Journal ArticleDOI
A Three‐Dimensional Homometallic Molecular Ferrimagnet
Sanjit Konar,Partha Sarathi Mukherjee,Ennio Zangrando,Francesc Lloret,Nirmalendu Ray Chaudhuri +4 more
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This article is published in Angewandte Chemie.The article was published on 2002-05-03. It has received 192 citations till now.read more
Citations
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Journal ArticleDOI
Magnetic metal-organic frameworks.
TL;DR: The diversity of magnetic exchange interactions between nearest-neighbour moment carriers is examined, covering from dimers to oligomers and their implications in infinite chains, layers and networks, having a variety of topologies.
Journal ArticleDOI
Synthesis and catalytic properties of MIL-100(Fe), an iron(III) carboxylate with large pores
Patricia Horcajada,Suzy Surblé,Christian Serre,Do-Young Hong,You-Kyong Seo,Jong-San Chang,Jean-Marc Greneche,Irene Margiolaki,Gérard Férey +8 more
TL;DR: The large-pore iron(III) carboxylate MIL-100(Fe) with a zeotype architecture has been isolated under hydrothermal conditions, its structure solved from synchrotron X-ray powder diffraction data, while Friedel-Crafts benzylation catalytic tests indicate a high activity and selectivity for MIL- 100(Fe).
Journal ArticleDOI
Syntheses, structures, photoluminescence, and theoretical studies of d(10) metal complexes of 2,2'-dihydroxy-[1,1']binaphthalenyl-3,3'-dicarboxylate.
TL;DR: The study reveals the dominant role of the structure of the ligand over that of the d(10) metal-hydroxy cluster-based coordination polymers and the presence of the cluster significantly increasing the emission lifetime and the manifestation of photoluminescence.
Journal ArticleDOI
From achiral ligands to chiral coordination polymers: spontaneous resolution, weak ferromagnetism, and topological ferrimagnetism.
TL;DR: Five azido-bridged coordination polymers are prepared and characterized crystallographically and magnetically, and exhibit very different magnetic behaviors.
References
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Journal ArticleDOI
Automatic indexing of rotation diffraction patterns
TL;DR: In this article, a method for assigning indices to a set of single-crystal reflections recorded by the rotation-oscillation technique using a fixed X-ray wavelength is described.
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[Mn(en)]3[Cr(CN)6]2⋅4 H2O: A Three-Dimensional Dimetallic Ferrimagnet (Tc=69 K) with a Defective Cubane Unit
TL;DR: The first modified analogue of the AII3 [BIII (CN)6 ]2 ⋅x H2 O type of Prussian-Blue, the title compound, has a three-dimensional network structure extended by CrIII -CN-MnII linkages, which is based on a defective cubane unit comprising three Cr and four Mn ions.
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Metal String Complexes: Synthesis and Crystal Structure of [Ni4(μ4-phdpda)4] and [Ni7(μ7-teptra)4Cl2] (H2phdpda = N-Phenyldipyridyldiamine and H3teptra = Tetrapyridyltriamine)
Shie-Yang Lai,Tzu-Wei Lin,Yu-Hua Chen,Chih-Chieh Wang,Gene-Hsiang Lee,Ming-hwa Yang,Man-kit Leung,Shie-Ming Peng +7 more
TL;DR: In this article, the authors reported two new types of metal string complexes, one contains an even number of the metal in a string of ligand I [Ni 4(μ4phdpda) 4], and the other is an extension of the triand pentanickel(II) complexes to at this time the longest metal string of IIb [Ni 7(μ7-teptra)4Cl2].
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Crystal structure and metamagnetic property of a 2-D layered complex, [FeII(N3)2(pyz)]n (pyz = pyrazine)
TL;DR: In crystals of FeII(N3)2(pyz), two adjacent Fe2+ ions bridged via two μ-1,1-N3−ligands along the c axis to afford ferromagnetic linear chains, which are bridged byμ-pyrazine ligands along a b axis to enable 2-D antiferromagnetically coupled layers as mentioned in this paper.
Journal ArticleDOI
Co-ordination complexes as organic-inorganic layer magnets
TL;DR: In this article, the transition-metal co-ordination complexes that give rise to alternating layers of organic and inorganic moieties in the solid state exhibiting finite zero-field magnetisation at low temperatures were described.