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Journal ArticleDOI

Application of Metal-Organic Frameworks in Adsorptive Removal of Organic Contaminants from Water, Fuel and Air.

TLDR
In this article, the authors discuss the adsorptive removal of organic substances by using metal-organic frameworks (MOFs) for a safe environment, including pharmaceuticals/personal care products, pesticides, and dyes from water, S- or N-containing compounds from liquid fuel, and volatile organic compounds from air.
Abstract
Currently, our environment is contaminated with various toxic substances. Removal of such hazardous materials from water, air and fuel is important for sustainability. In this minireview, adsorptive removal of organic substances, by using metal-organic frameworks (MOFs), for our safe environment will be discussed. For example, removal of (i) pharmaceuticals/personal care products, pesticides, and dyes from water; (ii) S- or N-containing compounds from liquid fuel; and (iii) volatile organic compounds from air will be summarized. Moreover, plausible mechanisms to explain the observation will also be discussed. Finally, prospects in the field will be suggested for further research and development.

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Citations
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Journal ArticleDOI

Adsorptive removal of pesticides from water with metal–organic framework-based materials

TL;DR: A review of metal-organic frameworks (MOFs) for the removal of pesticides from aqueous solutions can be found in this paper, where the authors report the development of MOF-based adsorbents, including pristine MOFs, functionalized MOFs and MOF composites.
Journal ArticleDOI

Covalent organic framework-based materials: Synthesis, modification, and application in environmental remediation

TL;DR: Covalent organic framework (COF) as mentioned in this paper is a group of porous organic polymeric materials obtained from covalently attached organic building blocks, which exhibit positional control in two- or three-dimensional spaces through the predesigned and specified bonding of the monomer linkers.
Journal ArticleDOI

Metal–organic frameworks (MOFs) for the efficient removal of contaminants from water: Underlying mechanisms, recent advances, challenges, and future prospects

TL;DR: In this paper , the underlying adsorption and catalytic degradation mechanisms of inorganic contaminants and emerging organic contaminants (EOCs) in water by MOFs, and discusses the best performing three-dimensional (3D)-MOFs and MOFs-based composites that have been tested to date for IOCs and EOCs elimination.
Journal ArticleDOI

Graphene-Based Metal–Organic Framework Hybrids for Applications in Catalysis, Environmental, and Energy Technologies

TL;DR: In this paper , a review of current knowledge concerning the growth, structure, and properties of graphene derivatives, metal-organic frameworks (MOFs), and their graphene@MOF composites as well as the associated structure-property-performance relationships is presented.
Journal ArticleDOI

Adsorption and membrane separation for removal and recovery of volatile organic compounds.

TL;DR: In this article , the authors provide an up-to-date progress of adsorption and membrane separation for removal and recovery of VOCs, and a comprehensive understanding of their mechanisms, factors, and current application statuses are discussed.
References
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Journal ArticleDOI

Adsorptive denitrogenation of model fuels with porous metal-organic frameworks (MOFs): Effect of acidity and basicity of MOFs

TL;DR: In this paper, the effect of the acidity or basicity of porous metal-organic frameworks (MOFs) on the adsorptive removal of nitrogen-containing compounds (NCCs) was investigated.
Journal ArticleDOI

Design and fabrication of nanoporous adsorbents for the removal of aromatic sulfur compounds

TL;DR: Nanoporous adsorbents are highly efficient in selectively capturing aromatic sulfur compounds such as thiophene, benzothiopane, dibenzothiophene and 4,6-dimethyldibenzethiophene as discussed by the authors.
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Zeolitic imidazolate framework membranes for gas separation: A review of synthesis methods and gas separation performance

TL;DR: In this paper, the authors review the methods of ZIF membrane preparation and discuss their performance in separating condensable and incondensable gases and discuss ways to improve the gas separation performance.
Journal ArticleDOI

Adsorption and Diffusion of Benzene on Chromium-Based Metal Organic Framework MIL-101 Synthesized by Microwave Irradiation

TL;DR: In this paper, the maximum amount adsorbed of benzene on the synthesized MIL-101 was up to 16.5 mmol/g (or 176 wt %) at 288 K and 56.0 mbar.
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Nitrogen-Doped Porous Carbons from Ionic Liquids@MOF: Remarkable Adsorbents for Both Aqueous and Nonaqueous Media

TL;DR: The IMDCs derived from IL@MOF might have various applications, especially in adsorptions, based on high porosity, mesoporosity, doped nitrogen, and functional groups, depending on the possible applications in purification of water and fuel, respectively.
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