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Comprehensive inorganic chemistry
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In this article, the transition elements involving metal-metal bonds are defined and an introductory essay is given, along with a discussion of homogeneous catalysis and transition metal chemistry, B L Shaw & N I Tucker.Abstract:
(partial) The lanthanides, T Moeller. Carbonyls, cyanides, isocyanides and nitrosyls, W P Griffith. Compounds of the transitional elements involving metal-metal bonds, D L Kepert. Transition metal, J C Green & M V H Green. Nonstoichiometric compounds. An introductory essay, D J M Bevan. Tungsten bronzes, vanadium bronzes and related compounds, P Hagenmuller. Isopolyanions and Heteropolyanions, D L Kepert. Ionic compounds, G C Allen. Transition metal chemistry, B F G Johnson. Organo-transition metal compounds and related aspects of homogenous catalysis, B L Shaw & N I Tucker.read more
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The relative acute toxicity of continuous and intermittent exposures of chlorine and bromine to aquatic organisms in the presence and absence of ammonia
TL;DR: In this paper, the authors evaluated the acute toxicity of bromine oxidants in both continuous and intermittent exposure scenarios, and found that they are two to five times more toxic than chlorine oxidants.
Book ChapterDOI
Features of organolanthanide complexes
TL;DR: In this paper, the intrinsic properties of the lanthanide elements guarantee promising applications in the fields of catalysis and material science, and how to cope with these features on a molecular level and under anaerobic conditions is discussed, including thermodynamic and kinetic considerations.
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Enabling Catalyst Discovery through Machine Learning and High-Throughput Experimentation
TL;DR: A novel framework that incorporates machine learning algorithms with experimental high-throughput catalytic data and elemental properties to discover new materials was described, which led to the discovery of several novel catalyst compositions for ammonia decomposition.
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Red Light-Triggered CO Release from Mn2(CO)10 Using Triplet Sensitization in Polymer Nonwoven Fabrics
TL;DR: By mixing in solution a triplet photosensitizer with the photoCORM and shining red light, energy transfer occurs from triplet excited-state 3PS* to a photolabile triplet state of Mn2(CO)10, which, like under near-UV irradiation, led to complete release of carbonyls.
Journal ArticleDOI
Calcite‐CO2 mixed into CO2‐free air: a new CO2‐in‐air stable isotope reference material for the VPDB scale
TL;DR: In this paper, a dedicated acid reaction and air mixing system (ARAMIS) was designed to generate reliable and long-lasting stable isotope ratio standard for CO 2 in samples of clean air, CO 2 is liberated from well-characterized carbonate material and mixed with CO 2 -free air.