Journal ArticleDOI
Electronic spectra of ion radicals and their molecular orbital interpretation. III. Aromatic hydrocarbons
Tadamasa Shida,Suehiro Iwata +1 more
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This article is published in Journal of the American Chemical Society.The article was published on 1973-05-30. It has received 298 citations till now. The article focuses on the topics: Molecular orbital & Electronic structure.read more
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Pulse Radiolysis Study of the Reactions of Hydrogen Atoms in the Ionic Liquid Methyltributylammonium Bis[(trifluoromethyl)sulfonyl]imide
TL;DR: In this paper, the authors studied the reactions of hydrogen atoms with pyrene, phenanthrene, benzophenone, 2-propanol, and crotonic acid in the ionic liquid methyltributylammonium bis[(trifluoromethyl)sulfonyl]imide (R4NNTf2) by pulse radiolysis.
Journal ArticleDOI
Experimental Near-Infrared Spectroscopy of Polycyclic Aromatic Hydrocarbons between 0.7 and 2.5 μm
TL;DR: In this paper, the near infrared (NIR) spectra and absolute band strengths of 27 polycyclic aromatic hydrocarbon (PAH) cations and anions ranging in size from C14H10 to C50H22, are reported.
Journal ArticleDOI
Exploiting Charge-Transfer States for Maximizing Intersystem Crossing Yields in Organic Photoredox Catalysts.
TL;DR: A design exploiting orthogonal π-systems and an intermediate-energy charge-transfer excited state to maximize ISC yields (ΦISC) in a highly reducing ( E0* = -1.7 V vs SCE), visible-light-absorbing phenoxazine-based PC.
Journal ArticleDOI
Reaction Kinetics in the Ionic Liquid Methyltributylammonium Bis(Trifluoromethylsulfonyl)imide. Pulse Radiolysis Study of •CF3 Radical Reactions
J Grodkowski,Pedatsur Neta +1 more
TL;DR: In this paper, the reactions of trifluoromethyl radicals with pyrene, phenanthrene, crotonic acid, and 2-propanol (2-PrOH) in the ionic liquid methyltributylammonium bis(trifluorsulfonyl)imide (R4NNTf2) are studied by pulse radiolysis.
Journal ArticleDOI
Radiative Depopulation of the Excited Intramolecular Charge-Transfer State of 9-(4-(N,N-Dimethylamino)phenyl)phenanthrene
A. Onkelinx,F. C. De Schryver,L. Viaene,M. Van der Auweraer,Kaoru Iwai,Masao Yamamoto,Musubu Ichikawa,Hiroshi Masuhara,M. Maus,Wolfgang Rettig +9 more
TL;DR: The solvent dependence of the fluorescence spectra of 9-p-N,N-dimethylanilino (9-DPhen) has been studied in solution as mentioned in this paper, showing that the emission occurs from a highly polar excited state.