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Journal ArticleDOI

A novel reagentless approach for synthesizing cellulose nanocrystal-supported palladium nanoparticles with enhanced catalytic performance

TLDR
In this article, a cellulose nanocrystal (CN)-supported palladium nanoparticles (Pd NPs) were synthesized without employing any other reductants, capping or dispersing agents.
Abstract
We report a one step and environment-friendly synthesis of cellulose nanocrystal (CN)-supported palladium nanoparticles (Pd NPs) without employing any other reductants, capping or dispersing agents. CNs played a dual role as a supporting matrix and a reductant and they were used to obtain stable dispersions of Pd NPs. The obtained hybrid material exhibited much higher activities than the unsupported and other polymer-supported Pd NPs in the catalyzed reduction of methylene blue and 4-nitrophenol. The approach presented in this paper promotes the use of renewable natural resources to prepare a variety of hybrid inorganic–organic materials for the purpose of catalysis, sensors, and other potential applications.

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Review: nanocelluloses as versatile supports for metal nanoparticles and their applications in catalysis

TL;DR: In this paper, the applications of metal-hybrid nanocellulose composites in catalysis are reviewed, without the use of metal nanoparticles, and the first part illustrates their use as support, stabilizer and/or reducing agent in the synthesis of various metal nanoparticle.
Journal ArticleDOI

Ni@Pd core–shell nanoparticles modified fibrous silica nanospheres as highly efficient and recoverable catalyst for reduction of 4-nitrophenol and hydrodechlorination of 4-chlorophenol

TL;DR: In this paper, a novel fibrous nano-silica (KCC-1) based nanocatalyst (Ni@Pd/KCC1) was synthesized by modifying KCC1 using Ni-Pd core-shell nanoparticles (NPs).
Journal ArticleDOI

Functionalization of cellulose nanocrystals for advanced applications

TL;DR: The recent development of functionalized cellulose nanocrystals for several important applications in the authors' and other laboratories will be described and perspectives on the potentials of these sustainable nanomaterials are offered.
Journal ArticleDOI

Cellulose nanomaterials: promising sustainable nanomaterials for application in water/wastewater treatment processes

TL;DR: In this paper, a detailed overview of pristine, surface-functionalized cellulose nanomaterials (CNCs) and CN-incorporated nanocomposites for applications in various water/wastewater treatment processes, such as sorption, membrane filtration, and flocculation are provided.
Journal ArticleDOI

Natural skin-inspired versatile cellulose biomimetic hydrogels

TL;DR: A skin-like cellulose biomimetic hydrogel was prepared based on dynamic covalent chemistry, which realized the combination of ultra-stretchability, self-healing, adhesiveness, antibacterial and mechano-stimuli sensitivity within a single structure.
References
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Journal ArticleDOI

Completely "green" synthesis and stabilization of metal nanoparticles.

TL;DR: In the present Communication, a completely "green" synthetic method for producing silver nanoparticles is introduced, by gentle heating of an aqueous starch solution containing silver nitrate and glucose, which produces relatively monodisperse, starchedsilver nanoparticles.
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Free-standing mesoporous silica films with tunable chiral nematic structures

TL;DR: This work describes the development of a photonic mesoporous inorganic solid that is a cast of a chiral nematic liquid crystal formed from nanocrystalline cellulose, and is the first materials to combine mesoporosity with long-range chiral ordering that produces photonic properties.
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Catalytic Activity of Palladium Nanoparticles Encapsulated in Spherical Polyelectrolyte Brushes and Core−Shell Microgels

TL;DR: In this paper, a quantitative comparison of the catalytic activity of palladium nanoparticles immobilized in different colloidal carrier systems, namely, in spherical polyelectrolyte brushes (SPB) and core−shell microgels, is presented.
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Rapid synthesis of silver nanoparticles using dried medicinal plant of basil

TL;DR: The various phytochemicals present within the ocimum plant result in effective reduction of silver salts to nanoparticles but their chemical framework is also effective at wrapping around the nanoparticles to provide excellent robustness against agglomeration.
Journal ArticleDOI

Banana peel extract mediated novel route for the synthesis of silver nanoparticles

TL;DR: In this paper, bio-inspired silver nanoparticles were synthesized with the aid of a novel, non-toxic, eco-friendly biological material namely, banana peel extract (BPE).
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