Journal ArticleDOI
Characterisation of N-vinyl-2-pyrrolidone-based hydrogels prepared by a Diels–Alder click reaction in water
TLDR
In this article, the Diels-Alder reaction in water for the first time was used to synthesize copolymers of N -vinyl-2-pyrrolidone (VP) and furfuryl methacrylate (FM).About:
This article is published in European Polymer Journal.The article was published on 2010-05-01. It has received 36 citations till now. The article focuses on the topics: Diels–Alder reaction & Maleimide.read more
Citations
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Journal ArticleDOI
The furan/maleimide Diels–Alder reaction: A versatile click–unclick tool in macromolecular synthesis
TL;DR: A review of the application of the Diels-Alder (DA) reaction between furan and maleimide moieties can be found in this paper, where the authors provide a critical survey covering a few decades of growing interest in the application to polymer chemistry of the DA reaction.
Journal ArticleDOI
Diels–Alder “click” reactions: recent applications in polymer and material science
TL;DR: In this article, the authors discuss the recent reports concerned with the use of DA "click" reactions in the synthesis of various macromolecular architectures, bioconjugates and hybrid materials.
Journal ArticleDOI
Diels−Alder Click Cross-Linked Hyaluronic Acid Hydrogels for Tissue Engineering
TL;DR: Rheological and degradation studies demonstrate that the Diels-Alder click reaction is a suitable cross-linking method for HA and these HA cross-linked hydrogels were shown to be cytocompatible and may represent a promising material for soft tissue engineering.
Journal ArticleDOI
Progress toward robust polymer hydrogels
TL;DR: In this paper, the authors highlight new developments in tough hydrogel materials in terms of their enhanced mechanical performance and their corresponding toughening mechanisms and provide a description of the fracture process that may be occurring.
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Multifunctional Hydrogel with Good Structure Integrity, Self-Healing, and Tissue-Adhesive Property Formed by Combining Diels-Alder Click Reaction and Acylhydrazone Bond.
TL;DR: A double cross-linked network was designed and prepared by combining Diels-Alder click reaction and acylhydrazone bond, which resulted in hydrogel's self-healing property and controlled the on-off switch of network cross-link density.
References
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Journal ArticleDOI
A Thermally Re-mendable Cross-Linked Polymeric Material
Xiangxu Chen,Matheus Adrianus Dam,Kanji Ono,Ajit Mal,Hongbin Shen,Steven Nutt,Kevin Sheran,Fred Wudl +7 more
TL;DR: A transparent organic polymeric material that can repeatedly mend or “re-mend” itself under mild conditions and is a tough solid at room temperature and below with mechanical properties equaling those of commercial epoxy resins.
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Thermosensitive chitosan-Pluronic hydrogel as an injectable cell delivery carrier for cartilage regeneration.
TL;DR: The results suggested that the CP hydrogel has potential as an injectable cell delivery carrier for cartilage regeneration and could serve as a new biomaterial for tissue engineering.
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Diels−Alder Reactions with Novel Polymeric Dienes and Dienophiles: Synthesis of Reversibly Cross-Linked Elastomers
TL;DR: In this paper, highly flexible copolymers bearing dienic or dienophilic moieties were prepared by either free radical copolymerization of hexyl acrylate and 2-furfuryl methacrylate or the chemical modification of siloxane copolymics with pendant primary propylamino functions.
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Rheological and Chemical Analysis of Reverse Gelation in a Covalently Cross-Linked Diels−Alder Polymer Network
Brian J. Adzima,H. Alan Aguirre,Christopher J. Kloxin,Timothy F. Scott,Christopher N. Bowman +4 more
TL;DR: A network polymer, incorporating dynamic and reversible crosslinks, was synthesized using the Diels-Alder reaction, demonstrating significant depolymerization via the retro-Diels- alder reaction.
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Synthesis and characterization of PVP/AAc copolymer hydrogel and its applications in the removal of heavy metals from aqueous solution
TL;DR: In this paper, the effects of preparation parameters such as PVP content in the hydrogel and irradiation dose on the swelling behavior of the PVP/AAc copolymer hydrogels were studied.