Journal ArticleDOI
An X-ray investigation of the adsorption of methane, water, and their mixtures in carbon micropores
TLDR
In this paper, X-ray scattering measurements provided detailed information on the coexisting state and can be used to study the temperature dependence of the phase behavior of the methane-water system during hydration formation in nanospaces.About:
This article is published in Carbon.The article was published on 2015-04-01. It has received 11 citations till now. The article focuses on the topics: Methane & Carbon.read more
Citations
More filters
Journal ArticleDOI
Adsorption-induced two-way nanoconvection enhances nucleation and growth kinetics of methane hydrates in confined porespace
TL;DR: In this article, a two-way convection at molecular scale gives rise to hydrate fibers, which grow out from inner pores and significantly depend on the contents of pre-adsorbed water.
Journal ArticleDOI
Selective adsorption of carbon dioxide, methane and nitrogen using resorcinol-formaldehyde-xerogel activated carbon
TL;DR: In this paper, the adsorption/desorption isotherms of CO2, CH4, and N2 gases onto resorcinol-formaldehyde activated carbon xerogel (RF-ACX) adsorbent were measured gravimetrically by a magnetic suspension microbalance at five different temperatures (20, 30, 40, 50 and 60
Journal ArticleDOI
Molecular insights into hybrid CH4 physisorption-hydrate growth in hydrophobic metal–organic framework ZIF-8: Implications for CH4 storage
TL;DR: In this paper, the authors investigated the hybrid CH4 physisorption-hydrate growth in ZIF-8 cavities and showed that the two-way migration phenomenon between water molecules inside the cavities of CH4 and CH4 molecules outside the cavity first occurs in the physision process, which increases the CH4 adsorption capacity to a level close to that of dry ZIF8.
Journal ArticleDOI
Kinetics of Interlayer Expansion of a Layered Silicate Driven by Caffeine Intercalation in the Water Phase Using Transmission X-ray Diffraction.
TL;DR: The kinetics of caffeine uptake into the interlayer nanospace of silicate nanosheets modified with benzylammonium was evaluated by in situ monitoring the basal spacing in aqueous media using transmission X-ray diffraction and indicates that a steady-state basal spacing is reached after the adsorption equilibrium.
Journal ArticleDOI
Isotope effect on water adsorption on hydrophobic carbons of different nanoporosities
TL;DR: In this paper, the adsorption isotherms of H2O and D2O on pitch-based activated carbon fibers (ACFs) of different pore widths from 0.6 to 1.5nm were measured at 298 K.
References
More filters
Journal ArticleDOI
Helical microtubules of graphitic carbon
TL;DR: Iijima et al. as mentioned in this paper reported the preparation of a new type of finite carbon structure consisting of needle-like tubes, which were produced using an arc-discharge evaporation method similar to that used for fullerene synthesis.
Journal ArticleDOI
A new family of mesoporous molecular sieves prepared with liquid crystal templates
Jeffrey S. Beck,James C. Vartuli,Wieslaw J. Roth,M. E. Leonowicz,Charles T. Kresge,Kirk D. Schmitt,Cynthia Ting-Wah Chu,David H. Olson,E. W. Sheppard,S. B. McCullen,J. B. Higgins,J.L. Schlenker +11 more
TL;DR: In this paper, the synthesis, characterization, and proposed mechanism of formation of a new family of silicatelaluminosilicate mesoporous molecular sieves designated as M41S is described.
Journal ArticleDOI
Design and synthesis of an exceptionally stable and highly porous metal-organic framework
TL;DR: In this article, an organic dicarboxylate linker is used in a reaction that gives supertetrahedron clusters when capped with monocarboxyates.
Book
Clathrate hydrates of natural gases
E. Dendy Sloan,Carolyn A. Koh +1 more
TL;DR: In this paper, the authors compared the properties of hydrates and ice with those of natural gas and showed the effect of thermodynamic inhibitors on the formation of hydrate formation and dissolution process.