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Journal ArticleDOI

Chemical sensors based on amplifying fluorescent conjugated polymers.

TLDR
This review restricts discussions to purely fluorescence-based methods using conjugated polymers (CPs) and details earlier research in this Introduction to illustrate fundamental concepts and terminology that underpin the recent literature.
Abstract
The field of chemical sensing is becoming ever more dependent upon novel materials. Polymers, crystals, glasses, particles, and nanostructures have made a profound impact and have endowed modern sensory systems with superior performance. Electronic polymers have emerged as one of the most important classes of transduction materials; they readily transform a chemical signal into an easily measured electrical or optical event. Although our group reviewed this field in 2000,1 the high levels of activity and the impact of these methods now justify a subsequent review as part of this special issue. In this review we restrict our discussions to purely fluorescence-based methods using conjugated polymers (CPs). We further confine our detailed coverage to articles published since our previous review and will only detail earlier research in this Introduction to illustrate fundamental concepts and terminology that underpin the recent literature.

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Citations
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Journal ArticleDOI

Aggregation-Induced Emission: Together We Shine, United We Soar!

TL;DR: This paper presents a meta-analysis of the chiral stationary phase transition of Na6(CO3)(SO4)2, a major component of the response of the immune system to Na2CO3.
Journal ArticleDOI

Aggregation-induced emission

TL;DR: In this critical review, recent progress in the area ofAIE research is summarized and typical examples of AIE systems are discussed, from which their structure-property relationships are derived.
Journal ArticleDOI

Gold nanoparticles in chemical and biological sensing.

TL;DR: The advent of AuNP as a sensory element provided a broad spectrum of innovative approaches for the detection of metal ions, small molecules, proteins, nucleic acids, malignant cells, etc. in a rapid and efficient manner.
Journal ArticleDOI

Luminescent metal–organic frameworks for chemical sensing and explosive detection

TL;DR: This review intends to provide an update of work published since then and focuses on the photoluminescence properties of MOFs and their possible utility in chemical and biological sensing and detection.
Journal ArticleDOI

Aggregation-induced emission: phenomenon, mechanism and applications.

TL;DR: The restriction of intramolecular rotation is identified as a main cause for the AIE effect and a series of new fluorescent and phosphorescent AIE systems with emission colours covering the entire visible spectral region and luminescence quantum yields up to unity are developed.
References
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Journal ArticleDOI

Selective Colorimetric Detection of Polynucleotides Based on the Distance-Dependent Optical Properties of Gold Nanoparticles

TL;DR: A highly selective, colorimetric polynucleotide detection method based on mercaptoalkyloligonucleotide-modified gold nanoparticle probes is reported, which can detect about 10 femtomoles of an oligonucleotide.
Journal ArticleDOI

Conjugated polymer-based chemical sensors.

TL;DR: When considering new sensory technologies one should look to nature for guidance, as living organisms have developed the ultimate chemical sensors.
Journal ArticleDOI

Fluorescent Porous Polymer Films as TNT Chemosensors: Electronic and Structural Effects

TL;DR: In this paper, the synthesis, spectroscopy, and fluorescence quenching behavior of pentiptycene-derived phenyleneethynylene polymers, 1−3, are reported.
Journal ArticleDOI

Highly sensitive biological and chemical sensors based on reversible fluorescence quenching in a conjugated polymer

TL;DR: It is established that the dramatic quenching results from weak complex formation [polymer(-)/quencher(+)], followed by ultrafast electron transfer from excitations on the entire polymer chain to the quencher, with a time constant of 650 fs.
Journal ArticleDOI

Porous Shape Persistent Fluorescent Polymer Films: An Approach to TNT Sensory Materials

TL;DR: In this article, the rigid three-dimensional pentiptycene moieties are incorporated in conjugated polymer films to prevent π-stacking or excimer formation.
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