Journal ArticleDOI
About the Realistic Porosity of Porous Glasses
TLDR
In this paper, small-angle scattering experiments in combination with scanning electron microscopy have been performed to determine the texture properties of a selected mesoporous glass and a well-defined range order L ≈ 60 nm has been selected.Abstract:
Nitrogen adsorption, mercury intrusion, scanning electron microscopy and small-angle X-ray scattering have been used to determine the texture properties of a selected mesoporous glass The glass has been prepared by a combined acid and alkaline leaching treatment of a phase separated sodium-borosilicate initial glass Residues of silica gel, remaining in the pores of the investigated glass after the treatment with alkaline solution, lead to differences in the results of the standard characterization techniques nitrogen adsorption and mercury intrusion In order to explain these differences, small-angle scattering experiments in combination with scanning electron microscopy have been performed Here, a well-defined range order L ≈ 60 nm has been selected and a 50% porosity results The behaviour of the second derivative of the small-angle scattering correlation function has been checked by the use of the linear simulation modelread more
Citations
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Preparation of Ultrathin‐Walled Carbon‐Based Nanoporous Structures by Etching Pseudo‐Amorphous Silicon Oxycarbide Ceramics
TL;DR: In this article, the authors measured the average pore size and pore volumes to estimate the width of the graphitic domain walls, δW, left behind by the etching process, which corresponds to the specimen with the highest surface area, approximately 1 nm, which is about equal to the total width of one graphene layer and two SiOmC4−m tetrahedra, one on either side of the graphene sheet.
Journal ArticleDOI
Single-Source Precursor to Complex Metal Oxide Monoliths with Tunable Microstructures and Properties: The Case of Mg-Containing Materials
TL;DR: In this paper, a single-source inorganic precursor route for macropore synthesis of complex metal oxide monoliths was proposed, where the synthesis approach mainly involves the formation of two-phase composite (desired complex metal oxides and MgO phases) mixtures induced by high-temperature sintering of layered double hydroxide (LDH) precursors, followed by a selective leaching of self-generated mgO sacrificial template from the sintered two phase composites.
Journal ArticleDOI
Changing the relation between micro- and mesoporosity in porous glasses: The effect of different factors
V. A. Kreisberg,T.V. Antropova +1 more
TL;DR: In this paper, the relation between micro- and mesoporosity in the porous glasses produced by leaching of two-phase alkali borosilicate glasses was studied by use of advanced classical nitrogen equilibrium adsorption-desorption methods and new kinetic method of diffusion diagnostics with mass spectral recording.
Journal ArticleDOI
Coherent analysis of disordered mesoporous adsorbents using small angle X-ray scattering and physisorption experiments
Daniela Stoeckel,Daniela Stoeckel,Dirk Wallacher,Gerald A. Zickler,Jan Perlich,Ulrich Tallarek,Bernd M. Smarsly +6 more
TL;DR: It is shown that small angle X-ray scattering (SAXS) combined with chord length distribution (CLD) analysis presents a precise and convenient approach to determine the structural properties of two-phase (solid-void) systems of mesopores.
Journal ArticleDOI
Effect of leaching concentration and time on the morphology of pores in porous glasses
TL;DR: In this article, the effects of HCl leaching concentrations varying from 0.1 to 3 m and leaching times varying from 2 to 48 h on pore size and shape were investigated through small angle X-rays scattering measurements and were compared to the classical nitrogen adsorption technique.
References
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Book
Structure Analysis by Small-Angle X-Ray and Neutron Scattering
TL;DR: The use of elastic scattering is used in various branches of science and technology, including condensed matter physics, molecular biology and biophysics, polymer science, and metallurgy as mentioned in this paper.
Journal ArticleDOI
Characterization of Porous Glasses: Simulation Models, Adsorption Isotherms, and the Brunauer−Emmett−Teller Analysis Method
Lev D. Gelb,Keith E. Gubbins +1 more
TL;DR: In this paper, the authors developed a realistic model for studying adsorption in porous glasses which reproduces the complex structure of these materials, and the model porous material is generated by a quench molecular dynamics procedure which mimics the processes by which Vycor glass and controlled-pore glasses are produced.
Journal ArticleDOI
Pore structure of single-wall carbon nanohorn aggregates
Katsuyuki Murata,Katsumi Kaneko,F. Kokai,Kunimitsu Takahashi,Masako Yudasaka,Sumio Iijima,Sumio Iijima +6 more
TL;DR: In this paper, single-wall carbon nanohorn aggregates were characterized by N2 adsorption at 77 K and ''particle density'' measurement using the high pressure He buoyancy method.
Journal ArticleDOI
Interprétation de la diffusion centrale des rayons X par les systèmes poreux. I
J. Méring,D. Tchoubar +1 more
TL;DR: In this article, the shape of small angle scattering and the distribution of segment lengths limited by particle and pore boundaries are derived for a porous system using two statistical distributions of chord lengths.