Journal ArticleDOI
Cyclic enaminones. Part II: applications as versatile intermediates in alkaloid synthesis
TLDR
This brief review discusses the application of cyclic enaminones as building blocks, as well as potential intermediates in the total synthesis of selected alkaloids.About:
This article is published in Chemical Communications.The article was published on 2015-11-05. It has received 71 citations till now.read more
Citations
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Journal ArticleDOI
Domino Reactions Based on Combinatorial Bond Transformations in Electron-Deficient Tertiary Enamines.
Jie-Ping Wan,Yong Gao +1 more
TL;DR: The research advances in organic synthesis via domino reactions making use of the combinatorial C-N, C=C, C-H, and other bond transformations of electron-deficient tertiary enamines are presented.
Journal ArticleDOI
Total Synthesis of Isodaphlongamine H: A Possible Biogenetic Conundrum
TL;DR: The first synthetic efforts toward the total synthesis of isodaphlongamine H, a calyciphylline B-type alkaloid, exhibit promising inhibitory activity against a panel of human cancer cell lines.
Journal ArticleDOI
Cyclic enaminones. Part I: stereocontrolled synthesis using diastereoselective and catalytic asymmetric methods
TL;DR: Three approaches for stereoselective syntheses of cyclic enaminones and their functionalized derivatives are summarized: chiral substrates (chirons) as starting materials, syntheses employing non-catalytic (stoichiometric) reagents, and catalytic asymmetric methods.
Journal ArticleDOI
Single‐Face/All‐cis Arene Hydrogenation by a Supported Single‐Site d0 Organozirconium Catalyst
Madelyn M. Stalzer,Christopher P. Nicholas,Alak Bhattacharyya,Alessandro Motta,Massimiliano Delferro,Tobin J. Marks +5 more
TL;DR: Kinetic/mechanistic and DFT analysis argue that stereoselection involves rapid, sequential H2 delivery to a single catalyst-bound arene face, versus any competing intramolecular arene π-face interchange.
Journal ArticleDOI
The nonlinear optical properties of two dihydropyridones derived from curcumin.
TL;DR: Two dihydropyridone compounds are synthesized from curcumin using microwave radiation using the Fraunhofer approximation of the Fresnel-Kirchhoff diffraction with good quantitative and excellent qualitative agreements compared with experimental results.
References
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Journal ArticleDOI
Asymmetric Transition Metal-Catalyzed Allylic Alkylations.
TL;DR: The focus of this review is on the area of enantioselective transition metal-catalyzed allylic alkylations which may involve C-C as well as C-X (X ) H or heteroatom) bond formation.
Journal ArticleDOI
Asymmetric transition-metal-catalyzed allylic alkylations: applications in total synthesis.
TL;DR: Alkylations with Phenols, Nitrogen Nucleophiles in AAA Total Synthesis, and Considerations for Enantioselective Allylic Alkylation are presented.
Book
Comprehensive organic synthesis
Paul Knochel,Gary A. Molander +1 more
TL;DR: Synthetic chemists requiring the essential facts in new areas, as well as students completely new to the field, will find "Comprehensive Organic Synthesis, Second Edition" an invaluable source, providing an authoritative overview of core concepts.
Journal ArticleDOI
A new method for the deoxygenation of secondary alcohols
TL;DR: In this paper, a general synthesis of O-cycloalkyl thioesters has been developed which gives access to O-cycle-alkyl seleno-formates and selenobenzoates.
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Synthesis of heterocycles from alkyl 3-(dimethylamino)propenoates and related enaminones.
Branko Stanovnik,Jurij Svete +1 more