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Journal ArticleDOI

Application of Metal-Organic Frameworks in Adsorptive Removal of Organic Contaminants from Water, Fuel and Air.

TLDR
In this article, the authors discuss the adsorptive removal of organic substances by using metal-organic frameworks (MOFs) for a safe environment, including pharmaceuticals/personal care products, pesticides, and dyes from water, S- or N-containing compounds from liquid fuel, and volatile organic compounds from air.
Abstract
Currently, our environment is contaminated with various toxic substances. Removal of such hazardous materials from water, air and fuel is important for sustainability. In this minireview, adsorptive removal of organic substances, by using metal-organic frameworks (MOFs), for our safe environment will be discussed. For example, removal of (i) pharmaceuticals/personal care products, pesticides, and dyes from water; (ii) S- or N-containing compounds from liquid fuel; and (iii) volatile organic compounds from air will be summarized. Moreover, plausible mechanisms to explain the observation will also be discussed. Finally, prospects in the field will be suggested for further research and development.

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Citations
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Journal ArticleDOI

Adsorptive removal of pesticides from water with metal–organic framework-based materials

TL;DR: A review of metal-organic frameworks (MOFs) for the removal of pesticides from aqueous solutions can be found in this paper, where the authors report the development of MOF-based adsorbents, including pristine MOFs, functionalized MOFs and MOF composites.
Journal ArticleDOI

Covalent organic framework-based materials: Synthesis, modification, and application in environmental remediation

TL;DR: Covalent organic framework (COF) as mentioned in this paper is a group of porous organic polymeric materials obtained from covalently attached organic building blocks, which exhibit positional control in two- or three-dimensional spaces through the predesigned and specified bonding of the monomer linkers.
Journal ArticleDOI

Metal–organic frameworks (MOFs) for the efficient removal of contaminants from water: Underlying mechanisms, recent advances, challenges, and future prospects

TL;DR: In this paper , the underlying adsorption and catalytic degradation mechanisms of inorganic contaminants and emerging organic contaminants (EOCs) in water by MOFs, and discusses the best performing three-dimensional (3D)-MOFs and MOFs-based composites that have been tested to date for IOCs and EOCs elimination.
Journal ArticleDOI

Graphene-Based Metal–Organic Framework Hybrids for Applications in Catalysis, Environmental, and Energy Technologies

TL;DR: In this paper , a review of current knowledge concerning the growth, structure, and properties of graphene derivatives, metal-organic frameworks (MOFs), and their graphene@MOF composites as well as the associated structure-property-performance relationships is presented.
Journal ArticleDOI

Adsorption and membrane separation for removal and recovery of volatile organic compounds.

TL;DR: In this article , the authors provide an up-to-date progress of adsorption and membrane separation for removal and recovery of VOCs, and a comprehensive understanding of their mechanisms, factors, and current application statuses are discussed.
References
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Journal ArticleDOI

Remarkable adsorptive removal of nitrogen-containing compounds from a model fuel by a graphene oxide/MIL-101 composite through a combined effect of improved porosity and hydrogen bonding.

TL;DR: The improved porosity of the GnO/MIL-101 composite was utilized for adsorptive denitrogenation (ADN) of a model fuel where indole (IND) and quinoline (QUI) were used as nitrogen-containing compounds (NCCs) and it was found that both IND and QUI showed improved adsorption on the composite compared with pristine MIL-101 or GnO due to the improved Porosity.
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Hybridization of metal–organic frameworks and task-specific ionic liquids: fundamentals and challenges

TL;DR: In this review, as an originator of MTHMs, a logical and easy-to-follow story about the hybridization of MOFs and TSILs is presented: from their origins, to the motivation behind hybridization, to a strategy to carry out the Hybridization, and finally to the consequences of hybridization based on a few illustrative examples.
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Adsorptive removal of an eight-component volatile organic compound mixture by Cu-, Co-, and Zr-metal-organic frameworks: Experimental and theoretical studies

TL;DR: In this article, four types of broadly studied metal-organic frameworks (MOFs) (i.e., Cu- (MOF-199), Co- (Co-CUK-1), Zr- (UiO-66 (U6)) were effectively synthesized, characterized, and studied as the adsorbents along with a microporous activated carbon (AC) as a reference.
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Effect of central metal ions of analogous metal-organic frameworks on the adsorptive removal of benzothiophene from a model fuel.

TL;DR: The CuCl₂/V-BDC adsorbed BT remarkably well compared to the virgin V-B DCs which suggests a specific favorable interaction (π-complexation) between the obtained Cu(+) in the CuCl ₂ /V- BDC and BT.
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