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Cu based Metal Organic Framework (Cu-MOF) for electrocatalytic hydrogen evolution reaction

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The article was published on 2020-11-18 and is currently open access. It has received 42 citations till now. The article focuses on the topics: Metal-organic framework & Copper.

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Multiscale design of 3D metal–organic frameworks (M−BTC, M: Cu, Co, Ni) via PLAL enabling bifunctional electrocatalysts for robust overall water splitting

TL;DR: In this paper , a transition-metal-based 3D metal-organic framework (MOF) was synthesized by pulsed laser ablation in dimethylformamide to influence hydrogen and oxygen evolution reactions (HER and OER).
Journal ArticleDOI

The potential of electrochemistry for one-pot and sensitive analysis of patent blue V, tartrazine, acid violet 7 and ponceau 4R in foodstuffs using IL/Cu-BTC MOF modified sensor.

TL;DR: In this paper, a sensitive sensor was developed based on copper BTC metal-organic framework (Cu-BTC MOF) and 1-ethyl-3-methylimidazolium chloride as an ionic liquid (IL) in an attempt to modify the carbon paste electrode and to improve the active surface area and electric conductivity so that electron transfer is faster for electro analysis.
Journal ArticleDOI

The potential of electrochemistry for one-pot and sensitive analysis of patent blue V, tartrazine, acid violet 7 and ponceau 4R in foodstuffs using IL/Cu-BTC MOF modified sensor

TL;DR: In this paper , a sensitive sensor was developed based on copper BTC metal-organic framework (Cu-BTC MOF) and 1-ethyl-3-methylimidazolium chloride as an ionic liquid (IL) in an attempt to modify the carbon paste electrode and to improve the active surface area and electric conductivity so that electron transfer is faster for electro analysis.
Journal ArticleDOI

Photocatalytic degradation effect and mechanism of Karenia mikimotoi by non-noble metal modified TiO2 loading onto copper metal organic framework (SNP-TiO2@Cu-MOF) under visible light.

TL;DR: In this article , the SNP-TiO2@Cu-MOF composite was prepared successfully by loading non-noble metal modified TiO2 (SNP-TiOnO2) on the surface of copper metal organic skeleton (Cu-MoF), and compared the inactivation efficiency of different photocatalysts to Karenia mikimotoi (K.mikimoto) under visible light.
References
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Journal ArticleDOI

Synthesis and characterization of conductive copper-based metal-organic framework/graphene-like composites

TL;DR: In this article, a metal-organic framework (MOF) incorporating conductive graphene-like layers was synthesized and characterized, and the selected MOF, HKUST-1, combines high surface area, water stability, simple preparation and low costs.
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Self-supported nanoporous cobalt phosphosulfate electrodes for efficient hydrogen evolution reaction

TL;DR: In this article, a simple method that can synthesize the self-supported nanoporous cobalt phosphosulfate (CoP|S) electrocatalyst was presented, which can accelerate charge transfer of CoP, therefore improving catalytic HER activity.
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Nanostructured metal-N-C electrocatalysts for CO2 reduction and hydrogen evolution reactions

TL;DR: In this paper, a series of electrocatalysts from the metal-nitrogen-carbon (M-N-C) family was synthesized by a sacrificial support method, where the salts of Cu, Mo, Pr, and Ce were employed as metal-precursors while the N-C network formed by the high temperature pyrolysis of aminoantipyrine (AAPyr) organic compound.
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Electrodeposited Mo3S13 Films from (NH4)2Mo3S13·2H2O for Electrocatalysis of Hydrogen Evolution Reaction.

TL;DR: The prepared Mo3S13 films exhibit highly efficient electrocatalytic activity for HER and achieve a current density of 10 mA/cm2 at an overpotential of 200 mV with an onset potential of 130 mV vs RHE and a Tafel slope of 37 mV/dec, which is superior to other reported MoS2 films.
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NiCo2O4 nanowire arrays rich in oxygen deficiencies for hydrogen evolution reaction

TL;DR: In this paper, a simple strategy to significantly enhance the catalytic activities of NiCo2O4 nanowire arrays by tuning the amount of oxygen vacancies was reported, which showed significantly improved catalytic activity toward hydrogen evolution reaction with the requirement of 104mV overpotential to afford 10mA cm−2, 122mV less than that for air-sintered NiCo 2O4 (226mV).
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