Journal ArticleDOI
A study of pyrolysis and pyrolysis products of flame-retardant cotton fabrics by DSC, TGA, and PY–GC–MS
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TLDR
In this article, the thermal decomposition temperatures, weight losses and potential reactions of the pyrolysis as well as resulted fragments, were analyzed, which are helpful in understanding of mechanisms of flame-retardant cotton fabrics.About:
This article is published in Journal of Analytical and Applied Pyrolysis.The article was published on 2004-06-01. It has received 224 citations till now. The article focuses on the topics: Thermal decomposition & Thermogravimetric analysis.read more
Citations
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Carbon Fibers: Precursor Systems, Processing, Structure, and Properties
TL;DR: This Review gives an overview of precursor systems, their processing, and the final precursor-dependent structure of carbon fibers (CFs) including new developments in precursor systems for low-cost CFs.
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Flame retardancy of cotton textiles by plasma-induced graft-polymerization (PIGP)
TL;DR: In this paper, the authors reported the synthesis and the plasma-induced graft-polymerization (PIGP) of two new phosphoramidate monomers, diethyl(acryloyloxyethyl)phosphoramide (DEAEPN) and acryl-loxy-1,3-bis(diethylphosphoric)propan (BisDEAepN) on cotton fabrics, compared with the previously used acrylate phosphate and phosphonate monomers.
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Recent trends and developments in pyrolysis-gas chromatography.
TL;DR: It has been predicted that future advances in separation technology such as the use of comprehensive two-dimensional gas chromatography will further enhance the analytical scope of Py-GC.
Journal ArticleDOI
Eco-friendly finishing agent for cotton fabrics to improve flame retardant and antibacterial properties.
TL;DR: The treated cotton fabric reveals excellent antibacterial properties, and thermal gravimetric analysis was employed to investigate the thermal decomposition behaviour of the treated samples.
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Thermal stability and flame retardancy of polyester, cotton, and relative blend textile fabrics subjected to sol–gel treatments
TL;DR: In this article, the effect of the presence of SiO2 on the thermal and fire stability of textile fabrics was investigated by means of scanning electronic microscopy (SEM), which showed the formation of a continuous silica film located in the neighboring fibers.
References
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Journal ArticleDOI
Influence of flame retardants on the mechanism of pyrolysis of cotton (cellulose) fabrics in air
TL;DR: In this paper, a revised model for the influence of flame retardant treatments on the pyrolysis behavior, in air, of cotton fabrics is proposed, based on extensive studies of a set of commercially flame retarded cotton fabrics using a range of experimental techniques, e.g., PyFTIR, Py/GC and GC-MS, thermal analysis, oxygen index/smoke-CO-CO2 evolution.
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Thermal Degradation of Cotton Cellulose
TL;DR: In this paper, the thermal degradation of cotton cellulose treated with chemical mixtures containing P and N was studied by thermal analysis, infrared spectroscopy, Char yield and limiting-oxygen-index (LOI).
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Thermal degradation of cotton under linear heating
TL;DR: In this article, the activation energy of the diffusion-controlled oxidative destruction was estimated as 120-140 kJ/mol, with an asymmetrical form and a short tail, which is typical for diffusion controlled processes.
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Pyrolytic Gas Generation of Cotton Cellulose With and Without Flame Retardants at Different Stages of Thermal Degradation: Effects of Nitrogen, Phosphorus, and Halogens
TL;DR: In this paper, pyrolytic gases generated at various temperature ranges were analyzed to observe changes in gas generation behavior dynamically in the process of thermal degradation, and the results revealed that flame retardant samples show extremely reduced amounts and fewer numbers of gas products compared with flammable samples, and some gases from flame-resilient samples decrease with rising temperature, even disappearing at 500°C in the case of the (NH4)2HPO4-treated sample.
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Initial Pyrolysis Reactions in Unmodified and Flame-Retardant Cotton
TL;DR: In this article, thermogravimetric data were used to make Arrhenius plots for the vacuum pyrolyses of unmodified cotton and of cotton finished with various add-ons of THPOH-NH3 and THPS-urea-Na2HPO4 flame retardants.