Journal ArticleDOI
Electronic spectra of ion radicals and their molecular orbital interpretation. III. Aromatic hydrocarbons
Tadamasa Shida,Suehiro Iwata +1 more
About:
This article is published in Journal of the American Chemical Society.The article was published on 1973-05-30. It has received 298 citations till now. The article focuses on the topics: Molecular orbital & Electronic structure.read more
Citations
More filters
Journal ArticleDOI
After 118 years, the isolation of two common radical anion reductants as simple, stable solids
Thomas A. Scott,Betty A. Ooro,David J. Collins,Michael Shatruk,Andrey A. Yakovenko,Kim R. Dunbar,Hong-Cai Zhou,Hong-Cai Zhou +7 more
TL;DR: Two common radical anion reductants have been isolated and characterized for the first time in solvent-free form or with low solvent content, allowing their use as pure solid reactants in preparative redox chemistry in accurate stoichiometric amounts.
Journal ArticleDOI
Theoretical electron affinities of PAHs and electronic absorption spectra of their mono-anions
Giuliano Malloci,Giuliano Malloci,Giacomo Mulas,Giancarlo Cappellini,Vincenzo Fiorentini,I. Porceddu +5 more
TL;DR: In this paper, the authors present theoretical electron affinities, calculated as total energy differences, for a large sample of polycyclic aromatic hydrocarbons (PAHs), ranging in size from azulene (C10H8) to dicoronylene (C48H20), showing them to be able to accept an additional electron in their LUMO π � orbital.
Journal ArticleDOI
Solvent-induced stabilization of the naphthalene anion by water molecules: A negative cluster ion photoelectron spectroscopic study
TL;DR: In this article, it was shown that only a single water molecule is needed to stabilize the naphthalene anion, and that the EAa of Nph1−(H2O)n is −0.20 eV, consistent with determinations by electron transmission spectroscopy.
Journal ArticleDOI
D2 ← D0 transition of the anthracene cation observed by cavity ring-down absorption spectroscopy in a supersonic jet
O. Sukhorukov,Angela Staicu,E. Diegel,Gaël Rouillé,Gaël Rouillé,Th. Henning,Friedrich Huisken,Friedrich Huisken +7 more
TL;DR: In this paper, the absorption spectrum of the anthracene cation (An + ) in a supersonic jet by cavity ring-down spectroscopy was studied and the D 2 ǫ← D 0 transition of An + has been located at 708.76 ± 0.13 nm.
Journal ArticleDOI
Generation of radical-cations from naphthalene and some derivatives, both by photoionization and reaction with SO4–˙: formation and reactions studied by laser flash photolysis
TL;DR: Radical-cations from naphthalene and some derivatives have been generated in aqueous acetonitrile both by direct photolysis (with λ 248 nm light via biphotonic ionization) and via reaction with SO4−˙ as discussed by the authors.