Journal ArticleDOI
Effect of solvents and co-solvents on the processibility of polyaniline: I. solubility and conductivity studies
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TLDR
In this article, the PANI-(acid)0.5 complex is solvated by at least an additional 0.5 mole of solvating agent per PANI unit (PhN).About:
This article is published in Synthetic Metals.The article was published on 1995-03-01. It has received 219 citations till now. The article focuses on the topics: Polyaniline & Solvent.read more
Citations
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Enhancement of electrical conductivity of poly(3,4-ethylenedioxythiophene)/poly(4-styrenesulfonate) by a change of solvents
TL;DR: In this paper, the authors measured the DC conductivity of poly(3,4-ethylenedioxythiophene) (PEDOT) doped with poly(4-styrenesulfonate) (PSS) with various organic solvents.
Journal ArticleDOI
Towards polymer-based organic thermoelectric generators
Olga Bubnova,Xavier Crispin +1 more
TL;DR: In this paper, the possibility of using organic conducting polymers in thermoelectric applications was examined and some of the first prototypes of polymer-based OEG generators were presented.
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Some aspects of preparation methods and properties of polyaniline blends and composites with organic polymers
TL;DR: In this paper, generalized approaches for the preparation of polyaniline materials are reviewed, focusing on features that determine properties of the final composites/blends, and two distinct groups of synthetic methods based on aniline polymerization either (1) in the presence of or inside a matrix polymer or (2) the blending of a previously prepared PANI with a matrix polymers.
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Recent progress in chemical modification of polyaniline
TL;DR: In this article, the main drawback of PANI is lack of solubility, which explains its limited processability due to a rigid backbone, and various procedures have been adapted to improve PANI's processability.
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Polyelectrolyte–Surfactant Complexes in the Solid State: Facile building blocks for self‐organizing materials
TL;DR: In this paper, a review of the state-of-the-art methods for the fabrication of self-doped conducting polymers is presented, in particular in the form of polyelectrolytes and surfactants.
References
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Journal ArticleDOI
Counter-ion induced processibility of conducting polyaniline and of conducting polyblends of polyaniline in bulk polymers
TL;DR: In this article, the authors demonstrate the feasibility of processing, in the conducting form, polyaniline and a variety of polyblends made from polyanILine, which can be melt-processed or processed from solution to enable the fabrication of thin films, sheets, fibers, transparent conductive films, bulk parts.
Journal ArticleDOI
Polyaniline: Solutions, Films and Oxidation State
M. Angelopoulos,G.E. Asturias,S. P. Ermer,Anjan Ray,E. M. Scherr,Alan G. MacDiarmid,M. Akhtar,Z. Kiss,Arthur J. Epstein +8 more
TL;DR: The emeraldine oxidation state of polyaniline in its base form, "emeraldine base" can be solution-processed to yield large flexible films which can be doped to the metallic conducting regime (σ ∼ 1-5 S/cm).
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Electrically-conductive fibers of polyaniline spun from solutions in concentrated sulfuric acid
TL;DR: In this article, the preparation of solutions of polyaniline in concentrated sulfuric acid was described, and the solutions were characterized by viscosity measurements and by ultraviolet(u.v)-visible spectroscopy.
Journal ArticleDOI
Solution-cast films of polyaniline: Optical-quality transparent electrodes
TL;DR: Optical quality transparent conducting films of polyaniline (PANI) and of conducting polyblends of PANI with amorphous bulk polymers are described in this article.
Journal ArticleDOI
Polyaniline: Protonic Acid Doping to the Metallic Regime
TL;DR: In this article, the quinoid-benzenoid-diimine form of polyaniline is doped by dilute aqueous protonic acids to the metallic regime to give the corresponding iminium salt.
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Counter-ion induced processibility of conducting polyaniline and of conducting polyblends of polyaniline in bulk polymers
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J. C. Chiang,Alan G. MacDiarmid +1 more