Journal ArticleDOI
Aerobic Oxidative C-H Olefination of Arylamides with Unactivated Olefins via a Rh(III)-Catalyzed C-H Activation.
TLDR
An efficient Rh(III)-catalyzed aerobic oxidative C-H alkenylation of arylamides with unactivated alkenes is described in this paper, where the olefination reaction was compatible with various substituted aryamides including primary, secondary, and tertiary as well as functionalized unactivated ole fins.About:
This article is published in Organic Letters.The article was published on 2021-04-05. It has received 13 citations till now. The article focuses on the topics: Catalytic cycle & Catalysis.read more
Citations
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Journal ArticleDOI
Ruthenium(II)-Catalyzed Redox-Neutral C-H Alkylation of Arylamides with Unactivated Olefins.
TL;DR: In this paper, a Ru(II)-catalyzed weak chelating group-aided ortho-C-H alkylation of arylamides with unactivated olefins in a redox-neutral fashion was demonstrated.
Journal ArticleDOI
Transition‐Metal‐Catalyzed, Chelation‐Assisted C‐H Alkenylation and Allylation of Organic Molecules with Unactivated Alkenes
TL;DR: Chelation-assisted C−H olefination and allylation with unactivated alkenes via the concerted-metallation-deprotonation pathway is discussed in this paper .
Journal ArticleDOI
Ru(II)-Catalyzed Controlled Cross-Dehydrogenative Coupling of Benzamides with Activated Olefins via Weakly Coordinating Primary Amides.
TL;DR: Ru(II)-catalyzed regioselective ortho-alkenylation of primary benzamides with activated olefins has been realized over the competitive cyclized products as discussed by the authors.
Journal ArticleDOI
Recent advances in rhodium-catalysed cross-dehydrogenative-coupling between two C(sp2)-H bonds
TL;DR: Rhodium-catalysed cross-dehydrogenative coupling has received considerable attention in recent years and has been considered as an attractive synthetic tool for selective C−C bond formation due to its attraction to Rhodium.
Journal ArticleDOI
Rh(III)-Catalyzed Selective Olefination of N-Carboxamide Indoles with Unactivated Olefins at Room Temperature via an Internal Oxidation.
TL;DR: In this paper , a mild, convenient, and effective Rh(III)-catalyzed site-selective C2-alkenylation of N-carboxamide indoles with unactivated alkenes via an internal oxidation is described.
References
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Journal ArticleDOI
Catalytic dehydrogenative cross-coupling: forming carbon-carbon bonds by oxidizing two carbon-hydrogen bonds
Charles S. Yeung,Vy M. Dong +1 more
Journal ArticleDOI
Ruthenium(II)-Catalyzed C–H Bond Activation and Functionalization
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Weak coordination as a powerful means for developing broadly useful C-H functionalization reactions.
TL;DR: The motivation for studying Pd-catalyzed C-H functionalization assisted by weakly coordinating functional groups is discussed, and efforts to bring reactions of this type to fruition are chronicle.
Journal ArticleDOI
Towards mild metal-catalyzed C–H bond activation
TL;DR: This critical review summarizes and discusses endeavours towards the development of mild C-H activation methods and wishes to trigger more research towards this goal.
Journal ArticleDOI
Oxidative Coupling of Aromatic Substrates with Alkynes and Alkenes under Rhodium Catalysis
Tetsuya Satoh,Masahiro Miura +1 more
TL;DR: Aromatic substrates with oxygen- and nitrogen-containing substituents undergo oxidative coupling with alkynes and alkenes under rhodium catalysis through regioselective C-H bond cleavage, creating fused-ring systems through these reactions.