Journal ArticleDOI
“Controlled” Synthesis and Characterization of High Molecular Weight Methyl Methacrylate/tert-Butyl Methacrylate Diblock Copolymers via ATRP
TLDR
Atom transfer radical polymerization (ATRP) of methyl methacrylate (MMA) using CuCl/N, N,N,N',N N, N', N N,Abstract:
Atom transfer radical polymerization (ATRP) of methyl methacrylate (MMA) using CuCl/N,N,N‘,N‘ ‘,N‘ ‘‘,N‘ ‘‘-hexamethyltriethylenetetramine (HMTETA) as a catalyst system with 2,2,2-trichloroethanol ...read more
Citations
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Journal ArticleDOI
Polymeric Surfactants : Synthesis, Properties, and Links to Applications
Journal ArticleDOI
Rapid Bonding/Debonding on Demand: Reversibly Cross-Linked Functional Polymers via Diels−Alder Chemistry
TL;DR: In this article, the synthesis of a poly(methyl methacrylate) (PMMA) chain bearing Cp functionality at both chain ends and a trifunctional pyridinyldithioformate linker was reported.
Journal ArticleDOI
Well-Defined Liquid-Crystalline Diblock Copolymers with an Azobenzene Moiety: Synthesis, Photoinduced Alignment and their Holographic Properties
TL;DR: A series of liquid-crystalline (LC) diblock copolymers with an azobenzene moiety in the side chain were prepared by atom transfer radical polymerization (ATRP).
Journal ArticleDOI
New poly(acrylic acid) containing segmented copolymer structures by combination of ''click" chemistry and atom transfer radical polymerization
Wim Van Camp,Vanessa Germonpré,Laetitia Mespouille,Philippe Dubois,Eric J. Goethals,Filip Du Prez +5 more
TL;DR: In this paper, the combination of atom transfer radical polymerization (ATRP) of 1-ethoxyethyl acrylate (EEA) and the copper(I) catalyzed 1,3-dipolar cycloaddition reaction of azides and terminal alkynes was evaluated as a method to synthesize diverse amphiphilic copolymer structures.
Journal ArticleDOI
Preparation of gradient copolymers via ATRP in miniemulsion. II. Forced gradient
TL;DR: A series of forced gradient copolymers with different controlled distribution of monomer units along the copolymer backbone were successfully prepared by atom transfer radical polymerization in miniemulsion as discussed by the authors.
References
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Journal ArticleDOI
Living free-radical polymerization by reversible addition - Fragmentation chain transfer: The RAFT process
John Chiefari,Y. K. Chong,Frances Ercole,Julia Krstina,Justine Leigh Jeffery,Tam P. T. Le,Roshan T. A. Mayadunne,Gordon Francis Meijs,Catherine Louise Moad,Graeme Moad,Ezio Rizzardo,San H. Thang +11 more
TL;DR: The authors proposed a reversible additive-fragmentation chain transfer (RAFT) method for living free-radical polymerization, which can be used with a wide range of monomers and reaction conditions and in each case it provides controlled molecular weight polymers with very narrow polydispersities.
Journal ArticleDOI
Metal-catalyzed living radical polymerization.
Journal ArticleDOI
Polymerization of Methyl Methacrylate with the Carbon Tetrachloride/Dichlorotris- (triphenylphosphine)ruthenium(II)/Methylaluminum Bis(2,6-di-tert-butylphenoxide) Initiating System: Possibility of Living Radical Polymerization
Journal ArticleDOI
Controlled Living Radical Polymerization - Halogen Atom-Transfer Radical Polymerization Promoted by a Cu(I)Cu(II) Redox Process
TL;DR: An extension of ATRA to atom transfer radical addition, ATRP, provided a new and efficient way to conduct controlled/living radical polymerization as mentioned in this paper, using a simple alkyl halide, R-X (X = Cl and Br), as an initiator and a transition metal species complexed by suitable ligand(s), M t n /L x, e.g., CuX/2,2'-bipyridine, as a catalyst.