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A Unique Crystalline-State Reaction of an Overcrowded Distibene with Molecular Oxygen: The First Example of a Single Crystal to a Single Crystal Reaction with an External Reagent

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This article is published in Journal of the American Chemical Society.The article was published on 1998-01-06. It has received 163 citations till now. The article focuses on the topics: Reagent & Single crystal.

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π-Bonding and the Lone Pair Effect in Multiple Bonds Involving Heavier Main Group Elements: Developments in the New Millennium

TL;DR: The key unifying feature of almost all molecules discussed in this review is that they are generally stabilized by the use of bulky substituents which block associative or various decomposition pathways.
Book

Solvent-free organic synthesis

TL;DR: In this paper, the authors proposed a Solvent Free Organic Synthesis (SOS) method for organic synthesis, which is a state-of-the-art method for solvent-free organic synthesis.
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Silver(I)−Polynitrile Network Solids for Anion Exchange: Anion-Induced Transformation of Supramolecular Structure in the Crystalline State

TL;DR: In this article, the counteranion self-assembly of Ag(C14H20N6) has been used for the selfassembly of supramolecular solids whose topologies depend on the counter-anion.
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Flexible sorption and transformation behavior in a microporous metal-organic framework.

TL;DR: Single-crystal X-ray diffraction experiments show that the ladder structure of the framework is maintained after desolvation of the material, resulting in the production of a porous solid stable to 215(4) degrees C.
References
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Synthesis and characterization of a stable dibismuthene : Evidence for a Bi-Bi double bond

TL;DR: In this article, a stable dibismuthene (TbtBi=BiTbt, where Tbt is 2,4,6-tris(bis(trimethylsilyl)methyl)phenyl) was found to contain a double bond formed between two bismuth atoms.
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