to-gate methodology developed in partnership with North Carolina State University (NCSU) while the impact assessment was performed utilizing GSK’s sustainability metrics methodology. Major contributors to the environmental footprint of a typical pharmaceutical product were identified. The results of this study indicate that solvent use accounts for a majority of the potential cradle-to-gate impacts associated with the manufacture of the commercial pharmaceutical product under study. If spent solvent is incinerated instead of recovered the life-cycle profile and impacts are considerably increased. This case study provided GSK with key insights into the life-cycle impacts of pharmaceutical products. It also helped to establish a well-documented approach to using life cycle within GSK and fostered the development of a practical methodology that is applicable to strategic decision making, internal business processes and other processes and tools.

Economic allocation: Examples and derived decision tree

Abstract: Goal, Scope and Background In the recently published (Dutch) Handbook on LCA, economic allocation is advised as baseline method for most allocation situations in a detailed LCA. Although the Handbook on LCA aimed to provide a ‘cookbook’ with operational guidelines for conducting each step of an LCA, this was not completely achieved for the allocation step. The guidelines for allocation largely remained at the level of principles. This restricted elaboration of economic allocation may hamper application in practice. Therefore, this paper elaborates some examples applying economic allocation.

Environmental Performance of a Municipal Wastewater Treatment Plant

Abstract: Nowadays, every strategy must be developed taking into account the global impact on the environment; if this aspect is forgotten, a change of environmental loads or their effect will be caused and no reduction will be attained. For instance, a wastewater treatment plant (WWIP), which is considereda priori as an ecological treatment system, gives rise to an environmental impact due to its energy consumption, use of chemical compounds, emissions to the atmosphere and sludge production, the post-treatment of which will also have diverse environmental effects. The goal of this study is to evaluate the potential environmental impact corresponding to a municipal WW1P and to identify the hot spots associated with the process. In this study, the Centre of Environmental Science (CML) of Leiden University methodology has been considered to quantify the potential environmental impact associated with the system under study. A comprehensive analysis of the WWTP was evaluated for the physico-chemical characterisation of the wastewaters as well as the inventory of all the inputs (energy, chemical compounds, ...) and outputs (emissions to air, water, soil and solid waste generation) associated with the global process. Regarding Life Cycle Inventory Assessment, SimaPro 5.0 was used and in particular CML factors (updated in 2002) were chosen for characterisation and normalisation stages. A comprehensive inventory of empirical data from water, sludge and gas flows during 2000 and 2001 was obtained. Two impact categories arise due to their significance: eutrophication and terrestrial ecotoxicity. Consequently, the aspects to be minimised in order to reduce the environmental impact of the system are the pollutant load at the watercourse discharge (mainly NH3, PO4 [3- and COD, even when all of them are below legal limits) and the emissions to soil (mainly Cr, Hg and Zn, even when they are present in low concentrations) when the sludge is used for agricultural application. As far as the environmental impact is concerned, differentiation between humid and dry season is not required as results are practically equal for both situations. Water discharge and sludge application to land have turned out to be the main contributors in the environmental performance of a WWTP. Regarding the former, the removal of nitrogen by means of a nitrification-denitrification system coupled to conventional biological aerobic treatment implies a high environmental impact reduction and, as for the latter, bearing in mind the proposed legislation, heavy metals as well as pathogens are supposed to be the key parameters to define the most adequate treatment strategies for the generated sludge. This study can serve as a basis for future studies that can apply a similar policy to a great number of wastewater facilities. Besides, features such as different treatment systems and capacities can provide additional information with the final aim of including the environmental vector in the decision-making process when the operation of a WWTP is intended to be optimised. Moreover, sludge must also be a focus of attention due to the expected increase and its major contribution to the global environmental impact of a WWTP, which can determine other treatment alternatives.

Uncertainty calculation in life cycle assessments

Abstract: Uncertainty is commonly not taken into account in LCA studies, which downgrades their usability for decision support. One often stated reason is a lack of method. The aim of this paper is to develop a method for calculating the uncertainty propagation in LCAs in a fast and reliable manner. The method is developed in a model that reflects the calculation of an LCA. For calculating the uncertainty, the model combines approximation formulas and Monte Carlo Simulation. It is based on virtual data that distinguishes true values and random errors or uncertainty, and that hence allows one to compare the performance of error propagation formulas and simulation results. The model is developed for a linear chain of processes, but extensions for covering also branched and looped product systems are made and described. The paper proposes a combined use of approximation formulas and Monte Carlo simulation for calculating uncertainty in LCAs, developed primarily for the sequential approach. During the calculation, a parameter observation controls the performance of the approximation formulas. Quantitative threshold values are given in the paper. The combination thus transcends drawbacks of simulation and approximation. The uncertainty question is a true jigsaw puzzle for LCAs and the method presented in this paper may serve as one piece in solving it. It may thus foster a sound use of uncertainty assessment in LCAs. Analysing a proper management of the input uncertainty, taking into account suitable sampling and estimation techniques; using the approach for real case studies, implementing it in LCA software for automatically applying the proposed combined uncertainty model and, on the other hand, investigating about how people do decide, and should decide, when their decision relies on explicitly uncertain LCA outcomes-these all are neighbouring puzzle pieces inviting to further work.

Weighting across safeguard subjects for LCIA through the application of conjoint analysis

Abstract: Background Many types of weighting methods, which have integrated the various environmental impacts that are used for life-cycle impact assessment (LCIA), were proposed with the aim of developing the methodology as a useful information resource for decision making, such as in the selection of products. Economic valuation indexes, in particular, have attracted attention, as their assessment results are easy to understand and can be applied in conjunction with other assessment tools, including life-cycle costing (LCC) and environmental accounting. Conjoint analysis has been widely used in market research, and has recently been applied to research in environmental economics. The method enables us to provide two types of assessment results; an economic valuation and a dimensionless index. This method is therefore expected to contribute greatly to increasing the level of research into weighting methodology, in which an international consensus has yet to be established. Conjoint analysis, however, has not previously been applied to LCIA.

Life cycle assessment of lightweight and end-of-life scenarios for generic compact class passenger vehicles

Abstract: The automotive industry has a long history in improving the environmental performance of vehicles - fuel economy and emission improvements, introduction of recycled and renewable materials, etc. The European Union also aims at improving the environmental performance of products by reducing, in particular, waste resulting from End-of-Life Vehicles (ELVs) for example. The European Commission estimates that ELVs contribute to approximately 1 % of the total waste in Europe [9]. Other European Union strategies are considering more life cycle aspects, as well as other impacts including resource or climate change. This article is summarizing the results of a European Commission funded project (LIRECAR) that aims at identifying the environmental impacts and relevance for combinations of recycling / recovery and lightweight vehicle design options over the whole life cycle of a vehicle - i.e. manufacturing, use and recycling/recovery. Three, independent and scientific LCA experts reviewed the study according to ISO 14040. From the beginning, representatives of all Life Cycle Stakeholders have been involved (European materials & supplier associations, an environmental Non-Governmental Organization, recycler’s association). The study compared 3 sets of theoretical vehicle weight scenarios: 1000 kg reference (material range of today’s end-of-life, mid-sized vehicles produced in the early 1990’s) and 2 lightweight scenarios for 100 kg and 250 kg less weight based on reference functions (in terms of comfort, safety, etc.) and a vehicle concept. The scenarios are represented by their material range of a broad range of lightweight strategies of most European car manufacturers. In parallel, three End-of-Life (EOL) scenarios are considered: EOL today and two theoretical extreme scenarios (100% recycling, respectively, 100% recovery of shredder residue fractions that are disposed of today). The technical and economical feasibility of the studied scenarios is not taken into consideration (e.g. 100% recycling is not possible). Significant differences between the various, studied weight scenarios were determined in several scenarios for the environmental categories of global warming, ozone depletion, photochemical oxidant creation (summer smog), abiotic resource depletion, and hazardous waste. However, these improvement potentials can be only realized under well defined conditions (e.g. material compositions, specific fuel reduction values and EOL credits) based on case-by-case assessments for improvements over the course of the life cycle. Looking at the studied scenarios, the relative contribution of the EOL phase represents 5% or less of the total life cycle impact for most selected impact categories and scenarios. The EOL technology variations studied do not impact significantly the considered environmental impacts. Exceptions include total waste, as long as stockpile goods (overburden, tailings and ore/coal processing residues) and EOL credits are considered. LIRECAR focuses only on lightweight/recycling, questions whereas other measures (changes in safety or comfort standards, propulsion improvements for CO2, user behavior) are beyond the scope of the study. The conclusions are also not necessarily transferable to other vehicle concepts. However, for the question of end-of-life options, it can be concluded that LIRECAR cannot support any general recommendation and/or mandatory actions to improve recycling if lightweight is affected. Also, looking at each vehicle, no justification could be found for the general assumption that lightweight and recycling greatly influence the affected environmental dimension (Global Warming Potential or resource depletion and waste, respectively). LIRECAR showed that this general assumption is not true under all analyzed circumstances and not as significant as suggested. Further discussions and product development targets shall not focus on generic targets that define the approach/technology concerned with how to achieve environmental improvement (weight reduction [kg], recycling quota [%]), but on overall life cycle improvement). To enable this case-by-case assessment, exchanges of necessary information with suppliers are especially relevant.

A Comparative Life Cycle Assessment of Building Insulation Products made of Stone Wool, Paper Wool and Flax Part 1: Background, Goal and Scope, Life Cycle Inventory, Impact Assessment and Interpretation

Abstract: Part 2 summarises the results of a comparative LCA study of HT stone wool, flax representing crop grown products and paper wool representing recycled products applied for roof insulation, in which an attempt is made to answer the question of whether the biological products flax and paper wool are more environmentally preferable than the mineral product stone wool representing more traditional insulation materials. Of the three products compared, paper wool has, in general, the lowest global and regional environmental impacts and flax insulation the highest, with stone wool falling in between. A notable exception is the total energy use, where stone wool has the lowest consumption, followed by cellulose and flax. The study also addresses occupational health, using an approach similar to that used for risk assessment. Here, the modern less biopersistent stone wool products are seen as the safest alternatives, because of a low potential for exposure, sufficient animal testing and the absence of carcinogenic properties. Overall, the differences between the investigated products are of minor environmental significance compared to that achieved by their use, namely insulation of buildings, which saves energy corresponding to more than 100 times the environmental impacts incurred in their manufacture. The main conclusion is that the quality and fitness for use of an insulation product throughout its useful life span is the most important aspect in the life cycle of insulation materials.

Production of Fine and Speciality Chemicals: Procedure for the Estimation of LCIs

Abstract: Goal, Scope, Background. To improve the environmental performance of chemical products or services, especially via comparisons of chemical products, LCA is a suitable evaluation method. However, no procedure to obtain comprehensive LCIdata on the production of fine and speciality chemicals is available to date, and information on such production processes is scarce. Thus, a procedure was developed for the estimation of LCIs of chemical production process-steps, which relies on only a small amount of input data. Methods. A generic input-output scheme of chemical production process-steps was set up, and equations to calculate inputs and outputs were established. For most parameters in the resulting estimation procedure, default values were derived from on-site data on chemical production processes and from heuristics. Uncertainties in the estimated default values were reflected as best-case and worst-case scenarios. The procedure was applied to a case study comparing the production of two active ingredients used for crop protection. Verification and a sensitivity analysis were carried out. Results and Discussion. It was found that the impacts from the mass and energy flows estimated by the procedure represent a significant share of the impacts assessed in the case study. In a verification, LCI-data from existing processes yielded results within the range of the estimated best-case and worst-case scenarios. Note that verification data could not be obtained for all process steps. From the verification results, it was inferred that mass and energy flows of existing processes for the production of fine and speciality chemicals correspond more frequently to the estimated best-case than to the worst-case scenario. In the sensitivity analysis, solvent demand was found to be the most crucial parameter in the environmental performance of the chemical production processes assessed. Conclusion. Mass and energy flows in LCIs of production processes for fine and speciality chemicals should not be neglected, even if only little information on a process is available. The estimation procedure described here helps to overcome lacking information in a transparent, consistent way. Recommendations and Outlook. Additional verifications and a more detailed estimation of the default parameters are desirable to learn more about the accuracy of the estimation procedure. The procedure should also be applied to case studies to gain insight into the usefulness of the estimation results in different decision-making contexts.

Eutrophication of aquatic ecosystems a new method for calculating the potential contributions of nitrogen and phosphorus

Abstract: Aquatic eutrophication is a widespread problem in inland and coastal waters around the world and it should therefore be one of the impact categories to be considered in LCA studies of products and services. In LCAs there are several impact assessment methods to determine characterisation factors for eutrophying nutrients, but few methods have been developed to model fate and spatial aspects. One such method was developed as part of an LCA application of the Finnish forest industry. The aim of this study was to present this characterisation method in which the potential contributions of nitrogen and phosphorus to eutrophication of aquatic ecosystems are calculated. The use of the method was demonstrated by producing site/sector-specific characterisation factors and by constructing a reference value of aquatic eutrophication for Finland. A discussion of sensitivity and uncertainty aspects related to input data is also presented. The potential contribution to eutrophication from a product system is calculated as a result of the nutrient inputs causing increased production of biomass within aquatic systems. Accordingly, direct nitrogen and phosphorus emissions as well as nitrogen and phosphorus deposition into the watercourses can be included. In the method, characterisation factors for nitrogen and phosphorus emissions are generated by multiplying commonly used equivalency factors by transport and effect factors. Transport and effect factors of the nutrient sources are case-specific and can be determined for each substance individually on the basis of scientific models, empirical data or expert judgements. In this paper, transport and effect factors are determined for different sectors (forest industry, field cultivation, fish farming, etc.) in Finland. In addition, temporal aspects can be taken account of in the model by coefficients representing the proportion of nutrient load in the productive period of the total annual load. The model uncertainty was studied by using three different scenarios based on different input data and assumptions. Uncertainties within the input data were assessed as ranges and the effects of input data uncertainty on the results were studied by varying maximum and minimum values of each input variable in the same time. The characterisation method developed was applied to provide characterisation factors of aquatic eutrophication for different sectors in Finland. The magnitude of these sector-specific characterisation factors varied greatly. For this reason, the method results were easily differentiated from those commonly used, site-generic characterisation factors produced in LCIAs. Furthermore, reference values of aquatic eutrophication for normalisation purposes in LCIA were gener-ated on the basis of sector-specific nutrient emissions and characterisation factors. Different scenarios produce alternative pictures of the contributions of various sectors to aquatic eutrophication. By examining the scores of different sectors, it can be concluded that uncertainties in the emission estimates of field cultivation and fate of nitrogen originating from deposition have the greatest effect on the results. In the average scenario, the uncertainty range for the reference value was estimated to be ± 40% due to all uncertainties in input variables. The results of the work reveal the importance of site-specific characterisation approach in the context of aquatic eutrophication. Furthermore, differentiation of nutrient forms in various sectors means that the question of determination of characterisation factors is also related to sector-specific issues. The method demonstrated is flexible, and it can be applied to geographical areas rather than to Finland as a whole. The use of sensitivity and uncertainty analysis is recommended for the interpretation of results, because there is no empirical test applicable for evaluation of the validity of results. In order to reduce uncertainty in results, further research is needed, in particular on the roles of different nutrient forms as sources for aquatic biota, on spatial differentiation of nitrogen and phosphorus as production-limiting factors, and on fate of nitrogen in catchments. The weakness of the method is related to the accessibility of input data, restricting to construct the characterisation model of aquatic eutrophication, for example, on the European level. However, it seems that legislative requirements of the European Union to study ‘target nutrient loads’ of aquatic eutrophication in the catchments of each Member State can improve the situation of the accessibility of input data in the near future.

Comparison between three different LCIA methods for aquatic ecotoxicity and a product Environmental Risk Assessment – Insights from a Detergent Case Study within OMNIITOX

Abstract: In the OMNIITOX project 11 partners have the common objective to improve environmental management tools for the assessment of (eco)toxicological impacts. The detergent case study aims at: i) comparing three Procter &c Gamble laundry detergent forms (Regular Powder-RP, Compact Powder-CP and Compact Liquid-CL) regarding their potential impacts on aquatic ecotoxicity, ii) providing insights into the differences between various Life Cycle Impact Assessment (LCIA) methods with respect to data needs and results and iii) comparing the results from Life Cycle Assessment (LCA) with results from an Environmental Risk Assessment (ERA). The LCIA has been conducted with EDIP97 (chronic aquatic ecotoxicity) [1], USES-LCA (freshwater and marine water aquatic ecotoxicity, sometimes referred to as CML2001) [2, 3] and IMPACT 2002 (covering freshwater aquatic ecotoxicity) [4]. The comparative product ERA is based on the EU Ecolabel approach for detergents [5] and EUSES [6], which is based on the Technical Guidance Document (TGD) of the EU on Environmental Risk Assessment (ERA) of chemicals [7]. Apart from the Eco-label approach, all calculations are based on the same set of physico-chemical and toxicological effect data to enable a better comparison of the methodological differences. For the same reason, the system boundaries were kept the same in all cases, focusing on emissions into water at the disposal stage. Significant differences between the LCIA methods with respect to data needs and results were identified. Most LCIA methods for freshwater ecotoxicity and the ERA see the compact and regular powders as similar, followed by compact liquid. IMPACT 2002 (for freshwater) suggests the liquid is equally as good as the compact powder, while the regular powder comes out worse by a factor of 2. USES-LCA for marine water shows a very different picture seeing the compact liquid as the clear winner over the powders, with the regular powder the least favourable option. Even the LCIA methods which result in die same product ranking, e.g. EDIP97 chronic aquatic ecotoxicity and USES-LCA freshwater ecotoxicity, significantly differ in terms of most contributing substances. Whereas, according to IMPACT 2002 and USES-LCA marine water, results are entirely dominated by inorganic substances, the other LCIA methods and the ERA assign a key role to surfactants. Deviating results are mainly due to differences in the fate and exposure modelling and, to a lesser extent, to differences in the toxicological effect calculations. Only IMPACT 2002 calculates the effects based on a mean value approach, whereas all other LCIA methods and the ERA tend to prefer a PNEC-based approach. In a comparative context like LCA the OMNIITOX project has taken the decision for a combined mean and PNEC-based approach, as it better represents the ‘average’ toxicity while still taking into account more sensitive species. However, the main reason for deviating results remains in the calculation of the residence time of emissions in the water compartments. The situation that different LCIA methods result in different answers to the question concerning which detergent type is to be preferred regarding the impact category aquatic ecotoxicity is not satisfactory, unless explicit reasons for the differences are identifiable. This can hamper practical decision support, as LCA practitioners usually will not be in a position to choose the ’right’ LCIA method for their specific case. This puts a challenge to the entire OMNIITOX project to develop a method, which finds common ground regarding fate, exposure and effect modelling to overcome the current situa-tion of diverging results and to reflect most realistic conditions.

Life cycle assessment of cane-sugar on the island of mauritius

Abstract: Agricultural production includes not only crop production, but also food processing, transport, distribution, preparation, and disposal. The effects of all these must be considered and controlled if the food chain is to be made sustainable. The goal of this case study was to identify and review the significant areas of potential environmental impacts across the whole life cycle of cane sugar on the island of Mauritius. The functional unit was one tonne of exported raw sugar from the island. The life cycle investigated includes the stage of cane cultivation and harvest, cane burning, transport, fertilizer and herbicide manufacture, cane sugar manufacture and electricity generation from bagasse. Data was gathered from companies, factories, sugar statistics, databases and literature. Energy depletion, climate change, acidification, oxidant formation, nutrification, aquatic ecotoxicity and human toxicity were assessed. The inventory of the current sugar production system revealed that the production of one tonne of sugar requires, on average, a land area of 0.12 ha, the application of 0.84 kg of herbicides and 16.5 kg of N-fertilizer, use of 553 tons of water and 170 tonne-km of transport services. The total energy consumption is about 14235 MJ per tonne of sugar, of which fossil fuel consumption accounts for 1995 MJ and the rest is from renewable bagasse. 160 kg of CO2 per tonne of sugar is released from fossil fuel energy use and the net avoided emissions of CO2 on the island due to the use of bagasse as an energy source is 932,000 tonnes. 1.7 kg TSP, 1.21 kg SO2,1.26 kgNOxand 1.26 kg CO are emitted to the air per tonne of sugar produced. 1.7 kg N, 0.002 kg herbicide, 19.1 kg COD, 13.1 kgTSS and 0.37 kg PO4 3- are emitted to water per tonne of sugar produced. Cane cultivation and harvest accounts for the largest environmental impact (44%) followed by fertilizer and herbicide manufacture (22%), sugar processing and electricity generation (20%), transportation (13%) and cane burning (1%). Nutrification is the main impact followed by acidification and energy depletion. There are a number of options for improvement of the environmental performance of the cane-sugar production chain. Cane cultivation, and fertilizer and herbicide manufacture, were hotspots for most of the impact categories investigated. Better irrigation systems, precision farming, optimal use of herbicides, centralisation of sugar factories, implementation of co-generation projects and pollution control during manufacturing and bagasse burning are measures that would considerably decrease resource use and environmental impacts. LCA was shown to be a valuable tool to assess the environmental impacts throughout the food production chain and to evaluate government policies on agricultural production systems.

Evaluating alternative life-cycle strategies for electrical appliances by the waste input-output model

Abstract: Goal, Scope and Background In 2001, a new law on the recycling of end-of-life electric home appliances (EL-EHA) was put into effect in Japan; it was the first legislation of its sort in the world, and deserves to be called the ‘Japan model.’ This article is concerned with the LCA of alternative life-cycle strategies for EL-EHA, which consist of recycling as prescribed by the law, ‘ecodesign’ strategies such as the implementation of design for disassembly (DfD) and the extension of product life (EPL), with and without ex-post functional upgradability, and the once-dominant treatment methods such as landfilling and simple shredding.

The ecolabel and sustainable development

Abstract: The goal of the different national and supranational ecolabelling programs is to encourage consumers to choose products which are the least damaging to the environment. It is clear that the involvement of product and service users is essential to the establishment of sustainable consumption patterns. For this reason, ecolabelling must necessarily limit any risks of uncertainty. To this end, labels must take into account all the impacts of a product’s life cycle and use a reliable and verifiable evaluation method. In general, the organizations in charge of ecolabelling programs claim that a multi-criteria approach is used to define the exact labelling criteria appropriate for the product categories in question. These organizations generally maintain that their approach is based on the completion of exhaustive and complete life cycle analyses, which take into account all of the impacts caused by a product throughout its life cycle. And yet, the real situation is often far less clear-cut, and these simplified approaches, which tend to reconcile economic realism and methodological coherence, constitute the usual procedure for criteria definition. Thus, the procedures involved in criteria development often rely on a ‘semi-qualitative’ approach to the life cycle which uses both qualitative and quantitative data in order to identify the product’s significant stages on the environment. Presently, the ecolabel is a ‘non-verifiable expert property’ for the consumer. The ecolabel’s lack of objectivity in its criteria and its lack of transparency, resulting from non standardized methods whose accuracy cannot be measured, can only damage this sustainable development tool’s credibility. In effect, the primary hindrance to ecolabel development lies precisely within this difficulty of finding a compromise between economic feasibility and the scientific and methodological rigor which are indispensable to the label’s credibility and veracity.

A method to include in lca road traffic noise and its health effects

Abstract: Background, Aims and Scope Transport noise represents an environmental problem that is perceived by humans more directly than the usual chemical emissions or resource uses. In spite of this, traditional LCA applications still exclude noise — probably due to the unavailability of an appropriate assessment method. In order to fill the gap, this article presents a study proposing a new computational procedure for the determination of health impairment resulting from noise emissions of road vehicles.

A diagnostic model for green productivity assessment of manufacturing processes

Abstract: Goal, Scope and Background Green Productivity (GP) is a new paradigm in sustainable manufacturing where resource conservation and waste minimization constitute the strategy in simultaneously enhancing environmental performance and productivity. This productivity approach to the sustainability of industries requires the adoption of clean production technology and the development of appropriate indicators and instruments to measure environmental performance in a continuous improvement strategy that focuses on the manufacturing stage of the product life cycle. The analysis may be expanded to include the entire life cycle with increasing details on impacts, improvement strategies and indicators.

A Life Cycle Impact Assessment Procedure with Resource Groups as Areas of Protection

Abstract: Goal and Background Current Life Cycle Impact Assessment (LCIA) procedures have demonstrated certain limitations in the South African manufacturing industry context. The aim of this paper is to propose a modified LCIA procedure, which is based on the protection of resource groups.

LCA application to integrated waste management planning in Gipuzkoa (Spain).

Abstract: Gipuzkoa is a department of the Vasque Country (Spain) with a population of about 700,000 people. By the year 2000 approximately 85% of municipal solid waste in this area was managed by landfilling, and only 15% was recycled. Due to environmental law restrictions and landfill capacity being on its limit, a planning process was initiated by the authorities. LCA was used, from an environmental point of view, to assess 7 possible scenarios arising from the draft Plan for the 2016 time horizon. In each scenario, 9 waste flows are analysed: rest waste, paper and cardboard, glass containers, light packaging, organic-green waste, as well as industrial/commercial wood, metals and plastics, and wastewater sludge. Waste treatments range from recycling to energy recovery and landfilling. Recycling of the waste flows separated at the source (paper and cardboard, glass, light packaging, organic-green waste, wood packaging, metals and plastics) results in net environmental benefits caused by the substitution of primary materials, except in water consumption. These benefits are common to the 7 different scenarios analysed. However, some inefficiencies are detected, mainly the energy consumption in collection and transport of low density materials, and water consumption in plastic recycling. The remaining flows, mixed waste and wastewater sludge, are the ones causing the major environmental impacts, by means of incineration, landfilling of partially stabilised organic material, as well as thermal drying of sludge. With the characterisation results, none of the seven scenarios can be clearly identified as the most preferable, although, due to the high recycling rates expected by the Plan, net environmental benefits are achieved in 9 out of 10 impact categories in all scenarios when integrated waste management is assessed (the sum of the 9 flows of waste). Finally, there are no relevant differences between scenarios concerning the number of treatment plants considered. Nevertheless, only the effects on transportation impacts were assessed in the LCA, since the plant construction stage was excluded from the system boundaries. The results of the study show the environmental importance of material recycling in waste management, although the recycling schemes assessed can be improved in some aspects. It is also important to highlight the environmental impact of incineration and landfilling of waste, as well as thermal drying of sludge using fossil fuels. One of the main findings of applying LCA to integrated waste management in Gipuzkoa is the fact that the benefits of high recycling rates can compensate for the impacts of mixed waste and wastewater sludge. Although none of the scenarios can be clearly identified as the one having the best environmental performance, the authorities in Gipuzkoa now have objective information about the future scenarios, and a multidisciplinary panel could be formed in order to weight the impacts if necessary. In our opinion, LCA was successfully applied in Gipuzkoa as an environmental tool for decision making.

Comparative life cycle assessment of two landfill technologies for the treatment of municipal solid waste.

Abstract: The potential environmental impacts associated with two landfill technologies for the treatment of municipal solid waste (MSW), the engineered landfill and the bioreactor landfill, were assessed using the life cycle assessment (LCA) tool. The system boundaries were expanded to include an external energy production function since the landfill gas collected from the bioreactor landfill can be energetically valorized into either electricity or heat; the functional unit was then defined as the stabilization of 600 000 tonnes of MSW and the production of 2.56x108 MJ of electricity and 7.81x108 MJ of heat. Only the life cycle stages that presented differences between the two compared options were considered in the study. The four life cycle stages considered in the study cover the landfill cell construction, the daily and closure operations, the leachate and landfill gas associated emissions and the external energy production. The temporal boundary corresponded to the stabilization of the waste and was represented by the time to produce 95% of the calculated landfill gas volume. The potential impacts were evaluated using the EDIP97 method, stopping after the characterization step. The inventory phase of the LCA showed that the engineered landfill uses 26% more natural resources and generates 81% more solid wastes throughout its life cycle than the bioreactor landfill. The evaluated impacts, essentially associated with the external energy production and the landfill gas related emissions, are on average 91% higher for the engineered landfill, since for this option 1) no energy is recovered from the landfill gas and 2) more landfill gas is released untreated after the end of the post-closure monitoring period. The valorization of the landfill gas to electricity or heat showed similar environmental profiles (1% more raw materials and 7% more solid waste for the heat option but 13% more impacts for the electricity option). The methodological choices made during this study, e.g. simplification of the systems by the exclusion of the identical life cycle stages, limit the use of the results to the comparison of the two considered options. The validity of this comparison could however be improved if the systems were placed in the larger context of municipal solid waste management and include activities such as recycling, composting and incineration.

OMNIITOX - Operational Life-Cycle Impact Assessment Models and Information Tools for Practitioners.

Abstract: This article is the preamble to a set of articles describing initial results from an on-going European Commission funded, 5th Framework project called OMNIITOX, Operational Models aNd Information tools for Industrial applications of eco/TOXicological impact assessments. The different parts of this case study-driven project are briefly presented and put in relation to the aims of contributing to an operational life cycle-impact assessment (LCIA) model for impacts of toxicants. The present situation has been characterised by methodological difficulties, both regarding choice of the characterisation model(s) and limited input data on chemical properties, which often has resulted in the omission of toxicants from the LCIA, or at best focus on well characterised chemicals. The project addresses both problems and integrates models, as well as data, in an information system- the OMNIITOX IS. There is also a need for clarification of the relations between the (environmental) risk assessments of toxicants and LCIA, in addition to investigating the feasibility of introducing LCA into European chemicals legislation, tasks that also were addressed in the project. Keywords: Case studies; characterisation factor; chemicals; environmental risk assessment; hazard assessment; information system; life cycle impact assessment (LCIA); potentially toxic substances; regulation; risk assessment; risk ranking

Evaluation of Long-Term Impacts in LCA

Abstract: When looking at a product’s life cycle, emissions and resource uses, as well as the resulting impacts, usually occur at different points in time. For instance, construction materials are often ‘stored’ in buildings for many decades before they are recycled or disposed of. The goal of the LCA Discussion Forum 22 was to present and discuss arguments pro and contra a temporally differentiated weighting of impacts. The discussion forum started with three talks that illustrated the importance of temporal aspects in LCI and LCIA. The following two presentations discussed the economical principles of discounting, the adequacy of this concept within LCA, and the ethical questions involved. After one further short presentation, three groups were formed that discussed questions about temporally-differentiated weighting, and consequences for LCI as well as LCIA (damage assessment and final weighting). The discussion forum ended with the following conclusions: (a) long-term impacts should be considered in LCA, and (b) long-term emissions should be inventoried separately from short-term emissions. There was no consensus on whether short-term and long-term impacts should be weighted equally. Some prefer to weigh short-term emissions higher, because they are considered to be closer. Consistent and approved forecasts should be used when considering future changes in environmental conditions in LCI and LCIA.

Comparative lca of industrial objects part 1: lca data quality assurance — sensitivity analysis and pedigree matrix

Abstract: Goal, Scope and Background The main aim of this paper is to present some methodological considerations concerning existing methods used to assess quality of the LCA study. It relates mainly to the quality of data and the uncertainty of the LCA results. The first paper is strictly devoted to methodological aspects whereas, the second is presented in a separate article (Part II) and devoted mainly to a case study.

Development of Damage Function of Acidification for Terrestrial Ecosystems Based on the Effect of Aluminum Toxicity on Net Primary Production

Abstract: Acidification is one of the important impact categories for life cycle impact assessment. Although its characterization has progressed during this decade through the employment of midpoint approaches, only limited studies of endpoint approaches have been performed. Objective. This study aimed at developing damage function of acidification for terrestrial ecosystems in Japan. Damage function expresses a quantitative relationship between the inventory and endpoint damage. The geographical boundary was limited in Japan both for emission and impact. In this study, sulfur dioxide (SO2), nitrogen monoxide (NO), nitrogen dioxide (NO2) (NO and NO2 collectively mean NOx), hydrogen chloride (HC1), and ammonia (NH3) were considered as major causative substances of acidification. Net primary production (NPP) of existing vegetation was adopted as an impact indicator of terrestrial ecosystems. The aluminum toxicity was adopted as the major factor of effect on terrestrial ecosystems due to acidification. The leachate concentration of monomeric inorganic aluminum ions was selected to express the plant toxicity of aluminum. The results of damage function gave utilizable factors both for a midpoint approach and an endpoint approach; Atmospheric Deposition Factor (ADF) and Damage Factor (DF) applicable to the former and the latter, respectively. The ADF indicates an increase of H+ deposition per unit area to an additional emission of causative sustance. The additional emission corresponds to some alternatives in industry, not the baseline emission. The DF indicates the total NPP damage in all of Japan due to the additional emission of causative substances. The derived NPP damage is on the order of one millionth of the NPP itself. HC1 and NH3 showed larger ADFs and DFs than that of SO2 and NOx. The reason was ascribed to the relatively large source-receptor relationships (SRR) of HC1 and NH3. However, since the method applied to determine the SRR of HC1 and NH3 has larger uncertainties than that of SO2 and NOx, attention is needed to handle the difference. The damage function easily defines the concrete NPP damage due to an additional emission. The impact indica tor, NPP, also has an advantage in its mass unit that is directly summable through the entire impact categories. Expansion of endpoints, such as in aquatic ecosystems, material degradation, human health, and biodiversity aspects of terrestrial ecosystems, is an important subject for future work. Further, uncertain analyses for major parameters will provide helpful information on the reliability of damage function.

Life Cycle Assessment of the District Heat Distribution System, Part 1: Pipe Production

Abstract: Goal, Scope and Background District heating, the utilization of centrally produced heat for space heating and domestic hot water generation, has the potential to contribute to the eco-efficient use of energy resources in the parts of the world where space heating is needed. In literature, environmental studies on district heating mainly consider the emissions from heat generation; the environmental impact from the distribution system is seldom discussed. This paper presents a life cycle assessment of the production of district heating pipes, based on a cradle-to-gate life cycle inventory commissioned by the Swedish District Heating Association. No external review has been performed but a reference group of district heating experts familiar with the practice was involved in the choice of cases as well as in reviewing parts of the study.

Parameterised inventories for life cycle assessment

Abstract: Background and Objective Life cycle assessment (LCA) is a highly data intensive undertaking, where collecting the life cycle inventory (LCI) data is the most labour intensive part. The aim of this paper is to show a method for representing the LCI in a simplified manner which not only allows an estimative, quantitative LCA, but also the application of advanced analysis methods to LCA.