Journal ArticleDOI
Electrochemical Reduction of Carbon Dioxide Using a Copper Rubeanate Metal Organic Framework
Reiko Hinogami,Satoshi Yotsuhashi,Masahiro Deguchi,Yuji Zenitani,Hiroshi Hashiba,Yuka Yamada +5 more
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TLDR
In this article, a copper rubeanate metal organic framework (CR-MOF) was used to improve the catalytic activity of electrochemical reduction of CO2 due to its characteristics of electronic conductivity, proton conductivity and dispersed reaction sites, and nanopores.Abstract:
We synthesized a copper rubeanate metal organic framework (CR-MOF) which has the potential to improve the catalytic activity of electrochemical reduction of CO2 due to its characteristics of electronic conductivity, proton conductivity, dispersed reaction sites, and nanopores. Synthesized CR-MOF particles were dropped on carbon paper (CP) to form a working electrode. The onset potential for CO2 reduction of a CR-MOF electrode was about 0.2 V more positive than that observed on a Cu metal electrode in an aqueous electrolyte solution. Our analysis of the reduction products during potentiostatic electrolysis showed formic acid (HCOOH) to be virtually the only CO2 reduction product on a CR-MOF electrode, whereas a Cu metal electrode generates a range of products. The quantity of products from the CR-MOF electrode was markedly greater (13-fold at −1.2 V vs. SHE) than that of a Cu metal electrode. Its stability was also confirmed.read more
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Carbon capture and conversion using metal–organic frameworks and MOF-based materials
TL;DR: This review provides a comprehensive account of significant progress in the design and synthesis of MOF-based materials, including MOFs, MOF composites and MOF derivatives, and their application to carbon capture and conversion.
Journal ArticleDOI
State of the Art and Prospects in Metal-Organic Framework (MOF)-Based and MOF-Derived Nanocatalysis.
Qi Wang,Didier Astruc +1 more
TL;DR: This review first briefly summarizes this background of MOF nanoparticle catalysis and then comprehensively reviews the fast-growing literature reported during the last years.
Journal ArticleDOI
Metal-Organic Frameworks as Platforms for Catalytic Applications.
TL;DR: An overview of recent developments achieved in MOF catalysis, including heterogeneousCatalysis, photocatalysis, and eletrocatalysis over MOFs and MOF-based materials, is provided.
Journal ArticleDOI
The chemistry of metal–organic frameworks for CO 2 capture, regeneration and conversion
Christopher A. Trickett,Aasif Helal,Bassem A. Al-Maythalony,Zain H. Yamani,Kyle E. Cordova,Omar M. Yaghi +5 more
TL;DR: In this paper, structural and chemical features of state-of-the-art metal-organic frameworks for their application in the entire carbon cycle of capturing, purifying and transforming CO 2 into valuable products are described.
Journal ArticleDOI
Metal−Organic Frameworks for Electrocatalytic Reduction of Carbon Dioxide
Nikolay Kornienko,Yingbo Zhao,Christopher S. Kley,Chenhui Zhu,Dohyung Kim,Song Lin,Christopher J. Chang,Omar M. Yaghi,Peidong Yang +8 more
TL;DR: Th thin films of nanosized metal-organic frameworks (MOFs) are introduced as atomically defined and nanoscopic materials that function as catalysts for the efficient and selective reduction of carbon dioxide to carbon monoxide in aqueous electrolytes.
References
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Functional porous coordination polymers.
TL;DR: The aim is to present the state of the art chemistry and physics of and in the micropores of porous coordination polymers, and the next generation of porous functions based on dynamic crystal transformations caused by guest molecules or physical stimuli.
Journal ArticleDOI
Selective gas adsorption and separation in metal–organic frameworks
TL;DR: This critical review starts with a brief introduction to gas separation and purification based on selective adsorption, followed by a review of gas selective adsorbents in rigid and flexible MOFs, and primary relationships between adsorptive properties and framework features are analyzed.
Journal ArticleDOI
Metal–organic framework materials as catalysts
JeongYong Lee,Omar K. Farha,John M. Roberts,Karl A. Scheidt,SonBinh T. Nguyen,Joseph T. Hupp +5 more
TL;DR: A critical review of the emerging field of MOF-based catalysis is presented and examples of catalysis by homogeneous catalysts incorporated as framework struts or cavity modifiers are presented.
Book
Modern Aspects of Electrochemistry
TL;DR: In this paper, the authors focus on topics at the forefront of electrochemical research, such as splitting water by electrolysis, splitting water with visible light, and the recent development of lithium batteries.
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