A mechanistic investigation on the electrocatalytic reduction of aliphatic ketones at platinum
C. J. Bondue,Marc T. M. Koper +1 more
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TLDR
In this paper, the authors derived that hydrogen competes with ketones for adsorption sites and that hydrogen underpotential deposition exerts an inhibiting influence on the reduction of ketones and eventually suppresses it.About:
This article is published in Journal of Catalysis.The article was published on 2019-01-01 and is currently open access. It has received 33 citations till now. The article focuses on the topics: Ketone & Enol.read more
Citations
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Handbook of heterogeneous catalytic hydrogenation for organic synthesis
TL;DR: In this paper, the authors present a method for the preparation of Amines by Reductive Alkylation and the subsequent hydrogenation of Imines, Oximes, and Related Compounds.
Journal ArticleDOI
Electrocatalytic Hydrogenation of Biomass-Derived Organics: A Review.
Sneha A. Akhade,Sneha A. Akhade,Nirala Singh,Nirala Singh,Oliver Y. Gutiérrez,Juan A. Lopez-Ruiz,Huamin Wang,Jamie D. Holladay,Yue Liu,Abhijeet J. Karkamkar,Robert S. Weber,Asanga B. Padmaperuma,Mal Soon Lee,Greg A. Whyatt,Michael L. Elliott,Johnathan E. Holladay,Jonathan L. Male,Johannes A. Lercher,Johannes A. Lercher,Roger Rousseau,Vassiliki Alexandra Glezakou +20 more
TL;DR: This review is to determine whether the following questions have been sufficiently answered in the open literature, and if not, what additional information is required.
Journal ArticleDOI
Structural principles to steer the selectivity of the electrocatalytic reduction of aliphatic ketones on platinum
TL;DR: In this article, the authors report a study on acetone reduction at platinum single-crystal electrodes using online electrochemical mass spectroscopy, in situ Fourier transform infrared spectrograms and density functional theory calculations.
Journal ArticleDOI
Electrochemical Reduction of the Carbonyl Functional Group: The Importance of Adsorption Geometry, Molecular Structure, and Electrode Surface Structure
C. J. Bondue,Marc T. M. Koper +1 more
TL;DR: This paper studies the electrochemical hydrogenation of the carbonyl functional group of acetophenone and 4-acetylpyridine at platinum single-crystal electrodes to determine the selective electroreduction of functionalized ketones.
Journal ArticleDOI
Electrochemically Tunable Proton-Coupled Electron Transfer in Pd-Catalyzed Benzaldehyde Hydrogenation.
Katherine Koh,Udishnu Sanyal,Mal Soon Lee,Guanhua Cheng,Miao Song,Vassiliki Alexandra Glezakou,Yue Liu,Dongsheng Li,Roger Rousseau,Oliver Y. Gutiérrez,Abhijeet J. Karkamkar,Miroslaw A. Derewinski,Miroslaw A. Derewinski,Johannes A. Lercher,Johannes A. Lercher +14 more
TL;DR: The enhancement of electrocatalytic reduction is realized by the participation of support‐generated hydronium ions in the proximity of the metal particles, and the hydrogenation rate is not affected when H2 is used as a reduction equivalent.
References
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Journal ArticleDOI
An overview of hydrogen production technologies
TL;DR: A review of technologies related to hydrogen production from both fossil and renewable biomass resources including reforming (steam, partial oxidation, autothermal, plasma, and aqueous phase) and pyrolysis is presented in this article.
Journal ArticleDOI
H2 and CO Electrooxidation on Well-Characterized Pt, Ru, and Pt-Ru. 1. Rotating Disk Electrode Studies of the Pure Gases Including Temperature Effects
TL;DR: In this article, the authors studied the mechanism and kinetics of CO oxidation on Ru and Pt-Ru electrodes under well-defined mass transfer conditions, highlighting the expected differences from measurements on the oxidation of preadsorbed monolayers of CO in CO-free electrolyte.
Book
Handbook of Heterogeneous Catalytic Hydrogenation for Organic Synthesis
TL;DR: Handbook of heterogeneous catalytic hydrogenation for organic synthesis as discussed by the authors, Handbook of HHC for synthesis of organic molecules, and Handbook of CFI for the synthesis of synthetic molecules.
Book
Handbook of heterogeneous catalytic hydrogenation for organic synthesis
TL;DR: In this paper, the authors present a method for the preparation of Amines by Reductive Alkylation and the subsequent hydrogenation of Imines, Oximes, and Related Compounds.