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Journal ArticleDOI

Cellulose nanomaterial reinforced polymer nanocomposites

TLDR
In this article, the authors focus on cellulose materials as filler in polymer nanocomposites and their properties depend on the type of nanomaterial used, but the crucial point is the processing technique.
Abstract
Several forms of cellulose nanomaterials, notably cellulose nanocrystals and cellulose nanofibrils, exhibit attractive properties and are potentially useful for a large number of industrial applications. These include the paper and cardboard industry, use as reinforcing filler in polymer nanocomposites, basis for low-density foams, additive in adhesives and paints, as well as a wide variety of filtration, electronic, food, hygiene, cosmetic, and medical products. This entry focuses on cellulose materials as filler in polymer nanocomposites. The ensuing mechanical properties obviously depend on the type of nanomaterial used, but the crucial point is the processing technique. The emphasis is on the melt processing of such nanocomposite materials that has not yet been properly resolved and remains a challenge.

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Citations
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Recent advances in nanocellulose processing, functionalization and applications: a review

TL;DR: The features of nanocellulosic nanomaterials are mainly dependent on the extraction technique, source and efficient subsequent surface functionalization as discussed by the authors, which is a major issue owing to the expansion of petroleum-based synthetic materials and products, and therefore the development of novel and effective synthetic materials that have ecofriendly and economical properties is of significant interest.
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Research progress in bio-based self-healing materials

TL;DR: In this article, a review summarizes research progress in bio-based self-healing materials developed over the past several decades and evaluates the role of biomass playing, including sensors, energy storage devices, biomaterials and so on.
Journal ArticleDOI

Fast IR-Actuated Shape-Memory Polymers Using in Situ Silver Nanoparticle-Grafted Cellulose Nanocrystals.

TL;DR: This study proposes to design plasmonic silver nanoparticles (AgNPs) grafted onto cellulose nanocrystals (CNCs) as an efficient plAsmonic system for fast and remote actuation and incorporates them at low loading into poly(ε-caprolactone) (PCL)-based networks with shape-memory properties.
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Self-healing and injectable polysaccharide hydrogels with tunable mechanical properties

TL;DR: An injectable polysaccharide hydrogel based on cellulose acetoacetate (CAA), hydroxypropyl chitosan (HPCS), and amino-modified cellulose nanocrystals (CNC-NH2) exhibited pH- responsive properties and excellent stability under physiological conditions and demonstrates good biocompatibility of CNCs reinforced hydrogels.
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Synergistic Reinforcing Mechanisms in Cellulose Nanofibrils Composite Hydrogels: Interfacial Dynamics, Energy Dissipation, and Damage Resistance

TL;DR: A model system of composite hydrogel reinforced with cellulose nanofibrils, where the integration of reversible hydrogen bonds into a lightly covalently cross-linked polyacrylamide (PAAm) matrix yields the dual cross- linked networks with synergistically improved strength, modulus, and toughness, is studied.
References
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Journal ArticleDOI

Cellulose nanomaterials review: structure, properties and nanocomposites

TL;DR: This critical review provides a processing-structure-property perspective on recent advances in cellulose nanoparticles and composites produced from them, and summarizes cellulOSE nanoparticles in terms of particle morphology, crystal structure, and properties.
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Review of Recent Research into Cellulosic Whiskers, Their Properties and Their Application in Nanocomposite Field

TL;DR: There are numerous examples where animals or plants synthesize extracellular high-performance skeletal biocomposites consisting of a matrix reinforced by fibrous biopolymers, which occur as whisker-like microfibrils that are biosynthesized and deposited in a continuous fashion.
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Nanocellulose: a new ageless bionanomaterial

TL;DR: In this paper, the hierarchical structure of cellulose is exploited to extract nanoparticles from this naturally occurring polymer, which can be used for the processing of polymer nanocomposites.
Journal ArticleDOI

Cellulose whiskers versus microfibrils: influence of the nature of the nanoparticle and its surface functionalization on the thermal and mechanical properties of nanocomposites.

TL;DR: It was proved that the chemical treatment clearly improves the ultimate properties of the nanocomposites and significant differences were reported according to the nature of the nanoparticle and amount of nanofillers used as reinforcement.
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