scispace - formally typeset
Journal ArticleDOI

Efficient Deep Blue Electroluminescence with an External Quantum Efficiency of 6.8% and CIEy < 0.08 Based on a Phenanthroimidazole–Sulfone Hybrid Donor–Acceptor Molecule

Reads0
Chats0
TLDR
In this article, a phenanthroimidazole-sulfone hybrid donor-acceptor (D-A) molecule with efficient deep blue emission has been reported, which has been proven to be an effective strategy to obtain high electroluminescence (EL) efficiency.
Abstract
Tremendous efforts have been devoted to develop efficient deep blue organic light-emitting diodes (OLEDs) materials with CIEy < 0.10 (Commission International de L’Eclairage (CIE)) and match the National Television System Committee (NTSC) standard blue CIE (x, y) coordinates of (0.14, 0.08) for display applications. However, deep blue fluorescent materials with an external quantum efficiency (EQE) over 5% are still rare. Herein, we report a phenanthroimidazole–sulfone hybrid donor–acceptor (D–A) molecule with efficient deep blue emission. D–A structure molecular design has been proven to be an effective strategy to obtain high electroluminescence (EL) efficiency. In general, charge transfer (CT) exciton formed between donor and acceptor is a weak coulomb bonded hole–electron pair and is favorable for the spin flip that can turn triplet excitons into singlet ones. However, the photoluminescence quantum yield (PLQY) of CT exciton is usually very low. On the other hand, a locally excited (LE) state normally ...

read more

Citations
More filters
Journal ArticleDOI

Recent Progress in High‐Efficiency Blue‐Light‐Emitting Materials for Organic Light‐Emitting Diodes

TL;DR: In this article, the authors summarized recent developments in blue fluorescent, phosphorescent and thermally activated delayed fluorescent emitters, and suggested key issues for each emitter and future development strategies.
Journal ArticleDOI

Deep Red Emissive Carbonized Polymer Dots with Unprecedented Narrow Full Width at Half Maximum

TL;DR: Deep red emissive carbonized polymer dots (CPDs) with unprecedented FWHM of 20 nm are synthesized and exhibit strong absorption and emission in the deep red light region, low toxicity, and good biocompatibility, making them an efficient probe for both one-photon and two- photon bioimaging.
Journal ArticleDOI

Recent progress in hot exciton materials for organic light-emitting diodes

TL;DR: A comprehensive review of the recent progress in hot exciton materials, which can effectively harness the non-radiative triplet excitons via reverse intersystem crossing (RISC) from high-lying triplet states to singlet states.
Journal ArticleDOI

Recent advances in organic light-emitting diodes: toward smart lighting and displays

TL;DR: In this paper, a review of light emission mechanisms of electroluminescent materials is presented, and a brief perspective on future research is also proposed for pursuing the commercialization of OLEDs.
References
More filters
Journal ArticleDOI

Highly efficient organic light-emitting diodes from delayed fluorescence

TL;DR: A class of metal-free organic electroluminescent molecules in which the energy gap between the singlet and triplet excited states is minimized by design, thereby promoting highly efficient spin up-conversion from non-radiative triplet states to radiative singlet states while maintaining high radiative decay rates.
Journal ArticleDOI

Structural Changes Accompanying Intramolecular Electron Transfer: Focus on Twisted Intramolecular Charge-Transfer States and Structures

TL;DR: The Rehybridization of the Acceptor (RICT) and Planarization ofThe Molecule (PICT) III is presented, with a comparison of the effects on yield and radiationless deactivation processes.
Journal ArticleDOI

Management of singlet and triplet excitons for efficient white organic light-emitting devices

TL;DR: This device challenges incandescent sources by exhibiting total external quantum and power efficiencies that peak at 18.7 ± 0.6 lm W-1, respectively, and two distinct modes of energy transfer within this device serve to channel nearly all of the triplet energy to the phosphorescent dopants, retaining the singlet energy exclusively on the blue fluorescent dopant.
Journal ArticleDOI

Recent Progresses on Materials for Electrophosphorescent Organic Light-Emitting Devices

TL;DR: Blue phosphorescence approaching the theoretical efficiency has also been achieved, which may overcome the final obstacle against the commercialization of full color display and white light sources from phosphorescent materials.
Journal ArticleDOI

Design of Efficient Thermally Activated Delayed Fluorescence Materials for Pure Blue Organic Light Emitting Diodes

TL;DR: TADF has been characterized for a carbazole/sulfone derivative in both solutions and doped films and a pure blue organic light emitting diode (OLED) based on this compound demonstrates a very high external quantum efficiency (EQE) of nearly 10% at low current density.
Related Papers (5)