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Journal ArticleDOI

Application of Metal-Organic Frameworks in Adsorptive Removal of Organic Contaminants from Water, Fuel and Air.

TLDR
In this article, the authors discuss the adsorptive removal of organic substances by using metal-organic frameworks (MOFs) for a safe environment, including pharmaceuticals/personal care products, pesticides, and dyes from water, S- or N-containing compounds from liquid fuel, and volatile organic compounds from air.
Abstract
Currently, our environment is contaminated with various toxic substances. Removal of such hazardous materials from water, air and fuel is important for sustainability. In this minireview, adsorptive removal of organic substances, by using metal-organic frameworks (MOFs), for our safe environment will be discussed. For example, removal of (i) pharmaceuticals/personal care products, pesticides, and dyes from water; (ii) S- or N-containing compounds from liquid fuel; and (iii) volatile organic compounds from air will be summarized. Moreover, plausible mechanisms to explain the observation will also be discussed. Finally, prospects in the field will be suggested for further research and development.

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Citations
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Journal ArticleDOI

Adsorptive removal of pesticides from water with metal–organic framework-based materials

TL;DR: A review of metal-organic frameworks (MOFs) for the removal of pesticides from aqueous solutions can be found in this paper, where the authors report the development of MOF-based adsorbents, including pristine MOFs, functionalized MOFs and MOF composites.
Journal ArticleDOI

Covalent organic framework-based materials: Synthesis, modification, and application in environmental remediation

TL;DR: Covalent organic framework (COF) as mentioned in this paper is a group of porous organic polymeric materials obtained from covalently attached organic building blocks, which exhibit positional control in two- or three-dimensional spaces through the predesigned and specified bonding of the monomer linkers.
Journal ArticleDOI

Metal–organic frameworks (MOFs) for the efficient removal of contaminants from water: Underlying mechanisms, recent advances, challenges, and future prospects

TL;DR: In this paper , the underlying adsorption and catalytic degradation mechanisms of inorganic contaminants and emerging organic contaminants (EOCs) in water by MOFs, and discusses the best performing three-dimensional (3D)-MOFs and MOFs-based composites that have been tested to date for IOCs and EOCs elimination.
Journal ArticleDOI

Graphene-Based Metal–Organic Framework Hybrids for Applications in Catalysis, Environmental, and Energy Technologies

TL;DR: In this paper , a review of current knowledge concerning the growth, structure, and properties of graphene derivatives, metal-organic frameworks (MOFs), and their graphene@MOF composites as well as the associated structure-property-performance relationships is presented.
Journal ArticleDOI

Adsorption and membrane separation for removal and recovery of volatile organic compounds.

TL;DR: In this article , the authors provide an up-to-date progress of adsorption and membrane separation for removal and recovery of VOCs, and a comprehensive understanding of their mechanisms, factors, and current application statuses are discussed.
References
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Journal ArticleDOI

Adsorption of benzotriazole and benzimidazole from water over a Co-based metal azolate framework MAF-5(Co)

TL;DR: MAF-5(Co) is suggested as a promising adsorbent for the removal of BTA and BZI from water over a newly synthesized metal-organic framework, MAF- 5(Co), which has the highest adsorption capacities.
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Adsorptive denitrogenation of model fuel with CuCl-loaded metal–organic frameworks (MOFs)

TL;DR: In this article, the porosity of the adsorbent was reduced after impregnation and the adsorption of nitrogen-containing compounds (NCCs) increased, which may be attributed to the π-complexation effect of the Cu+ sites of CuCl.
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Adsorptive removal of benzothiophene using porous copper-benzenetricarboxylate loaded with phosphotungstic acid

TL;DR: In this paper, the effect of PWAs on the adsorption/removal of benzothiophene (BT) has been studied and it was suggested that MOF-type materials, modified suitably, can be used in adsorptive desulfurization of fuels.
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Mesoporous metal-organic framework PCN-222(Fe): Promising adsorbent for removal of big anionic and cationic dyes from water

TL;DR: In this paper, a highly mesoporous metal-organic framework PCN-222(Fe), together with commercial activated carbon (AC), was applied for the removal of both cationic (brilliant green (BG), crystal violet (CV), and methylene blue (MB)) and anionic (acid red 1 (AR 1), acid blue 80 (AB 80) and methyl orange (MO)) dyes from water through adsorption.
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Ionic liquid@MIL-101 prepared via the ship-in-bottle technique: remarkable adsorbents for the removal of benzothiophene from liquid fuel.

TL;DR: Ionic liquids were synthesized inside a porous metal-organic framework (MIL-101) via a ship-in-bottle (SIB) technique that was very stable for the liquid phase adsorption of benzothiophene from liquid fuel.
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