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Aqueous Ammonia Equilibrium Calculations: Effect of pH and Temperature

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TLDR
A critical evaluation of the literature data on the ammonia–water equilibrium system has been carried out and results of calculations of values of pKa at different temperatures and of percent of NH3 in aqueous ammonia solutions of zero salinity as a function of pH and temperature are presented.
Abstract
The toxicity of ammonia to fishes has been attributed to the un-ionized ammonia chemical species present in aqueous solution Because the percent of total ammonia present as un-ionized ammonia (NH3) is so dependent upon pH and temperature, an exact understanding of the aqueous ammonia equilibrium is important for toxicity studies A critical evaluation of the literature data on the ammonia–water equilibrium system has been carried out Results of calculations of values of pKa at different temperatures and of percent of NH3 in aqueous ammonia solutions of zero salinity as a function of pH and temperature are presented

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Citations
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Journal ArticleDOI

Effects of Environmental Sodium Chloride on Percent Hatch, Yolk Utilization, and Survival of Channel Catfish Fry

TL;DR: The results indicate that addition of NaCI to hatchery water supplies can increase production of channel catfish fry, but additional research is needed before this practice can be recommended on a commercial basis.
Journal ArticleDOI

Monitoring oxidative stress, immune response, Nrf2/NF-κB signaling molecules of Rhynchocypris lagowski living in BFT system and exposed to waterborne ammonia.

TL;DR: The results indicated that BFT could enhance growth, antioxidant and immune response and regulate Nrf2 and NF-κB related genes expression in R. lagowski, with most excellent effects in fish given C:N 20:1 group.
Journal ArticleDOI

Complexation of copper in the effluent of a sewage treatment plant and an estimate of its influence on toxicity to coho salmon

James A. Buckley
- 01 Jan 1983 - 
TL;DR: In this paper, the cupric ion electrode of the complexing capacity of the effluent from a sewage treatment plant (STPE) averaged 0.300 mg 1 −1, of which 67% was due to compounds of ⩽ 10,000 MW.
Journal ArticleDOI

The distribution of nitrogen species in polluted Onondaga Lake, N.Y., U.S.A.

TL;DR: In this paper, the temporal and vertical distributions of four N species, N03−, NO2−, total ammonia (T-NH3), and free ammonia (NH3) are documented for Onondaga Lake, an urban, polluted, hypereutrophic, dimictic, lake that receives a very high load of T-NH 3.
Journal ArticleDOI

Evaluation of a trickling biofilter in a recirculating aquaculture system containing channel catfish

TL;DR: Water quality was good to excellent when the packed towers contained the medium, and the rate of production was influenced by the combined effect of concentrations of dissolved oxygen, NH 3 N and/or NO 2 − N otherwise considered safe.
References
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Journal ArticleDOI

The Percent Un-Ionized Ammonia in Aqueous Ammonia Solutions at Different pH Levels and Temperatures

TL;DR: In this article, it was shown that the un-ionized ammonia molecule and not the ammonium ion is the form of the toxicant harmful to fish, and the amount of unionised ammonia in the water was quantified.
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