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Comprehensive inorganic chemistry
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TLDR
In this article, the transition elements involving metal-metal bonds are defined and an introductory essay is given, along with a discussion of homogeneous catalysis and transition metal chemistry, B L Shaw & N I Tucker.Abstract:
(partial) The lanthanides, T Moeller. Carbonyls, cyanides, isocyanides and nitrosyls, W P Griffith. Compounds of the transitional elements involving metal-metal bonds, D L Kepert. Transition metal, J C Green & M V H Green. Nonstoichiometric compounds. An introductory essay, D J M Bevan. Tungsten bronzes, vanadium bronzes and related compounds, P Hagenmuller. Isopolyanions and Heteropolyanions, D L Kepert. Ionic compounds, G C Allen. Transition metal chemistry, B F G Johnson. Organo-transition metal compounds and related aspects of homogenous catalysis, B L Shaw & N I Tucker.read more
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Coalescence enhanced synthesis of nanoparticles to control size, morphology and crystalline phase at high concentrations
Donggeun Lee,Mansoo Choi +1 more
TL;DR: In this article, the enhancement of coalescence of nanoparticles using laser beam irradiation on aggregates formed in flames can be a solution for this problem and successfully controls the size, morphology, and crystalline phase of high concentration nanoparticles of silica and titania.
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Why is hydrofluoric acid a weak acid
TL;DR: The infrared vibrational spectra of amorphous solid water thin films doped with HF at 40 K reveal a strong continuous absorbance in the 1000-3275 cm(-1) range, supporting the interpretation that dilute HF aqueous solutions behave as weak acids largely due to the large positive reaction entropy resulting from the structure making character of the hydrated fluoride ion.
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Synthesis and spectroscopic studies of new binuclear transition metal complexes of Schiff bases derived from 4,6-diacetylresorcinol
Adel A.A. Emara,Omima M.I. Adly +1 more
TL;DR: In this paper, the Schiff base, H4L1 and H2L2, ligands were synthesized by condensation of 4,6-diacetylresorcinol with o-aminophenol or o-phenylenediamine.
Journal ArticleDOI
Furnace gas‐phase chemistry of silicon oxynitridation in N2O
K. A. Ellis,Robert A. Buhrman +1 more
TL;DR: In this article, the authors show that the NOx species varies strongly with the flow rate of N2O and that this can lead to a substantial variation in the concentration of N in the oxynitride as a function of N 2O flow.
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Structural requirements for Hg(II) antidotes
TL;DR: In this paper, the structural properties of Hg(II) complexes with thiol containing ligands, the stability constants for such systems and the relative efficacy of 29 compounds as antidotes for mercury poisoning have been investigated.