Journal ArticleDOI
2,3-Dichlorobicyclo[2.2.1]hepta-2,5-diene: A Convenient Precursor of Norbornadiene-2,3-diynes
TLDR
Norbornadienes that feature the properties of norbornadiene and of the ene-diyne in the same molecule have been prepared via a simple and high-yielding route starting from dichlorobicyclo[221]hepta-2,5-diene (1) as mentioned in this paper.About:
This article is published in Synthetic Communications.The article was published on 1997-04-01. It has received 6 citations till now. The article focuses on the topics: Norbornadiene & Diene.read more
Citations
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Journal ArticleDOI
Synthesis and Properties of Dinuclear Complexes with a Photochromic Bridge: An Intervalence Electron Transfer Switching “On” and “Off”
TL;DR: In this article, two cyclometallated Ru(bpy)2(pp) units were grafted via ethynyl spacers onto the photochromic cores of the norbornadiene or dithienylethene families, to give the bimetallic ruthenium(II) complexes 1 and 2a, respectively.
Journal ArticleDOI
Low Molecular Weight Norbornadiene Derivatives for Molecular Solar-Thermal Energy Storage.
Maria Quant,Anders Lennartson,Ambra Dreos,Mikael Kuisma,Paul Erhart,Karl Börjesson,Karl Börjesson,Kasper Moth-Poulsen +7 more
TL;DR: The synthesis, characterization, and computational evaluation of a series of low molecular weight norbornadiene–quadricyclane systems indicate that the ethynyl moiety plays a critical role in obtaining the high oscillator strengths seen for these molecules.
Journal ArticleDOI
Synthesis of cyclopentadiene derivatives by retro-Diels–Alder reaction of norbornadiene derivatives
Erdin Dalkılıç,Arif Daştan +1 more
TL;DR: In this paper, the synthesis of cyclopentadiene derivatives starting from norbornadiene was investigated using dimethyl 1,2,4,5-tetrazine-3,6-dicarboxylate.
Journal ArticleDOI
Photochemical tuning of light emission in a conjugated polymer containing norbornadiene units in the main chain
Francesco Babudri,Gianmarco Bilancia,Antonio Cardone,Paolo Coppo,Luisa De Cola,Gianluca M. Farinola,Johannes W. Hofstraat,Francesco Naso +7 more
TL;DR: A conjugated alternating copolymer containing norbornadiene and bis(ethynylene)phenylene units was prepared by the Cassar-Heck-Sonogashira cross-coupling reaction and its electroluminescence was tested in a device, and its fluorescence colour could be tuned by light-induced nor bornadiene-quadricyclane isomerization.
Synthesis and Photochemical Characterisation of Photoactive Compounds for Molecular Electronics
TL;DR: In this paper, the authors explored the potential of norbornadiene-quadricyclane (NBD-QC)-based photochromic system, to serve as a switch for molecular electronics application.
References
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Journal ArticleDOI
Preparation and Chemistry of PhI+C≡CI+Ph·2-OTf, Bis[phenyl[[(trifluoromethyl)sulfonyl]oxy]iodo]acetylene, a Novel Difunctional Acetylene, Bis(iodonium) Species and a Stable C2-Transfer Agent
TL;DR: In this paper, the title compound 2 is readily prepared as a stable microcrystalline solid from bis(tri-n-butylstannyl) acetylene and PhICN•OTf.