Journal ArticleDOI
Catalysed aerobic dehydrogenation of amines and an X-ray crystal structure of a bis(benzylamine) ruthenium(II) porphyrin species
Alan J. Bailey,Brian R. James +1 more
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TLDR
In this article, the trans-[RuVI(tmp)(O)2] 1 (tmp = dianion of 5,10,15,20-tetramesitylporphyrin) catalytically dehydrogenates primary and secondary amines in the presence of air; possible reaction steps involve a disproportionation reaction that generates a RuII intermediate.About:
This article is published in Chemical Communications.The article was published on 1996-01-01. It has received 112 citations till now. The article focuses on the topics: Disproportionation & Ruthenium.read more
Citations
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Journal ArticleDOI
Gold-catalyzed carbon-heteroatom bond-forming reactions.
TL;DR: Application to Total Synthesis 1699 6.1.
Journal ArticleDOI
Ruthenium-Catalyzed Reactions for Organic Synthesis.
Journal ArticleDOI
Gold Supported on Hydroxyapatite as a Versatile Multifunctional Catalyst for the Direct Tandem Synthesis of Imines and Oximes
TL;DR: Two birds with one auric stone: the title system acts as a highly efficient heterogeneous catalyst for the one-pot tandem synthesis of imines or oximes from alcohols and the corresponding amines under mild conditions.
Journal ArticleDOI
Highly Efficient Oxidation of Amines to Imines by Singlet Oxygen and Its Application in Ugi-Type Reactions
TL;DR: A protocol was developed for oxidative Ugi-type reactions with singlet oxygen as the oxidant that has been used to synthesize C1- and N-functionalized benzylic amines in up to 96% yields.
Journal ArticleDOI
Developments in the Aerobic Oxidation of Amines
TL;DR: In this paper, a review of amine oxidation reactions is presented, highlighting both the major achievements and the challenges that still remain in this important area and highlighting the potential for sustainable production of key N-containing building blocks for modern chemical industry.
References
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Journal ArticleDOI
Aerobic epoxidation of olefins with ruthenium porphyrin catalysts
John T. Groves,Robert E. Quinn +1 more
TL;DR: Le dioxo(tetramesitylporphyrinato) ruthenium(VI) catalyse l'epoxydation des olefines (cyclooctene, cis-and trans-β-methylstyrene, norbornene) a temperature and pression ambiantes
Journal ArticleDOI
Characterization of an oxoruthenium(IV) porphyrin complex
John T. Groves,Kwang-Hyun Ahn +1 more
TL;DR: Caracterisation du complexe cite dans le titre, qui est un intermediaire dans l'oxygenation a l'air de Ru(II) TMP en Ru(III TMP(O) 2. TMP=tetramesitylporphyrine
Journal ArticleDOI
Isolation and characterization of a (diphenylamido)ruthenium(IV) porphyrin
Book ChapterDOI
Selective Oxidations Catalyzed By Dioxo(Porphyrinato)Ruthenium(VI) Species
TL;DR: The trans-Ru(porp) (O)2 complexes as discussed by the authors, where porp = the dianion of 5,10,15,20-tetramesityl porphyrinato)ruthenium(VI) species are capable of transferring O-atoms to, or abstracting H-atom from, several diverse types of substrates; as O2 is the O-atom source, the systems represent a major advance in O2-oxidation chemistry and offer an excellent opportunity for detailed mechanistic insight into oxidations of biological
Journal ArticleDOI
Preparation and crystal structure of trans-dihydroxo-[tetrakis(2,6-dichlorophenyl)porphinato]ruthenium(IV)·2toluene
Patrick Dubourdeaux,Patrick Dubourdeaux,Manuella Tavares,Manuella Tavares,André Grand,André Grand,René Ramasseul,René Ramasseul,Jean-Claude Marchon,Jean-Claude Marchon +9 more
TL;DR: Trans-dihydroxo-[tetrakis(2,6-dichlorophenyl)porphinato]ruthenium(IV) was prepared by meta-chloroperbenzoic acid oxidation of [Ru(CO)(TDCPP)] in dichloromethane-toluene, and its crystal structure was reported.
Related Papers (5)
Efficient Heterogeneous Aerobic Oxidation of Amines by a Supported Ruthenium Catalyst
Kazuya Yamaguchi,Noritaka Mizuno +1 more