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Open AccessJournal ArticleDOI

Dye-sensitization on the Photocurrent at Zinc Oxide Electrode in Aqueous Electrolyte Solution

Michio Matsumura, +2 more
- 01 Oct 1977 - 
- Vol. 50, Iss: 10, pp 2533-2537
TLDR
In this article, the dye-sensitized photocurrents generated from the electrochemical systems have been studied and the action spectra for the photocurrent, its dependence on the concentration of the dye solution and other experimental results have revealed that photocurrent is caused by the dye adsorbed on the electrode, not from that dissolved in the liquid phase.
Abstract
The dye-sensitized photocurrents generated from the electrochemical systems have been studied The action spectra for the photocurrent, its dependence on the concentration of the dye solution and other experimental results have revealed that the photocurrent is caused by the dye adsorbed on the electrode, not from that dissolved in the liquid phase From the analysis of the decay of the photocurrent with the time of illumination, the quantum yield for the electron injection from the excited dye has been determined Rose Bengal showed the quantum yield of 22% The influence of halide ions on the photocurrent has also been studied

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Citations
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Journal ArticleDOI

A low-cost, high-efficiency solar cell based on dye-sensitized colloidal TiO2 films

TL;DR: In this article, the authors describe a photovoltaic cell, created from low-to medium-purity materials through low-cost processes, which exhibits a commercially realistic energy-conversion efficiency.
Journal ArticleDOI

Dye-Sensitized Solar Cells

TL;DR: Dye-sensitized solar cells (DSCs) offer the possibilities to design solar cells with a large flexibility in shape, color, and transparency as mentioned in this paper, and many DSC research groups have been established around the world.
Journal ArticleDOI

Photo-electrochemical hydrogen generation from water using solar energy. Materials-related aspects

TL;DR: In this paper, the authors focused on the materials-related issues in the development of high-efficiency photo-electrochemical cells (PECs), in terms of semiconducting and electrochemical properties and their impact on the performance of PECs.
Journal ArticleDOI

Physical Chemistry of Semiconductor−Liquid Interfaces

TL;DR: A review of the basic physicochemical principles of semiconductor−liquid interfaces, including their historical development, and describe the major technological applications that are based on these scientific principles can be found in this paper.
Journal ArticleDOI

Nanostructured photoelectrodes for dye-sensitized solar cells

TL;DR: In this article, the authors classify the nanostructures into (1) nanoparticles, which offer large surface area to photo-electrode film for dye-adsorption, (2) core-shell structures, which are derived from the nanoparticles however with a consideration to reduce charge recombination by forming a coating layer, (3) one-dimensional nanstructures such as nanowires and nanotubes, which provide direct pathways for electron transport much faster than in the nanoparticle films, and (4) three-dimensional nanoparticles such as Nan
References
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Journal ArticleDOI

Electrochemical Photolysis of Water at a Semiconductor Electrode

TL;DR: Water photolysis is investigated by exploiting the fact that water is transparent to visible light and cannot be decomposed directly, but only by radiation with wavelengths shorter than 190 nm.
Journal ArticleDOI

Photoelectrochemical energy conversion and storage using polycrystalline chalcogenide electrodes

TL;DR: In this article, a major improvement in the conversion efficiency of corrosion-free photoelectrochemical cells (PECs) was reported, and a novel extension of such cells which allows the storage of part or all of the converted energy in situ for subsequent use.
Journal ArticleDOI

Dye sensitised zinc oxide: aqueous electrolyte: platinum photocell

TL;DR: In this article, the authors reported the successful construction of cells with a high power efficiency, achieving a quantum efficiency of 10−2 in the presence of dye sensitized photo-currents.
Journal ArticleDOI

Electrochemical Behavior of Semiconductors under Illumination

TL;DR: In contrast to metals, the average free energy of electrons can be changed in semiconductors to a great extent by illumination Especially the concentration of minority electronic carriers can differ by orders of magnitude from the equilibrium value.
Journal ArticleDOI

Photochemical and electrochemical processes of excited dyes at semiconductor and metal electrodes

TL;DR: In this article, anodic and cathodic photocurrents were observed, depending on the semiconducting material, and the mechanism of supersensitization was discussed in detail.
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